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Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…

General Physics · Physics 2009-11-13 David Sands

We prove existence of equilibrium states with special properties for a class of distance expanding local homeomorphisms on compact metric spaces and continuous potentials. Moreover, we formulate a C$^1$ generalization of Pesin's Entropy…

Dynamical Systems · Mathematics 2019-04-09 Vitor Araujo , Felipe Santos

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

Some general considerations on the notion of entropy in physics are presented. An attempt is made to clarify the question of the differentiation between physical entropy (the Clausius-Boltzmann one) and quantities called entropies…

Statistical Mechanics · Physics 2007-05-23 Roberto Luzzi , Áurea R. Vasconcellos , J. Galvão Ramos

By using the Jacobi metric of the configuration space, and assuming ergodicity, we calculate the Boltzmann entropy $S$ of a finite-dimensional system around a non-degenerate critical point of its potential energy $V$. We compare $S$ with…

Mathematical Physics · Physics 2009-11-11 Nikos Kalogeropoulos

A plethora of natural, artificial and social complex systems exists which violate the basic hypothesis (e.g., ergodicity) of Boltzmann-Gibbs (BG) statistical mechanics. Many of such cases can be satisfactorily handled by introducing…

Statistical Mechanics · Physics 2016-07-26 Constantino Tsallis

In the works on Statistical Mechanics and Statistical Physics, when deriving the distribution of particles of ideal gases, one uses the method of Lagrange multipliers in a formal way. In this paper we treat rigorously this problem for…

Mathematical Physics · Physics 2016-01-12 Constantin Zalinescu

The Boltzmann and Gibbs approaches to statistical mechanics have very different definitions of equilibrium and entropy. The problems associated with this are discussed and it is suggested that they can be resolved, to produce a version of…

Statistical Mechanics · Physics 2007-10-11 David A. Lavis

The present paper studies a large class of temperature dependent probability distributions and shows that entropy and energy can be defined in such a way that these probability distributions are the equilibrium states of a generalized…

Statistical Mechanics · Physics 2015-06-24 Jan Naudts

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

Finite heat reservoir capacity and temperature fluctuations lead to modification of the well known canonical exponential weight factor. Requiring that the corrections least depend on the one-particle energy, we derive a deformed entropy,…

Statistical Mechanics · Physics 2016-05-20 T. S. Biro , G. G. Barnafoldi , P. Van

A mathematical procedure is suggested to obtain deformed entropy formulas of type K(S_K) = sum_i P_i K(-ln P_i), by requiring zero mutual K(S_K)-information between a finite subsystem and a finite reservoir. The use of this method is first…

Statistical Mechanics · Physics 2014-05-19 Tamas S. Biro

We give a new characterization of relative entropy, also known as the Kullback-Leibler divergence. We use a number of interesting categories related to probability theory. In particular, we consider a category FinStat where an object is a…

Information Theory · Computer Science 2017-08-22 John C. Baez , Tobias Fritz

Experimental and theoretical results about entropy limits for macroscopic and single-particle systems are reviewed. It is clarified when it is possible to speak about a quantum of entropy, given by the Boltzmann constant k, and about a…

Quantum Physics · Physics 2023-11-06 Uwe Hohm , Christoph Schiller

In a recent paper, Dunkel and Hilbert [Nature Physics 10, 67-72 (2014)] use an entropy definition due to Gibbs to provide a 'consistent thermostatistics' which forbids negative absolute temperatures. Here we argue that the Gibbs entropy…

Statistical Mechanics · Physics 2015-01-22 Daan Frenkel , Patrick B Warren

A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the…

Mathematical Physics · Physics 2014-07-02 Bernhard Baumgartner

Recent investigations of turbulent circulation fluctuations have uncovered substantial insights into the statistical organization of flow structures and revealed unexpected geometric features of turbulent intermittency. Of particular…

Certain fluctuations in particle number at fixed total energy lead exactly to a cut-power law distribution in the one-particle energy, via the induced fluctuations in the phase-space volume ratio. The temperature parameter is expressed…

Statistical Mechanics · Physics 2014-12-10 Tamas Sandor Biro , Peter Van , Gergely Gabor Barnafoldi , Karoly Urmossy

Gibbs' theorem, which is originally intended for canonical ensembles with complete statistics has been generalized to open systems with incomplete statistics. As a result of this generalization, it is shown that the stationary equilibrium…

Statistical Mechanics · Physics 2015-05-13 G. B. Bagci

The q-exponential distributions, which are generalizations of the Zipf-Mandelbrot power-law distribution, are frequently encountered in complex systems at their stationary states. From the viewpoint of the principle of maximum entropy, they…

Statistical Mechanics · Physics 2009-11-07 Sumiyoshi Abe
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