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According to Boltzmann-Gibbs (BG) statistical mechanics, the thermodynamic response, such as the isothermal susceptibility, at critical points (CPs) presents a divergent-like behavior. An appropriate parameter to probe both classical and…

Statistical Mechanics · Physics 2024-09-18 Samuel M. Soares , Lucas Squillante , Henrique S. Lima , Constantino Tsallis , Mariano de Souza

The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…

Statistical Mechanics · Physics 2020-07-01 S. N. Saadatmand , Tim Gould , E. G. Cavalcanti , J. A. Vaccaro

There is a conception that Boltzmann-Gibbs statistics cannot yield the long tail distribution. This is the justification for the intensive research of nonextensive entropies (i.e. Tsallis entropy and others). Here the error that caused this…

Information Theory · Computer Science 2009-06-30 Oded Kafri

An axiomatic foundation regarding the entropy for complex systems is established. Missing from decades of research was the requirement that entropy must measure the uncertainty at the informational scale of the maximizing distribution,…

Statistical Mechanics · Physics 2026-05-29 Kenric P. Nelson

The nonequilibrium stationary state of an irreversible spherical model is investigated on hypercubic lattices. The model is defined by Langevin equations similar to the reversible case, but with asymmetric transition rates. In spite of…

Statistical Mechanics · Physics 2015-06-03 M. O. Hase , M. J. de Oliveira

We consider a general lattice model of a finite protein in its environment and calculate its Boltzmann entropy SB(E) as a function of its energy E in a microcanonical ensemble, and Gibbs entropy SG(E) as a function of its average energy E…

Soft Condensed Matter · Physics 2007-08-17 P. D. Gujrati , Bradley Lambeth

The nonextensive statistics based on the $q$-entropy $S_q=-\frac{\sum_{i=1}^v(p_i-p_i^q)}{1-q}$ has been so far applied to systems in which the $q$ value is uniformly distributed. For the systems containing different $q$'s, the…

Statistical Mechanics · Physics 2007-05-23 L. Nivanen , M. Pezeril , Q. A. Wang , A. Le Mehaute

We prove the Shepp--Olkin conjecture, which states that the entropy of the sum of independent Bernoulli random variables is concave in the parameters of the individual random variables. Our proof is a refinement of an argument previously…

Probability · Mathematics 2017-05-24 Erwan Hillion , Oliver Johnson

Entropy in nonequilibrium statistical mechanics is investigated theoretically so as to extend the well-established equilibrium framework to open nonequilibrium systems. We first derive a microscopic expression of nonequilibrium entropy for…

Statistical Mechanics · Physics 2007-06-13 Takafumi Kita

Boltzmann's struggle with a derivation of the Second Law of Thermodynamics is sketched. So is his first derivation of the connection between entropy and probability in 1877. Planck's derivation and quantum mechanical modifications of…

History and Philosophy of Physics · Physics 2008-07-11 E. G. D. Cohen

The aim of this work is to analyze the entropy, entropy flux and entropy supply rate of granular fluids within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas…

Statistical Mechanics · Physics 2010-11-17 Gilberto M. Kremer

The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…

Statistical Mechanics · Physics 2020-07-01 Sheldon Goldstein , Joel L. Lebowitz , Roderich Tumulka , Nino Zanghi

We study the dynamical properties of certain shift spaces. To help study these properties we introduce two new classes of shifts, namely boundedly supermultiplicative (BSM) shifts and balanced shifts. It turns out that any almost specified…

Dynamical Systems · Mathematics 2014-11-27 Simon Baker , Andrei E. Ghenciu

We examine deviations from Boltzmann-Gibbs statistics for partially equilibrated systems of finite size. We find that such systems are characterized by the Levy distribution whose non-extensivity parameter is related to the number of…

Nuclear Theory · Physics 2007-05-23 Athanasios N. Petridis

A well-known result across information theory, machine learning, and statistical physics shows that the maximum entropy distribution under a mean constraint has an exponential form called the Gibbs-Boltzmann distribution. This is used for…

Machine Learning · Computer Science 2020-06-26 Amir R. Asadi , Emmanuel Abbe

The Bekenstein-Hawking entropy suggests that thermodynamics is an intrinsic ingredient of gravity. Here, we explore the idea that requirements of thermodynamic consistency could determine the gravitational entropy in other set-ups. We…

General Relativity and Quantum Cosmology · Physics 2011-12-23 Charis Anastopoulos , Ntina Savvidou

We consider the maximum entropy problems associated with R\'enyi $Q$-entropy, subject to two kinds of constraints on expected values. The constraints considered are a constraint on the standard expectation, and a constraint on the…

Information Theory · Computer Science 2008-12-18 Jean-François Bercher

Gibbsian statistical mechanics is extended into the domain of non-negligible {though non-specified} correlations in phase space while respecting the fundamental laws of thermodynamics. The appropriate Gibbsian probability distribution is…

Statistical Mechanics · Physics 2014-06-26 R. A. Treumann , W. Baumjohann

It is always some constraint that yields any nontrivial structure from statistical averages. As epitomized by the Boltzmann distribution, the energy conservation is often the principal constraint acting on mechanical systems. Here, we…

Statistics Theory · Mathematics 2016-07-06 Naoki Sato , Zensho Yoshida

By considering general Markov stochastic dynamics and its coarse-graining, we study the framework of stochastic thermodynamics for the original and reduced descriptions corresponding to different scales. We are especially concerned with the…

Statistical Mechanics · Physics 2015-01-29 Yohei Nakayama , Kyogo Kawaguchi
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