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We report our theoretical results on the order parameters for the pyrochlore metal Cd$_2$Re$_2$O$_7$, which undergoes enigmatic phase transitions with inversion symmetry breaking. By carefully examining active electronic degrees of freedom…

Strongly Correlated Electrons · Physics 2019-04-17 Satoru Hayami , Yuki Yanagi , Hiroaki Kusunose , Yukitoshi Motome

We consider a system where structural polymorphism suggests the possible existence of superconductivity through the implied structural instability. SrPd2Bi2 has two poly-morphs which can be controlled by the synthesis temperature: a…

Superconductivity · Physics 2016-02-04 Weiwei Xie , Elizabeth M. Seibel , Robert J. Cava

Unconventional superconductors with nearly degenerate pairing states are rare. CeRh$_2$As$_2$ has recently emerged as one of the few existing multi-phase superconductors. It exhibits a first-order phase transition between two distinct…

The single-crystal growth, stoichiometry, and structure of Rb1-xFe2-ySe2-zSz crystals with substitution of Se by S are reported. The variation of the magnetic and thermodynamic parameters of samples was studied by differential-scanning…

We report the ferroelectric property in Tb2Ti2O7 pyrochlore, prepared by a two-step solid-state reaction method. A concave P-E (polarisation vs electric field) loop observed from 382 K confirms ferroelectricity, below which the loop remains…

Materials Science · Physics 2021-02-03 B. Santhosh Kumar , Rajesh Narayana Perumal , C. Venkateswaran

Spinel compounds AB$_{2}$X$_{4}$ consist of both tetrahedral (AX$_{4}$) and octahedral (BX$_{6}$) environments with the former forming a diamond lattice and the latter a geometrically frustrated pyrochlore lattice. Exploring the fascinating…

Chemical Physics · Physics 2023-03-29 Qiang Zhang , Wei Tian , Roshan K. Nepal , Ashfia Huq , Stephen Nagler , J. F. DiTusa , Rongying Jin

Very recently, a new superconductor with Tc = 80 K was reported in nickelate (La3Ni2O7) at around 15 - 40 GPa conditions (Nature, 621, 493, 2023) [1], which is the second type of unconventional superconductor, beside the cuprates, with Tc…

The classification of structural phase transitions as displacive or order-disorder in character is usually based on spectroscopic data above the transition. We use single crystal x-ray diffraction to investigate structural correlations in…

The discovery of unconventional superconductivity in the heavy-fermion material UTe$_2$ has reinvigorated research of spin-triplet superconductivity. We perform a theoretical study of coupled two-component spin-triplet superconducting order…

Superconductivity · Physics 2024-02-23 Henrik S. Røising , Max Geier , Andreas Kreisel , Brian M. Andersen

We investigate the interplay of the electronic and structural transition in La$_{0.2}$Sr$_{0.8}$MnO$_{3}$. The transport and specific heat measurements exhibit unusual evolutions and signature of a first order phase transition around 265 K.…

Strongly Correlated Electrons · Physics 2009-11-13 R. Bindu , Kalobaran Maiti , R. Rawat , S. Khalid

The interplay between unconventional superconductivity and the ordering of charge/spin density wave is one of the most vital issues in both condensed matter physics and material science. The Ti-based compound BaTi_2As_2O, which can be seen…

Thermodynamic experiments as well as Raman scattering have been used to study the magnetic instabilities in the spin-tetrahedra systems Cu_2Te_2O_5X_2, X=Cl and Br. While the phase transition observed in the Cl system at T_o=18.2 K is…

Strongly Correlated Electrons · Physics 2009-11-07 P. Lemmens , K. -Y. Choi , E. E. Kaul , Ch. Geibel , K. Becker , W. Brenig , R. Valenti , C. Gros , M. Johnsson , P. Millet , F. Mila

Experimental evidence from measurements of the a.c. and d.c. susceptibility, and heat capacity data show that the pyrochlore structure oxide, Gd_2Ti_2O_7, exhibits short range order that starts developing at 30K, as well as long range…

Disordered Systems and Neural Networks · Physics 2009-10-31 N. P. Raju , M. Dion , M. J. P. Gingras , T. E. Mason , J. E. Greedan

The structural properties of LaRu$_2$P$_2$ under external pressure have been studied up to 14 GPa, employing high-energy x-ray diffraction in a diamond-anvil pressure cell. At ambient conditions, LaRu$_2$P$_2$ (I4/mmm) has a tetragonal…

We report investigation of structural phase transitions in technologically important material sodium niobate as a function of temperature on heating over 300-1075 K. Our high resolution powder neutron diffraction data show variety of…

Materials Science · Physics 2015-05-20 S. K. Mishra , R. Mittal , V. Yu. Pomjakushin , S. L. Chaplot

Er$_2$Sn$_2$O$_7$ remains a puzzling case among the extensively studied frustrated compounds of the rare-earth pyrochlore family. Indeed, while a first order transition towards a long-range antiferromagnetic state with the so-called…

Strongly Correlated Electrons · Physics 2017-11-16 S. Petit , E. Lhotel , F. Damay , P. Boutrouille , A. Forget , D. Colson

Synchrotron X-ray diffraction patterns were measured and analyzed for a polycrystalline sample of the room-temperature ferromagnet Sr3.12Er0.88Co4O10.5 from 300 to 650 K, from which two structural phase transitions were found to occur…

Strongly Correlated Electrons · Physics 2009-11-13 Shintaro Ishiwata , Wataru Kobayashi , Ichiro Terasaki , Kenichi Kato , Masaki Takata

DyRh4B4 has been known to crystallize in the primitive tetragonal (pt)-structure and to exhibit a ferromagnetic transition at 12 K, the highest magnetic transition temperature in the entire series of the RRh4B4 materials [1]. We show here…

Superconductivity · Physics 2009-06-13 A. Köhler , G. Behr , G. Fuchs , K. Nenkov , L. C. Gupta

Perturbed angular correlation spectroscopy combined with $ab-initio$ electronic structure calculations is used to unravel the structural phase transition path from the low-temperature polar structure to the high-temperature structural phase…

The role of layer disorder is important in establishing the topological phases of MoTe${_2}$. A rich tapestry of atomic ordering influences the structural phase transitions (SPTs), but there is little understanding of the mechanistic…

Materials Science · Physics 2023-12-07 Sumit Khadka , Leighanne C. Gallington , Byron Freelon
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