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Two-dimensional (2D) hybrid sp-sp2 carbon systems are an appealing subject for science and technology. For these materials, topology and structure significantly affect electronic and vibrational properties. We investigate here by periodic…

Materials Science · Physics 2022-05-18 P. Serafini , A. Milani , M. Tommasini , C. Castiglioni , D. M. Proserpio , C. E. Bottani , C. S. Casari

Atomic vibrations control all thermally activated processes in materials including diffusion, heat transport, phase transformations, and surface chemistry. Recent developments in monochromated, aberration-corrected scanning transmission…

Materials Science · Physics 2020-01-08 Kartik Venkatraman , Barnaby D. A. Levin , Katia March , Peter Rez , Peter A. Crozier

We experimentally quantify the Raman scattering from individual carbyne chains confined in double-walled carbon nanotubes. We find that the resonant differential Raman cross section of confined carbyne is on the order of $10^{-22}$…

Mesoscale and Nanoscale Physics · Physics 2020-08-18 Cla Duri Tschannen , Georgy Gordeev , Stephanie Reich , Lei Shi , Thomas Pichler , Martin Frimmer , Lukas Novotny , Sebastian Heeg

Recently, the novel system of linear carbon chains inside of double-walled carbon nanotubes has extended the length of $sp^1$ hybridized carbon chains from 44 to thousands of atoms [L. Shi et al., Nat. Mater. 15, 634 (2016)]. The…

Mesoscale and Nanoscale Physics · Physics 2017-05-09 M. Wanko , Seymur Cahangirov , Lei Shi , Philip Rohringer , Zachary J. Lapin , Lukas Novotny , Paola Ayala , Thomas Pichler , Angel Rubio

We demonstrate sensitive and fast electrical measurements of a carbon nanotube mechanical resonator. The nanotube is configured as a single-electron transistor, whose conductance is a sensitive transducer for its own displacement. Using an…

Mesoscale and Nanoscale Physics · Physics 2018-10-25 Yutian Wen , N. Ares , T. Pei , G. A. D. Briggs , E. A. Laird

We present atomically-resolved STM images of single-wall carbon nanotubes (SWNTs) embedded in a crystalline nanotube rope. Although they may be interpreted as of a chiral nanotube, the images are more consistently explained a an achiral…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 W. Clauss , D. J. Bergeron , A. T. Johnson

Aqueous suspensions of bundles and individual single-wall carbon nanotubes were prepared with the help of surfactants. We study the changes in the Raman spectra of the suspensions with respect to powders, and of exfoliated tubes with…

Other Condensed Matter · Physics 2007-05-23 Nicolas Izard , Didier Riehl , Eric Anglaret

Recently, laser-assisted chemical vapor deposition was used to synthesize a free-standing, continuous, and stable monolayer amorphous carbon (MAC). MAC is a pure carbon structure composed of randomly distributed five, six, seven, and eight…

We synthesized distorted octahedral(T') molybdenum ditelluride (MoTe2) and investigated its vibrational properties with Raman spectroscopy, density functional theory and symmetry analysis. Compared to the results from high temperature…

Mesoscale and Nanoscale Physics · Physics 2016-08-22 Shao-Yu Chen , Thomas Goldstein , Dhandapani Venkataraman , Ashwin Ramasubramaniam , Jun Yan

We report on three new types of nanoelectromechanical systems based on carbon nanotubes: an electromechanical nanothermometer, a nanorelay and a nanomotor. The nanothermometer can be used for accurate temperature measurements in spatially…

Other Condensed Matter · Physics 2015-05-13 Andrey M. Popov , Yurii E. Lozovik , Elena Bichoutskaia , Anton S. Kulish

We use Boltzmann transport equation (BE) to study time evolution of a photo-excited state in a nanoparticle including phonon-mediated exciton relaxation and the multiple exciton generation (MEG) processes, such as exciton-to-biexciton…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Andrei Kryjevski , Deyan Mihaylov , Svetlana Kilina , Dmitri Kilin

Tellurium can form nanowires of helical atomic chains. Given their unique one-dimensional van der Waals structure, these nanowires are expected to show remarkably different physical and electronic properties than bulk tellurium. Here we…

Raman intensities of Si quantum dots (QDs) with up to 11,489 atoms (about 7.6 nm in diameter) for different scattering configurations are calculated. First, phonon modes in these QDs, including all vibration frequencies and vibration…

Materials Science · Physics 2009-11-07 Wei Cheng , Shang-Fen Ren

Chiral phonons are mirror-symmetric vibrations that correspond to twisting and rotational motions of atoms. In chiral biomolecules, they correspond to low-energy terahertz (THz)-range vibrations of the molecular segments involving dozens of…

We show that thin horizontal arrays of single wall carbon nanotubes (SWNTs) suspended above the channel of silicon MOSFETs can be used as vibrating gate electrodes. This new class of nano-electromechanical system (NEMS) combines the unique…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 A. Arun , S. Campidelli , A. Filoramo , V. Derycke , P. Salet , A. M. Ionescu , M. F. Goffman

We have performed polarized and temperature-dependent Raman scattering measurements on extremely large magnetoresitance compounds TaAs$_2$ and NbAs$_2$. In both crystals, all the Raman active modes, including six A$_g$ modes and three B$_g$…

The fracture of carbon nanotubes is studied by atomistic simulations. The fracture behavior is found to be almost independent of the separation energy and to depend primarily on the inflection point in the interatomic potential. The rangle…

Atomic and Molecular Clusters · Physics 2009-11-07 T. Belytschko , S. P. Xiao , G. C. Schatz , R. Ruoff

Infrared and Raman spectra of the three chiral molecular conductors (EDT-TTF-OX)_2AsF_6, comprising two salts based on enantiopure EDT-TTF-OX donor molecules and one based on their racemic mixture, have been measured as a function of…

We report first principles linear response calculations on NaCoO$_2$. Phonon frequencies and eigenvectors are obtained throughout the Brillouin zone for two geometries with different Na site occupancies. While most of the phonon modes are…

Materials Science · Physics 2007-05-23 Zhenyu Li , Jinlong Yang , J. G. Hou , Qingshi Zhu

Raman scattering is used to observe pronounced electronic excitations around 230 meV - well above the two-phonon range - in the Mott insulators LaTiO$_3$ and YTiO$_3$. Based on the temperature, polarization, and photon energy dependence,…

Strongly Correlated Electrons · Physics 2007-05-23 C. Ulrich , A. Gössling , M. Grüninger , M. Guennou , H. Roth , M. Cwik , T. Lorenz , G. Khaliullin , B. Keimer
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