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We show that quantum coherence can increase the quantum efficiency of various thermodynamic systems. For example, we can enhance the quantum efficiency for a quantum dot photocell, a laser based solar cell and the photo-Carnot quantum heat…

Quantum Physics · Physics 2011-02-03 Kimberly Chapin , Konstantin Dorfman , Anatoly Svidzinsky , Marlan Scully

We study how much the efficiency of a solar cell as a quantum heat engine could be enhanced by quantum coherence. In contrast to the conventional approach that a quantum heat engine is in thermal equilibrium with both hot and cold…

Quantum Physics · Physics 2020-05-28 Sangchul Oh

Photovoltaic materials are recognized for their potential as sustainable energy sources that enable the conversion between light and electrical energy. However, solar cells have been unable to surpass the theoretical limit of 32%, known as…

Applied Physics · Physics 2024-06-18 Jeonggyu Hwang

To absorb the photons below the band-gap energy effectively, we proposed a quantum dot (QD) photocell modeled by multi-level system for the quantum yields and photo-to-charge efficiency limits. The theoretical results show the quantum…

Mesoscale and Nanoscale Physics · Physics 2024-02-26 Shun-Cai Zhao , Jing-Yi Chen

Thermophotovoltaic devices are energy-conversion systems generating an electric current from the thermal photons radiated by a hot body. In far field, the efficiency of these systems is limited by the thermodynamic Schockley-Queisser limit…

Mesoscale and Nanoscale Physics · Physics 2016-07-19 Riccardo Messina , Philippe Ben-Abdallah

Improving the conversion efficiency of solar energy to electricity is most important to mankind. For single-junction photovoltaic solar-cells, the Shockley-Queisser thermodynamic efficiency limit is extensively due to the heat dissipation,…

Optics · Physics 2015-06-11 Assaf Manor , Leopoldo L. Martin , Carmel Rotschild

The fundamental efficiency limit of a single bandgap solar cell is about 31% at one sun with a bandgap of about Eg = 1.35 eV (1), determined by the trade-off of maximising current with a smaller bandgap and voltage with a larger bandgap.…

Mesoscale and Nanoscale Physics · Physics 2016-06-17 C Rohr , P Abbott , I M Ballard , D B Bushnell , J P Connolly , N J Ekins- Daukes , K W J Barnham

Maximum efficiency of ideal single-junction photovoltaic (PV) cells is limited to 33% (for one sun illumination) by intrinsic losses such as band edge thermalization, radiative recombination, and inability to absorb below-bandgap photons.…

Optics · Physics 2015-06-17 Svetlana V. Boriskina , Gang Chen

A theoretical model using electron-phonon scattering rate equations is developed for assessing carrier thermalization under steady-state conditions in two-dimensional systems. The model is applied to investigate the hot carrier effect in…

It is thought that nature already exploits quantum mechanical properties to increase the efficiency of solar energy harvesting devices. So, the operation of these devices can be enhanced by clever design of a nanoscopic, quantum mechanical…

Mesoscale and Nanoscale Physics · Physics 2024-07-17 Baharak Mohamad Jafari Navadel , Esfandyar Faizi , Baharam Ahansaz , Jaber Jahanbin Sardroodi

Carrier Selective (CS) Silicon solar cells are increasingly explored as a low cost alternative to PN junction Silicon solar cells. While the recent trends on power conversion efficiency are encouraging, the temperature coefficient and hence…

Applied Physics · Physics 2021-01-28 Nithin Chatterji , Aldrin Antony , Pradeep R. Nair

Absorbed sunlight in a solar cell produces electrons and holes. But, at the open circuit condition, the carriers have no place to go. They build up in density and, ideally, they emit external fluorescence that exactly balances the incoming…

Optics · Physics 2013-08-02 Owen D. Miller , Eli Yablonovitch , Sarah R. Kurtz

Thermodynamic properties of the one-dimensional (1D) quantum well (QW) with miscellaneous permutations of the Dirichlet (D) and Neumann (N) boundary conditions (BCs) at its edges in the perpendicular to the surfaces electric field…

Mesoscale and Nanoscale Physics · Physics 2018-10-17 O. Olendski

The Shockley-Queisser (S-Q) theory defines the thermodynamic upper limits for Jsc, Voc, FF, and efficiency of a solar cell. The classical calculation assumes an abrupt onset of absorption at the band-edge, perfect absorption for all…

General Physics · Physics 2015-07-02 M. Ryyan Khan , Peter Bermel , Muhammad A. Alam

The correct accounting for thermal effects is always a challenge when one needs to make quantitative predictions for any laser applications. In such complicated devices as quantum cascade lasers temperature strongly affects the operational…

Mesoscale and Nanoscale Physics · Physics 2023-01-20 Ivan I. Vrubel , Evgeniia D. Cherotchenko , Georgii D. Miskovets , Vladislav V. Dudelev , Grigorii S. Sokolovskii

The Shockley-Queisser limit describes the maximum solar energy conversion efficiency achievable for a particular material and is the standard by which new photovoltaic technologies are compared. This limit is based on the principle of…

Optics · Physics 2014-12-04 Yunlu Xu , Tao Gong , Jeremy N. Munday

One way for solar cell efficiencies to overcome the Shockley-Queisser limit is downconversion of high-energy photons using singlet fission (SF) in polyacenes like tetracene (Tc). SF enables generation of multiple excitons from the…

Applied Physics · Physics 2018-01-31 S. W. Tabernig , B. Daiber , T. Wang , B. Ehrler

We propose a scheme of multilayer thermoelectric engine where {\em one} electric current is coupled to {\em two} temperature gradients in three-terminal geometry. This is realized by resonant tunneling through quantum dots embedded in two…

Mesoscale and Nanoscale Physics · Physics 2015-07-06 Jian-Hua Jiang

The use of low-dimensional structures such as quantum wells, wires or dots in the absorbing regions of solar cells strongly affects the spectral response of the latter, the spectral properties being drastically modified by quantum…

Mesoscale and Nanoscale Physics · Physics 2012-06-14 U. Aeberhard

The enhancement of power conversion efficiency beyond the theoretical limit of single-junction solar cells is a key objective in the advancement of hot carrier solar cells. Recent findings indicate that quantum wells (QWs) can effectively…

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