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It is nontrivial whether the average size of a ring polymer should become smaller or larger under a topological constraint. Making use of some knot invariants, we evaluate numerically the mean square radius of gyration for ring polymers…

Statistical Mechanics · Physics 2016-08-31 Miyuki K. Shimamura , Tetsuo Deguchi

The probability of a random polygon (or a ring polymer) having a knot type $K$ should depend on the complexity of the knot $K$. Through computer simulation using knot invariants, we show that the knotting probability decreases exponentially…

Soft Condensed Matter · Physics 2009-11-07 Miyuki K. Shimamura , Tetsuo Deguchi

We study knotted polymers in equilibrium with an array of obstacles which models confinement in a gel or immersion in a melt. We find a crossover in both the geometrical and the topological behavior of the polymer. When the polymers' radius…

Soft Condensed Matter · Physics 2013-05-29 Enzo Orlandini , Attilio L. Stella , Carlo Vanderzande

We argue that the mean crossing number of a random polymer configuration is simply a measure of opacity, without being closely related to entanglement as claimed by several authors. We present an easy way of estimating its asymptotic…

Statistical Mechanics · Physics 2009-10-31 Peter Grassberger

The interplay between the topological and geometrical properties of a polymer ring can be clarified by establishing the entanglement trapped in any portion (arc) of the ring. The task requires to close the open arcs into a ring, and the…

Soft Condensed Matter · Physics 2015-05-27 Luca Tubiana , Enzo Orlandini , Cristian Micheletti

Polymers in a melt may be subject to topological constraints, as in the example of unlinked polymer rings. How to do statistical mechanics in the presence of such constraints remains a fundamental open problem. We study the effect of…

Statistical Mechanics · Physics 2015-12-04 Pablo Serna , Guy Bunin , Adam Nahum

Two types of average structures of a single knotted ring polymer are studied by Brownian dynamics simulations. For a ring polymer with N segments, its structure is represented by a 3N -dimensional conformation vector consisting of the…

Soft Condensed Matter · Physics 2009-11-13 Shinya Saka , Hiroshi Takano

Polymers are an effective test-bed for studying topological constraints in condensed matter due to a wide array of synthetically-available chain topologies. When linear and ring polymers are blended together, emergent rheological properties…

Soft Condensed Matter · Physics 2024-04-25 Daniel L. Vigil , Ting Ge , Michael Rubinstein , Thomas C. O'Connor , Gary S. Grest

Inspired by how certain proteins "sense" knots and entanglements in DNA molecules, here we ask if there exist local geometric features that may be used as a read-out of the underlying topology of generic polymers. We perform molecular…

Unconcatenated, unknotted polymer rings in the melt are subject to strong interactions with neighboring chains due to the presence of topological constraints. We study this by computer simulation using the bond-fluctuation algorithm for…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , J. P. Wittmer , M. E. Cates

Stochastic simulations are used to characterize the knotting distributions of random ring polymers confined in spheres of various radii. The approach is based on the use of multiple Markov chains and reweighting techniques, combined with…

Soft Condensed Matter · Physics 2009-11-11 C. Micheletti , D. Marenduzzo , E. Orlandini , D. W. Sumners

Several nontrivial properties are shown for the mean square radius of gyration $R_K^2$ of ring polymers with a fixed knot type K. Through computer simulation, we discuss both finite-size and asymptotic behaviors of the gyration radius under…

Soft Condensed Matter · Physics 2009-11-07 Miyuki K. Shimamura , Tetsuo Deguchi

We investigate the effect of knot type on the properties of a ring polymer confined to a slit. For relatively wide slits, the more complex the knot, the more the force exerted by the polymer on the walls is decreased compared to an…

Soft Condensed Matter · Physics 2014-11-18 R. Matthews , A. A. Louis , J. M. Yeomans

For various polymers with different topological structures we numerically evaluate the mean-square radius of gyration and the hydrodynamic radius systematically through simulation. We call polymers with nontrivial topology topological…

Soft Condensed Matter · Physics 2016-11-23 Erica Uehara , Tetsuo Deguchi

Computing the crossing number of a graph is one of the most classical problems in computational geometry. Both it and numerous variations of the problem have been studied, and overcoming their frequent computational difficulty is an active…

Computational Geometry · Computer Science 2024-12-18 Thekla Hamm , Fabian Klute , Irene Parada

Topological constraints can affect both equilibrium and dynamic properties of polymer systems, and can play a role in the organization of chromosomes. Despite many theoretical studies, the effects of topological constraints on the…

Soft Condensed Matter · Physics 2014-12-12 Maxim Imakaev , Konstantin Tchourine , Sergei Nechaev , Leonid Mirny

We present computer simulations to examine probability distributions of gyration radius for the no-thickness closed polymers of N straight segments of equal length. We are particularly interested in the conditional distributions when the…

Soft Condensed Matter · Physics 2007-05-23 N. T. Moore , R. Lua , A. Y. Grosberg

The statistical mechanics of a long knotted collapsed polymer is determined by a free-energy with a knot-dependent subleading term, which is linked to the length of the shortest polymer that can hold such knot. The only other parameter…

Statistical Mechanics · Physics 2014-12-01 Marco Baiesi , Enzo Orlandini , Attilio L. Stella

There are many methods developed to approximate a cloud of vectors embedded in high-dimensional space by simpler objects: starting from principal points and linear manifolds to self-organizing maps, neural gas, elastic maps, various types…

Machine Learning · Statistics 2016-09-01 E. M. Mirkes , A. Zinovyev , A. N. Gorban

Large scale molecular dynamics simulations on graphic processing units (GPUs) are employed to study the scaling behavior of ring polymers with various topological constraints in melts. Typical sizes of rings containing $3_1$, $5_1$ knots…

Soft Condensed Matter · Physics 2015-09-04 Benjamin Trefz , Peter Virnau
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