English

Geometry and topology of knotted ring polymers in an array of obstacles

Soft Condensed Matter 2013-05-29 v1 Statistical Mechanics

Abstract

We study knotted polymers in equilibrium with an array of obstacles which models confinement in a gel or immersion in a melt. We find a crossover in both the geometrical and the topological behavior of the polymer. When the polymers' radius of gyration, RGR_G, and that of the region containing the knot, RG,kR_{G,k}, are small compared to the distance b between the obstacles, the knot is weakly localised and RGR_G scales as in a good solvent with an amplitude that depends on knot type. In an intermediate regime where RG>b>RG,kR_G > b > R_{G,k}, the geometry of the polymer becomes branched. When RG,kR_{G,k} exceeds b, the knot delocalises and becomes also branched. In this regime, RGR_G is independent of knot type. We discuss the implications of this behavior for gel electrophoresis experiments on knotted DNA in weak fields.

Keywords

Cite

@article{arxiv.1004.4501,
  title  = {Geometry and topology of knotted ring polymers in an array of obstacles},
  author = {Enzo Orlandini and Attilio L. Stella and Carlo Vanderzande},
  journal= {arXiv preprint arXiv:1004.4501},
  year   = {2013}
}

Comments

4 pages, 6 figures