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Transport properties of metal-molecule-metal junctions containing monolayer of conjugated and saturated molecules with characteristic dimensions in the range of 30-300 nm are correlated with microscopic topography, stress and chemical…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Nikolai B. Zhitenev , Weirong Jiang , Artur Erbe , Zhenan Bao , Eric Garfunkel , Donald M. Tennant , Raymond A. Cirelli

Molecular electronics on silicon has distinct advantages over its metallic counterpart. We describe a theoretical formalism for transport through semiconductor-molecule heterostructures, combining a semi-empirical treatment of the bulk…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 T. Rakshit , G-C. Liang , A. W. Ghosh , S. Datta

We have investigated electrical transport through the molecular model systems benzenedithiol, benzenediamine, hexanedithiol and hexanediamine. Conductance histograms under different experimental conditions indicate that measurements using…

Mesoscale and Nanoscale Physics · Physics 2008-07-01 C. A. Martin , D. Ding , H. S. J. van der Zant , J. M. van Ruitenbeek

The variation of the electronic structure normal to 1D defects in quasi-freestanding MoS$_2$, grown by molecular beam epitaxy, is investigated through high resolution scanning tunneling spectroscopy at $5$K. Strong upwards bending of…

Electronic conduction through single molecules is affected by the molecular electronic structure as well as by other information that is extremely difficult to assess, such as bonding geometry and chemical environment. The lack of an…

Mesoscale and Nanoscale Physics · Physics 2009-05-21 Daniel R. Ward , Naomi J. Halas , Jacob W. Ciszek , James M. Tour , Yanpeng Wu , Peter Nordlander , Douglas Natelson

Equilateral triangle-shaped graphene nanoislands with a lateral dimension of $n$ benzene rings are known as $[n]$triangulenes. Individual $[n]$triangulenes are open-shell molecules, with single-particle electronic spectra that host $n-1$…

Mesoscale and Nanoscale Physics · Physics 2023-09-13 R. Ortiz , G. Catarina , J. Fernández-Rossier

The molecular structures of the monomeric, pentacoordinated ethylchloroniobium(V) compounds Me3NbCl2 and Me2NbCl3 have been determined by gas electron diffraction (GED)and Density Functional Theory (DFT) calculations, and, for Me3NbCl2, by…

Graphene bilayer systems are known to exhibit a band gap when the layer symmetry is broken, by applying a perpendicular electric field. The resulting band structure resembles that of a conventional semiconductor with a parabolic dispersion.…

Mesoscale and Nanoscale Physics · Physics 2015-07-03 Søren Schou Gregersen , Jesper Goor Pedersen , Stephen R. Power , Antti-Pekka Jauho

Search for low-dimensional materials with unique electronic properties is important for the development of electronic devices in nano scale. Through systematic first-principles calculations, we found that the band gaps of the…

Materials Science · Physics 2018-03-23 Xiaoxuan Ma , Jun Hu , Bicai Pan

We report on a theoretical study of the electronic structures of InSb and GaSb nanowires oriented along the [001] and [111] crystallographic directions. The nanowires are described by atomistic, spin-orbit inteaction included, tight-binding…

Mesoscale and Nanoscale Physics · Physics 2015-09-08 Gaohua Liao , Ning Luo , Zhihu Yang , Keqiu Chen , H. Q. Xu

The electronic structure of an isostructural series of molecular conductors, {\beta}'-X[Pd(dmit)_2]_2 is systematically studied by a first-principles method based on the density-functional theory. The calculated band structures are fitted…

Strongly Correlated Electrons · Physics 2013-03-15 Takao Tsumuraya , Hitoshi Seo , Masahisa Tsuchiizu , Reizo Kato , Tsuyoshi Miyazaki

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

Using first-principles density functional theory calculations, we investigate a family of stable two-dimensional crystals with chemical formula $A_2B_2$, where $A$ and $B$ belong to groups IV and V, respectively ($A$ = C, Si, Ge, Sn, Pb;…

Materials Science · Physics 2018-08-01 B. Ozdamar , G. Ozbal , M. N. Cinar , K. Sevim , G. Kurt , B. Kaya , H. Sevincli

Three-dimensional pentamode metamaterials are artificial solids that approximately behave like liquids, which have vanishing shear modulus. Pentamodes have recently become experimental reality. Here, we calculate their phonon band…

Materials Science · Physics 2015-06-05 Aude Martin , Muamer Kadic , Robert Schittny , Tiemo Bückmann , Martin Wegener

For analyzing quantum transport in semiconductor devices, accurate electronic structures are critical for quantitative predictions. Here we report theoretical analysis of electronic structures of all III-V zinc-blende semiconductor…

Materials Science · Physics 2015-06-15 Yin Wang , Haitao Yin , Ronggen Cao , Ferdows Zahid , Yu Zhu , Lei Liu , Jian Wang , Hong Guo

First-principles calculations using the plane-wave pseudopotential method within the generalized gradient approximation method were performed to study the pressure dependence of the structural, elastic, electronic and optical properties for…

Materials Science · Physics 2021-12-21 M. Radjai , A. Bouhemadou , D. Maouche

We have obtained a hole mobility for the organic conductor pentacene of 35 cm2/Vs at room temperature increasing to 58 cm2/Vs at 225K. These high mobilities result from a purification process in which 6,13-pentacenequinone was removed by…

Soft Condensed Matter · Physics 2009-11-10 Oana D. Jurchescu , Jacob Baas , Thomas T. M. Palstra

In the present work, first-principles calculations based on the density functional theory (DFT), GW approximation and Bethe-Salpeter equation (BSE) are performed to study the electronic and optical properties of penta-graphene (PG)…

Computational Physics · Physics 2024-01-12 Babak Minaie , Seyed A. Ketabi , José M. De Sousa

Using first-principles calculations based on density-functional theory, we investigated the adsorption of pentacene molecules on monolayer two-dimensional transition metal dichalcogenides (TMD). We considered the four most popular TMDs,…

Materials Science · Physics 2023-11-13 E. Black , P. Kratzer , J. M. Morbec

We validate that off-resonant electron transport across {\it ultra-short} oligomer molecular junctions is characterised by a conductance which decays exponentially with length, and we discuss a method to determine the damping factor via the…

Materials Science · Physics 2007-05-23 Giorgos Fagas , Agapi Kambili , Marcus Elstner
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