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The effect of hydrostatic pressure up to 27 GPa on the Raman scattering (RS) in bulk HfS$_2$ is investigated. There are two transformations of RS spectra, which take place during compression at pressure between 5.7 GPa and 9.8 GPa as well…

Materials Science · Physics 2022-04-21 M. Grzeszczyk , J. Gawraczyński , T. Woźniak , J. Ibáñez , Z. Muhammad , W. Zhao , M. R. Molas , A. Babiński

We study the pressure-induced structural transformation of Ge$_{136}$ clathrate by ab initio molecular dynamics and metadynamics. The system under pressure first undergoes amorphization followed by an ultrafast recrystallization to the…

Materials Science · Physics 2022-04-28 Marián Ryník , Stefano Leoni , Roman Martoňák

The high pressure structural properties of bismuth oxide Bi2SiO5 have been investigated up to 28 GPa using in situ powder synchrotron X-ray diffraction and up to 50 GPa with DFT calculations. The monoclinic structure is found to persist up…

To investigate the pressure-induced structural transitions of chromium dioxide (CrO$_{2}$), phonon dispersions and total energy band structures are calculated as a function of pressure. The first structural transition has been confirmed at…

Materials Science · Physics 2012-05-17 Sooran Kim , Kyoo Kim , Chang-Jong Kang , B. I. Min

The structural phase behaviors of pure zirconium metal under compressions up to $160$ GPa at room temperature are investigated from the perspective of ensemble theory where the partition function is solved by our recently proposed method…

Materials Science · Physics 2022-10-21 Bo-Yuan Ning

The structural analogue of iron-based superconductors the BaMn$_2$P$_2$ and BaMn$_2$As$_2$ compounds under hydrostatic pressure upto 140 GPa were studied within the framework of DFT+U. The transition from an antiferromagnetic (AFM)…

Superconductivity · Physics 2024-06-07 N. S. Pavlov , I. R. Shein , I. A. Nekrasov

We performed magnetization and electrical resistivity measurements under high pressures of up to 19 GPa for FeTe0.92. The compound shows an anomaly in magnetization and resistivity at atmospheric pressure due to a structural distortion…

Electrical resistivity \rho(T) of the 5f ferromagnet UGa2 was investigated for single-crystal samples as a function of pressure and magnetic field. The Curie temperature monotonously increases from T$_{C}$ = 124 K under quasi-hydrostatic…

Strongly Correlated Electrons · Physics 2015-02-18 A. V. Kolomiets , J. -C. Griveau , J. Prchal , A. V. Andreev , L. Havela

Magnesium dihydride ($\mgh$) stores 7.7 weight % hydrogen, but it suffers from a high thermodynamic stability and slow (de)hydrogenation kinetics. Alloying Mg with lightweight transition metals (TM = Sc, Ti, V, Cr) aims at improving the…

Materials Science · Physics 2009-02-04 Suleyman Er , Dhirendra Tiwari , Gilles A. de Wijs , Geert Brocks

Pressure-induced superconductivity and structural phase transitions in phosphorous (P) are studied by resistivity measurements under pressures up to 170 GPa and fully $ab-initio$ crystal structure and superconductivity calculations up to…

Transport and magnetic studies of PbTaSe$_2$ under pressure suggest existence of two superconducting phases with the low temperature phase boundary at $\sim 0.25$ GPa that is defined by a very sharp, first order, phase transition. The first…

We report on the crystal structure and electronic properties of the heavy fermion superconductor UTe2 at high pressure up to 11 GPa, as investigated by X-ray diffraction and electrical resistivity experiments. The X-ray diffraction…

We report that calculating the Gibbs free energy of the alpha-Al_2O_3 (0001) surfaces in equilibrium with a realistic environment containing both oxygen and hydrogen species is essential for obtaining theoretical predictions consistent with…

Materials Science · Physics 2009-10-31 Xiao-Gang Wang , Anne Chaka , Matthias Scheffler

With the motivation of searching for new superconductors in the Mg-B system, we performed ab initio evolutionary searches for all the stable compounds in this binary system in the pressure range of 0-200 GPa. We found previously unknown,…

Superconductivity · Physics 2017-05-24 M. M. Davari Esfahani , Q. Zhu , H. Dong , A. R. Oganov , S. Wang , M. S. Rakitin , X-F. Zhou

Titanium dioxide has been extensively studied in the rutile or anatase phases, while its high-pressure phases are less well understood, despite that many are thought to have interesting optical, mechanical and electrochemical properties.…

Materials Science · Physics 2022-03-14 Jacob G. Lee , Chris J. Pickard , Bingqing Cheng

Dielectric response in methanol measured in wide pressure and temperature range ($P < 6.0$ GPa; 100 K $<T<$ 360 K) reveals a series of anomalies which can be interpreted as a transformation between several solid phases of methanol including…

Materials Science · Physics 2015-06-15 M. V. Kondrin , A. A. Pronin , Y. B. Lebed , V. V. Brazhkin

The structural properties of Thallium (III) oxide (Tl2O3) have been studied both experimentally and theoretically under compression at room temperature. X-ray powder diffraction measurements up to 37.7 GPa have been complemented with ab…

Solid hydrogen sulfide is well known as a typical molecular crystal but its stability under pressure is still under debate. Particularly, Eremets et al. found the high pressure superconductivity with $T_{c}\approx$ 190 K in a H$_{2}$S…

Superconductivity · Physics 2015-05-20 Defang Duan , Xiaoli Huang , Fubo Tian , Da Li , Hongyu , Yu , Yunxian Liu , Yanbin Ma , Bingbing Liu , Tian Cui

We have investigated the pressure-induced phase transition and superconducting properties of niobium disulfide (NbS$_2$) based on the density functional theory. The structures of NbS$_2$ at pressures from 0 to 200 GPa were predicted using…

Superconductivity · Physics 2014-10-31 Zhong-Li Liu , Ling-Cang Cai , Xiu-Lu Zhang

We report the results of the X-ray diffraction study of B2O3 glass in the pressure interval up to 10 GPa in the 300-700 K temperature range, the results of in-situ volumetric measurements of the glass at pressures up to 9 GPa at room…

Disordered Systems and Neural Networks · Physics 2008-07-19 V. V. Brazhkin , Y. Katayama , K. Trachenko , O. B. Tsiok , A. G. Lyapin , Emilio Artacho , M. Dove , G. Ferlat , Y. Inamura , H. Saitoh