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We report on the preparation and characterization of single crystal gamma phase NaxCoO2 with 0.25 < x < 0.84 using a non-aqueous electrochemical chronoamperemetry technique. By carefully mapping the overpotential versus x (for x < 0.84), we…

Strongly Correlated Electrons · Physics 2009-11-13 G. J. Shu , Andrea Prodi , S. Y. Chu , Y. S. Lee , H. S. Sheu , F. C. Chou

We report the structural, vibrational and electrical transport properties up to 16 GPa of the 1T-TiTe2, a prominent layered 2D system, which is predicted to show a series of topologically trivial - nontrivial transitions under hydrostatic…

On the basis of the pseudopotential plane-wave(PP-PW) method and the local-density-functional theory(LDFT), this paper studies energetics, stress-strain relation, stability and ideal strength of $\beta $-SiC under various loading modes,…

Materials Science · Physics 2009-10-31 Weixue Li , Tzuchiang Wang

Two dimensional ferroic materials exhibit a variety of functional properties that can be tuned by temperature and pressure. CuInP2S6 is a layered material that is ferrielectric at room temperature and whose properties are a result of the…

Materials Science · Physics 2023-06-14 R. Rao , B. S. Conner , J. Jiang , R. Pachter , M. A. Susner

We present a combined experimental and theoretical study of the effects of pressure on T_c of the hexagonal layered superconductors nH-CaAlSi (n = 1, 5, 6), where nH labels the different stacking variants that were recently discovered.…

Superconductivity · Physics 2009-11-13 L. Boeri , J. S. Kim , M. Giantomassi , F. S. Razavi , S. Kuroiwa , J. Akimitsu , R. K. Kremer

Novel superhard materials, especially those with superior thermal and chemical stability, are needed to replace diamond. Carbon nitrides (C-N), which are likely to possess these charac- teristics and have even been expected to be harder…

Materials Science · Physics 2015-06-29 Huafeng Dong , Artem R. Oganov , Qiang Zhu , Guang-Rui Qian

Reducing the stabilization pressure of superhydrides represents one of the most important challenges in hydrogen-saturated compound chemistry. Moving in this direction, we studied the Ba-Si-H system at 0-142 GPa using transport…

Diamond Si is a semiconductor with an indirect band gap that is the basis of modern semiconductor technology. Although many metastable forms of Si were observed using diamond anvil cells for compression and chemical precursors for…

Superconductivity · Physics 2018-04-18 Ha-Jun Sung , W. H. Han , In-Ho Lee , K. J. Chang

We present a structural analysis of the substituted system (Ba$_{1-x}$Sr$_{x}$)CuSi$_{2}$O$_{6}$, which reveals a stable tetragonal crystal structure down to 1.5 K. We explore the structural details with lowtemperature neutron and…

The relative stability of different high-pressure phases of various Cesium Halides is studied from first principles and analyzed using the Landau theory of phase transitions. We present results for CsI, CsBr, and CsCl up to pressures of…

Condensed Matter · Physics 2007-05-23 M. Buongiorno Nardelli , S. Baroni , P. Giannozzi

We investigate the evolution of the electrical resistivity of BaFe2As2 single crystals with pressure. The samples used were from the same batch grown from self flux and showed properties that were highly reproducible. Samples were…

Superconductivity · Physics 2015-05-14 W. J. Duncan , O. P. Welzel , C. Harrison , X. F. Wang , X. H. Chen , F. M. Grosche , P. G. Niklowitz

The high pressure structural properties of bismuth oxide Bi2SiO5 have been investigated up to 28 GPa using in situ powder synchrotron X-ray diffraction and up to 50 GPa with DFT calculations. The monoclinic structure is found to persist up…

First-order, rhombohedral to orthorhombic, stress-induced phase transitions have been evidenced by bulk charge-stress measurements and X-ray diffraction derived lattice strain measurements in [001]c-poled PZN-4.5PT. The transitions are…

Materials Science · Physics 2007-05-23 P. -E. Janolin , M. Davis , B. Dkhil , D. Damjanovic , N. Setter

Few-layer $\alpha$-In$_2$Se$_3$ has been studied under pressure using Raman spectroscopy in a diamond anvil cell up to 60 GPa (at room temperature). A combination of AFM and Raman was used to estimate the thickness of the specimens. While…

Materials Science · Physics 2025-09-25 Shiyu Feng , Anurag Ghosh , Gautham Vijayan , Ziyi Xu , Qian Zhang , Elad Koren , Elissaios Stavrou

Superconductivity owes its properties to the phase of the electron pair condensate that breaks the $U(1)$ symmetry. In the most traditional ground state, the phase is uniform and rigid. The normal state can be unstable towards special…

Superconductivity · Physics 2020-02-05 P. Holmvall , M. Fogelström , T. Löfwander , A. B. Vorontsov

We report simultaneous measurements of the magnetization and the ac susceptibility across the magnetic phase diagram of single-crystal MnSi. In our study we explore the importance of the excitation frequency, excitation amplitude, sample…

Strongly Correlated Electrons · Physics 2012-06-26 A. Bauer , C. Pfleiderer

A first-order-like resistivity hysteresis is induced by a subtle structural transition under hydrostatic pressure in the topological nodal-line superconductor PbTaSe$_2$. This structure transition is quickly suppressed to zero at pressure…

Superconductivity · Physics 2017-09-06 C. Q. Xu , R. Sankar , W. Zhou , Bin Li , Z. D. Han , B. Qian , J. H. Dai , Hengbo Cui , A. F. Bangura , F. C. Chou , Xiaofeng Xu

The Li$_2$S-P$_2$S$_5$ pseudo-binary system has been a valuable source of promising superionic conductors, with $\alpha$-Li$_3$PS$_4$, $\beta$-Li$_3$PS$_4$, HT-Li$_7$PS$_6$, and Li$_7$P$_3$S$_{11}$ having excellent room temperature Li-ion…

Materials Science · Physics 2023-07-04 Ronald L. Kam , KyuJung Jun , Luis Barroso-Luque , Julia H. Yang , Fengyu Xie , Gerbrand Ceder

Pressure-induced phase transformation occurs during silicon (Si) wafering processes. \b{eta}-tin (Si-II) phase is formed at high pressures, followed by the transformation to Si-XII, Si-III or/and amorphous Si ({\alpha}-Si) phases during the…

The phase diagram and equation of state of dense nitrogen are of interest in understanding the fundamental physics and chemistry under extreme conditions, including planetary processes, and in discovering new materials. We predict several…

Materials Science · Physics 2013-12-02 Jian Sun , Miguel Martinez-Canales , Dennis D. Klug , Chris J. Pickard , Richard J. Needs