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The experimental data on the thermal properties of the nanostructured perovskite ferroelectrics are presented and analysed. The ability of the modified 3w method for specific heat measurements is discussed and illustrated by the thermal…

Materials Science · Physics 2007-05-23 B. Strukov , S. Davitadze , V. Lemanov , S. Shulman , Y. Uesu , S. Asanuma

In recent years, Raman spectroscopy of two-dimensional (2D) materials has been conducted. However, only a small portion of those studies note the full width half maximum (FWHM) of these 2D materials. FWHM is an indicator of phonon…

Optics · Physics 2024-07-31 Elham Easy , Jeric Hernandez , Tseng-Ming Chou , Xian Zhang

We present a Raman spectroscopy investigation of the vibrational properties of L-histidine crystals at low temperatures. The temperature dependence of the spectra show discontinuities at 165 K, which we identify with modifications in the…

Chemical Physics · Physics 2015-06-15 G. P. De Sousa , P. T. C. Freire , J. Mendes Filho , F. E. A. Melo , C. L. Lima

Lead vanadate PbVO3 is a polar crystal with a P4mm space group at ambient conditions. It is isostructural with the model soft-mode driven ferroelectric PbTiO3, but differs from it by the so-called 'supertetragonal' elongation of its unit…

Materials Science · Physics 2022-11-30 Pierre Bouvier , Alireza Sasani , Eric Bousquet , Mael Guennou , Joaquim Agostinho Moreira

The correlated polar semimetal Ca$_3$Ru$_2$O$_7$ exhibits a rich phase diagram including two magnetic transitions ($T_N$=56 K and $T_C$=48 K) with the appearance of an insulating-like pseudogap (at $T_C$). In addition, there is a crossover…

Synthetic powder, ore samples and mineral single crystals of goethite ($\alpha-$FeOOH) were investigated with polarized Raman spectroscopy at temperatures from 300 K to 473 K. The symmetry of the vibrational modes, observed in different…

Materials Science · Physics 2020-06-24 M. V. Abrashev , V. G. Ivanov , B. S. Stefanov , N. D. Todorov , J. Rosell , V. Skumryev

Raman studies of nanocomposite SiCN thin film by sputtering showed that with an increase of substrate temperature from room temperature to 500oC, a transition from mostly sp2 graphitic phase to sp3 carbon took place which was observed from…

Materials Science · Physics 2016-11-24 A. S. Bhattacharyya , S. K. Mishra

We study superradiant Raman scattering from an ultra-cold, but finite temperature Bose gas in a harmonic trap. Numerical simulations indicate the existence of distinct timescales associated with the decoherence of the condensed versus…

Atomic Physics · Physics 2009-11-13 H. Uys , P. Meystre

Molybdenum sulfides are in the spotlight of materials science thanks to their interesting properties for applications in optoelectronics, nanocomposites, lubricants, and catalysis. The structural characterization of Molybdenum sulfides is a…

Materials Science · Physics 2026-04-10 Samuel Longo , Aloïs Castellano , Matthieu J. Verstraete

Raman spectroscopy is a widely used experimental technique to study the vibrational properties of solids. Atomic scale simulations can be used to predict such spectra, but trustworthy studies at finite temperatures are challenging, mainly…

Materials Science · Physics 2025-09-03 Petter Rosander , Erik Fransson , Nicklas Österbacka , Paul Erhart , Göran Wahnström

Electronic structure and optical band gap of CoFe2O4 thin films grown on (001) oriented LaAlO3 have been investigated. Surprisingly, these films show additional Raman modes at room temperature as compared to a bulk spinel structure. The…

Materials Science · Physics 2015-06-11 A. V. Ravindra , P. Padhan , W. Prellier

Orhorhombic $\alpha$-MoO$_3$ is a layered oxide with various applications and with excellent potential to be exfoliated as a 2D ultrathin film or monolayer. In this paper, we present a first-principles computational study of its vibrational…

Materials Science · Physics 2021-09-20 Amol Ratnaparkhe , Santosh Kumar Radha , Walter R. L. Lambrecht

We have performed for the first time micro-Raman studies of lysozyme crystals for the temperatures lower than the room one (in the range 282-300K). Anomalous temperature dependence of the positions of Raman scattering bands has been…

Soft Condensed Matter · Physics 2007-06-29 Yu. Vasylkiv , M. Polomska , Yu. Nastishin , R. Vlokh

Temperature influences the performance of two-dimensional materials in optoelectronic devices. Indeed, the optical characterization of these materials is usually realized at room temperature. Nevertheless most {\it ab-initio} studies are…

Mesoscale and Nanoscale Physics · Physics 2016-06-06 Alejandro Molina-Sánchez , Maurizia Palummo , Andrea Marini , Ludger Wirtz

We have found that the polarization dependence of Raman scattering in organic crystals at finite temperatures can only be described by a fourth-rank formalism. This generalization of the second-rank Raman tensor $\mathcal{R}$ stems from the…

Room-temperature Raman scattering has been measured in barium tungstate (BaWO4) up to 16 GPa. We report the pressure dependence of all the Raman-active first-order phonons of the tetragonal scheelite phase (BaWO4-I, space group I41/a),…

We investigate temperature-dependent resonance fluorescence spectra obtained from a single self-assembled quantum dot. A decrease of the Mollow triplet sideband splitting is observed with increasing temperature, an effect we attribute to a…

Mesoscale and Nanoscale Physics · Physics 2014-09-18 Yu-Jia Wei , Yu He , Yu-Ming He , Chao-Yang Lu , Jian-Wei Pan , Christian Schneider , Martin Kamp , Sven Höfling , Dara P. S. McCutcheon , Ahsan Nazir

We investigate the vibrational properties and Raman spectra of two-dimensional Ga$_2$O$_3$ monolayer, using density functional theory. Two ferroelectric (FE) phases of Ga$_2$O$_3$ monolayer with wurtzite(WZ) and zincblende(ZB) structures(…

Materials Science · Physics 2022-05-18 Zexiang Deng

A vast amount of Raman spectroscopic data, obtained using diamond anvil cell technique under in situ high pressure-temperature conditions, has been used for mapping the phase transitions of hydrogen in the temperature range of 300 K to 900…

Materials Science · Physics 2022-01-19 Chang-Sheng Zha , Hanyu Liu , Zhongwu Wang , William A. Bassett

A prominent band centered at around 1000-1300 cm-1 and associated with resonant enhancement of two-phonon Raman scattering is reported in multiferroic BiFeO3 thin films and single crystals. A strong anomaly in this band occurs at the…

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