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Ab initio determination of model Hamiltonian parameters for strongly correlated materials is a key issue in applying many-particle theoretical tools to real narrow-band materials. We propose a self-contained calculation scheme to construct,…

Strongly Correlated Electrons · Physics 2008-09-09 Dm. Korotin , A. V. Kozhevnikov , S. L. Skornyakov , I. Leonov , N. Binggeli , V. I. Anisimov , G. Trimarchi

The Empirical Tight Binding(ETB) method is widely used in atomistic device simulations. The reliability of such simulations depends very strongly on the choice of basis sets and the ETB parameters. The traditional way of obtaining the ETB…

We provide a methodology to understand materials with complex bonding patterns, and apply it to the example of heteroanionic and lone pair materials. We build a tight-binding model based on Wannier functions fitted on density functional…

Materials Science · Physics 2024-10-28 Emily G. Ward , Alexandru B. Georgescu

We investigate the feasability of improving the semi-empirical density functional based tight-binding method (DFTB) through a general and transferable many-body repulsive potential for pure silicon using a common machine-learning framework.…

Materials Science · Physics 2022-02-23 Dylan Bissuel , Tristan Albaret , Thomas A. Niehaus

In this paper we present an accurate numerical scheme for extracting inter-atomic exchange parameters ($J_{ij}$) of strongly correlated systems, based on first-principles full-potential electronic structure theory. The electronic structure…

Strongly Correlated Electrons · Physics 2015-03-11 Y. O. Kvashnin , O. Grånäs , I. Di Marco , M. I. Katsnelson , A. I. Lichtenstein , O. Eriksson

In this work, transferable empirical tight binding parameters of strained group IV and III-V semiconductors are generated from ab-initio calculations. The empirical tight binding parameters show good transferability when applied to strained…

Materials Science · Physics 2015-04-28 Yaohua P. Tan , Michael Povolotskyi , Tillmann Kubis , Timothy B. Boykin , Gerhard Klimeck

A novel efficient method to calculate the scattering matrix (SM) of arbitrary tight-binding Hamiltonians is proposed, including cases with multiterminal structures. In particular, the SM of two kind of fundamental structures are given,…

Mesoscale and Nanoscale Physics · Physics 2020-03-11 Carlos Ramirez , Luis A. Medina-Amayo

We present a tight-binding parametrization for penta-graphene that correctly describes its electronic band structure and linear optical response. The set of parameters is validated by comparing to ab-initio density functional theory…

Materials Science · Physics 2020-12-25 Sergio Bravo , J. D. Correa , Leonor Chico , M. Pacheco

We present a simple implementation of the dynamical mean-field theory approach to the electronic structure of strongly correlated materials. This implementation achieves full self-consistency over the charge density, taking into account…

Strongly Correlated Electrons · Physics 2009-11-13 L. V. Pourovskii , B. Amadon , S. Biermann , A. Georges

We analyze the electronic structure of group II-VI semiconductors obtained within LMTO approach in order to arrive at a realistic and minimal tight binding model, parameterized to provide an accurate description of both valence and…

Materials Science · Physics 2009-11-10 Sameer Sapra , N. Shanthi , D. D. Sarma

We present a Mathematica program package MagneticTB, which can generate the tight-binding model for arbitrary magnetic space group. The only input parameters in MagneticTB are the (magnetic) space group number and the orbital information in…

Materials Science · Physics 2022-01-25 Zeying Zhang , Zhi-Ming Yu , Gui-Bin Liu , Yugui Yao

\textit{Ab initio} pseudo-atomic orbital (PAO) Hamiltonians express the electronic structure of a solid in a compact, localized basis that spans the same Hilbert space as a conventional Slater--Koster tight-binding model, thereby providing…

Materials Science · Physics 2026-04-17 Marco Buongiorno Nardelli

An empirical $s_cp^3_a$ tight-binding (TB) model is applied to the investigation of electronic states in semiconductor quantum dots. A basis set of three $p$-orbitals at the anions and one $s$-orbital at the cations is chosen. Matrix…

Other Condensed Matter · Physics 2009-11-11 Stefan Schulz , Gerd Czycholl

A mixed basis all-electron full-potential method, which uses two kinds of augmented waves, the augmented plane waves and the muffin-tin orbitals simultaneously, in addition to the local orbitals, was proposed by Kotani and van Schilfgaarde…

Materials Science · Physics 2015-02-10 Takao Kotani , Hiori Kino , Hisazumi Akai

Hexagonal boron nitride ($\it h$-BN) exhibits dominant $\pi$-bands near the Fermi level, similar to graphene. However, unlike graphene, where tight-binding (TB) models accurately reproduce band edges near the $K$ and $K^{\prime}$ points in…

Materials Science · Physics 2024-09-04 Srivani Javvaji , Fengping Li , Jeil Jung

We report results from a fast, efficient, and first-principles full-potential N$^{th}$-order muffin-tin orbital (FP-NMTO) method combined with van Leeuwen-Baerends correction to local density exchange-correlation potential. We show that…

Motivated by the recent experimental determination of the three-dimensional Fermi surface of overdoped La-based cuprate superconductors [Horio et al., Phys. Rev. Lett. 2018, 121, 077004], we revisit the tight-binding parameterization of…

Superconductivity · Physics 2019-10-30 Raphaël Photopoulos , Raymond Frésard

Materials with optimized band gap are needed in many specialized applications. In this work, we demonstrate that Hellmann-Feynman forces associated with the gap states can be used to find atomic coordinates with a desired electronic density…

Materials Science · Physics 2015-06-16 Kiran Prasai , Parthapratim Biswas , D. A. Drabold

A new method for calculating the total energy of Si systems is presented. The method is based on the effective-medium theory concept of a reference system. Instead of calculating the energy of an atom in the system of interest a reference…

Condensed Matter · Physics 2016-08-14 K. Stokbro , N. Chetty , K. W. Jacobsen , J. K. Nørskov

The microstructure of the Ti-Al binary system is an area of great interest as it affects material properties and plasticity. Phase transformations induce microstructural changes; therefore, accurately modeling the phase transformations of…

Materials Science · Physics 2024-11-13 Micah Nichols , Christopher D. Barrett , Doyl E. Dickel , Mashroor S. Nitol , Saryu J. Fensin