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The formal link between the linear combination of atomic orbitals approach to density functional theory and two-center Slater-Koster tight-binding models is used to derive an orthogonal $d$-band tight-binding model for iron with only two…

Materials Science · Physics 2015-03-19 Georg K. H. Madsen , Eunan J. McEniry , Ralf Drautz

Conventional photoemission orbital tomography based on Fourier iterative method enables us to extract a projected two-dimensional (2D) molecular orbital from a 2D photoelectron momentum map (PMM) of planar $\pi$-conjugated molecules in a…

Materials Science · Physics 2024-03-01 Misa Nozaki , Takehisa Konishi

We present optimized tight-binding models with atomic orbitals to improve \textit{ab initio} tight-binding models constructed by truncating full density functional theory (DFT) Hamiltonian based on localized orbitals. Retaining qualitative…

Mesoscale and Nanoscale Physics · Physics 2024-02-20 Sejoong Kim

We discuss how to construct tight-binding models for ultra cold atoms in honeycomb potentials, by means of the maximally localized Wannier functions (MLWFs) for composite bands introduced by Marzari and Vanderbilt [1]. In particular, we…

Moir\'e superlattices have emerged as a versatile platform for exploring a wide range of ex- otic quantum phenomena. Unlike angstrom-scale materials, the moir\'e length-scale system contains a large number of atoms, and its electronic…

Materials Science · Physics 2025-11-10 Xueheng Kuang , Federico Escudero , Pierre A. Pantaleón , Francisco Guinea , Zhen Zhan

Using the recently developed Nth-order muffin-tin-orbital (NMTO) based downfolding technique we revisit the electronic properties of half-metallic ferromagnets, the semi-Heusler NiMnSb and rutile CrO2. The NMTO Wannier orbitals for the Mn-d…

Strongly Correlated Electrons · Physics 2007-05-23 A. Yamasaki , L. Chioncel , A. I. Lichtenstein , O. K. Andersen

We obtain parameters for non-orthogonal and orthogonal TB models from two-atomic molecules for all combinations of elements of period 1 to 6 and group 3 to 18 of the periodic table. The TB bond parameters for 1711 homoatomic and…

Materials Science · Physics 2021-02-17 Jan Jenke , Alvin N. Ladines , Thomas Hammerschmidt , David G. Pettifor , Ralf Drautz

Empirical tight binding(ETB) methods are widely used in atomistic device simulations. Traditional ways of generating the ETB parameters rely on direct fitting to bulk experiments or theoretical electronic bands. However, ETB calculations…

Materials Science · Physics 2015-08-12 Yaohua P. Tan , Michael Povolotsky , Tillmann Kubis , Timothy B. Boykin , Gerhard Klimeck

This paper advocates for an innovative approach designed for estimating optoelectronic properties of quantum structures utilizing Tight-Binding (TB) theory. Predicated on the comparative analysis between estimated and actual properties, the…

Quantum Physics · Physics 2024-08-30 Ali Haji Ebrahim Zargar , Ali Amini , Ahmad Ayatollahi

A multiband empirical tight-binding model for group-III-nitride semiconductors with a wurtzite structure has been developed and applied to both bulk systems and embedded quantum dots. As a minimal basis set we assume one s-orbital and three…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Daniel Mourad , Stefan Barthel , Gerd Czycholl

We extend a tight-binding method to include the effects of spin-orbit coupling, and apply it to the study of the electronic properties of the actinide elements Th, U, and Pu. These tight-binding parameters are determined for the fcc crystal…

Materials Science · Physics 2013-05-29 M. D. Jones , R. C. Albers

We present PYATB, a Python package designed for computing band structures and related properties of materials using the ab initio tight-binding Hamiltonian. The Hamiltonian is directly obtained after conducting self-consistent calculations…

Materials Science · Physics 2023-08-09 Gan Jin , ongsheng Pang , Yuyang Ji , Zujian Dai , Lixin He

The magnetic and surface properties of some transition metals have been investigated within the tight-binding approximation, including Coulomb correlations. These surface properties are calculated after applying a charge neutrality rule…

Materials Science · Physics 2025-08-05 Jacques R. Eone

The most popular electronic structure method, the linear muffin-tin orbital method (LMTO), in its full-potential (FP) and relativistic forms has been extended to calculate the spectroscopic properties of materials form first principles,…

Materials Science · Physics 2007-05-23 M. Alouani , J. M. Wills

Accurate modeling of electronic properties of nanostructures is a challenging theoretical problem. Methods making use of continuous media approximation, such as k.p, sometimes struggle to reproduce results obtained with more accurate…

Mesoscale and Nanoscale Physics · Physics 2019-10-16 Krzysztof Gawarecki , Michał Zieliński

A computer program LMTART for electronic structure calculations using full potential linear muffin-tin orbital method is described

Materials Science · Physics 2007-05-23 S. Y. Savrasov

We propose a simple and effective approach to construct the empirical tight-binding parameters of ternary alloys in the virtual crystal approximation. This combines a new, compact formulation of the strain parameters and a linear…

Mesoscale and Nanoscale Physics · Physics 2016-06-27 M. O. Nestoklon , R. Benchamekh , P. Voisin

A recent tight-binding scheme provides a method for extending the results of first principles calculations to regimes involving $10^2 - 10^3$ atoms in a unit cell. The method uses an analytic set of two-center, non-orthogonal tight-binding…

mtrl-th · Physics 2008-02-03 Michael J. Mehl , Dimitrios A. Papaconstantopoulos

We investigate electron correlation effects in stoichiometric Titanium Nitride (TiN) using a combination of electronic structure and many-body calculations. In a first step, the Nth-order muffin tin orbital technique is used to obtain…

Strongly Correlated Electrons · Physics 2015-05-13 H. Allmaier , L. Chioncel , E. Arrigoni

A general-purpose Density Functional Tight Binding method, the GFN-xTB model is gaining increased popularity in accurate simulations that are out of scope for conventional ab initio formalisms. We show that in its original GFN1-xTB…

Chemical Physics · Physics 2021-12-14 Leonid Komissarov , Toon Verstraelen