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We introduce a new form of density functional theory for the {\em ab initio} description of electronic systems in contact with a molecular liquid environment. This theory rigorously joins an electron density-functional for the electrons of…

Soft Condensed Matter · Physics 2009-11-11 Sahak Petrosyan , Jean-Francois Briere , David Roundy , T. A. Arias

We introduce a novel energy functional for ground-state electronic-structure calculations. Its fundamental variables are the natural spin-orbitals of the implied singlet many-body wave function and their joint occupation probabilities. The…

Chemical Physics · Physics 2015-06-23 Ralph Gebauer , Morrel H. Cohen , Roberto Car

Model-independent identities and inequalities relating the various spin observables of a reaction are reviewed in a unified formalism, together with their implications for dynamical models, their physical interpretation, and the quantum…

High Energy Physics - Phenomenology · Physics 2009-01-14 Xavier Artru , Mokhtar Elchikh , Jean-Marc Richard , Jacques Soffer , Oleg V. Teryaev

We present and discuss some ideas concerning an ``average-pair-density functional theory'', in which the ground-state energy of a many-electron system is rewritten as a functional of the spherically and system-averaged pair density. These…

Materials Science · Physics 2009-11-11 Paola Gori-Giorgi , Andreas Savin

We introduce an energy functional for ground-state electronic structure calculations. Its variables are the natural spin-orbitals of singlet many-body wave functions and their joint occupation probabilities deriving from controlled…

Chemical Physics · Physics 2016-12-04 Ralph Gebauer , Morrel H. Cohen , Roberto Car

Two forms of relativistic density functional are derived from Dirac equation. Based on their structure analysis model of split electron is proposed. In this model electric charge and mass of electron behave like two point-like particles. It…

Quantum Physics · Physics 2015-05-29 Kirill Koshelev

Different bases for the spin-1 density matrix are discussed to clarify the connection between its components and observables measured in heavy-ion collisions. The theoretical advantage of using the adjoint representation for spin matrices…

Nuclear Theory · Physics 2026-02-03 Wojciech Florkowski , Sudip Kumar Kar , Valeriya Mykhaylova

Based on our derivation of finite temperature reduced density matrix functional theory and the discussion of the performance of its first-order functional this work presents several different correlation-energy functionals and applies them…

Other Condensed Matter · Physics 2012-08-24 Tim Baldsiefen , E. K. U. Gross

We probe for statistical and Coulomb induced spin textures among the low-lying states of repulsively-interacting particles confined to potentials that are both rotationally and time-reversal invariant. In particular, we focus on…

Mesoscale and Nanoscale Physics · Physics 2011-03-08 Catherine J. Stevenson , Jordan Kyriakidis

We develop a bottom-up formulation of spin-kinetic theory for hot and/or dense plasmas. We introduce scalar and axial-vector phase-space functions as dynamical variables that parametrize both spin-averaged and spin-dependent distribution…

Nuclear Theory · Physics 2026-01-21 Zonglin Mo , Yi Yin

A bivariate perspective on Kohn-Sham density functional theory is proposed, treating potential and density as simultaneous independent variables, and used to make fruitful connection between Lieb's rigorous foundational framework and…

Materials Science · Physics 2020-07-07 Paul E. Lammert

Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

It has been known for some time that the exchange-correlation potential in time-dependent density functional theory is an intrinsically nonlocal functional of the density as soon as one goes beyond the adiabatic approximation. In this paper…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Z. Qian , A. Constantinescu , G. Vignale

A hard sphere fluid confined by hard, structureless, and parallel walls is investigated using a certain version of weighted density functional theory. The density profile, the excess coverage, the finite size contribution to the free…

Statistical Mechanics · Physics 2008-02-03 B. Gotzelmann , S. Dietrich

The spin-spin correlation function of the spherical model being precisely at an anisotropic Lifshitz point of arbitrary order is calculated exactly. The results are in agreement with scaling. The scaling function is shown to be universal.…

Condensed Matter · Physics 2011-09-26 Laurent Frachebourg , Malte Henkel

Density Functional Theory relies on universal functionals characteristic of a given system. Those functionals in general are different for the electron gas and for jellium (electron gas with uniform background). However, jellium is…

Statistical Mechanics · Physics 2017-05-23 James W. Dufty

We discuss energy densities in the strong-interaction limit of density functional theory, deriving an exact expression within the definition (gauge) of the electrostatic potential of the exchange-correlation hole. Exact results for small…

Chemical Physics · Physics 2012-11-14 André Mirtschink , Michael Seidl , Paola Gori-Giorgi

A class of generalized non-minimal coupling theories is investigated, in search of scaling attractors able to provide an accelerated expansion at the present time. Solutions are found in the strong coupling regime and when the coupling…

Astrophysics · Physics 2008-11-26 Luca Amendola

Given a vector space of microscopic quantum observables, density functional theory is formulated on its dual space. A generalized Hohenberg-Kohn theorem and the existence of the universal energy functional in the dual space are proven. In…

Nuclear Theory · Physics 2009-09-25 G. Rosensteel , Ts. Dankova

We compute the entanglement between separated blocks in certain spin models showing that at criticality this entanglement is a function of the ratio of the separation to the length of the blocks and can be written as a product of a power…

Quantum Physics · Physics 2009-08-05 H. Wichterich , J. Molina-Vilaplana , S. Bose