Related papers: The second phase transition in the pyrochlore oxid…
We report on the structural and superconducting properties of the intermetallic compound BaGaGe. We find that this material undergoes a structural second-order phase transition from the distorted AlB$_2$-type structure (1H, $a$ = 4.3254(2)…
Pressure not only provides a powerful way to tune the crystal structure of transition metal dichalcogenides (TMDCs) but also promotes the discovery of exotic electronic states and intriguing phenomena. Structural transitions from the…
The interplay of charge, spin, and lattice degrees of freedom in matter leads to various forms of ordered states through phase transitions. An important subclass of these phenomena of complex materials is charge ordering (CO), mainly driven…
Single crystals of Bi$_{2} $Rh$ _{3}$S$ _{2}$ and Bi$_{2} $Rh$ _{3.5}$S$ _{2}$ were synthesized by solution growth and the crystal structures, thermodynamic and transport properties of both compounds were studied. In the case of Bi$_{2}…
Beginning in 1973, several non-cuprate transition metal and non-transition metal oxides were discovered with superconducting transition temperatures between 10 and 30 K. Retrospectives about these discoveries in spinel structure LiTi2O4 and…
We address the concomitant metal-insulator transition (MIT) and antiferromagnetic ordering in the novel pyrochlore iridate Eu2Ir2O7 by combining x-ray absorption spectroscopy, x-ray and neutron diffractions and density functional theory…
We report the synthesis and structural study of mixed oxides in the Ln2ScNbO7 series. New phases with Ln = Pr, Eu, Gd and Dy are obtained. All crystallize in the cubic pyrochlore structure type, space group F-d3m, with no Sc-Nb ordering on…
The temperature dependence of the ac susceptibility for single-crystalline Fe1.02Se has been measured at high pressures to 6.7 GPa. The superconducting transition temperature Tc displays a large increase from 7 K to 30 K in the two-phase…
The electronic phase diagram of PrFeAsO$_{1-x}$F$_{x}$ (0$\leq$x$\leq$0.225) has been determined using synchrotron X-ray powder diffraction, magnetization and resistivity measurements. The structural transition temperature is suppressed…
A2Ir2O7 iridates were proven to crystallise in the geometrically frustrated pyrochlore structure, which remains stable upon rare-earth cation substitution, temperature variation, and external pressure application. However, the change of…
Heat capacity, magnetic susceptibility, NMR, and resistivity of SrNi2P2 single crystals are presented, illustrating a purely structural transition at 325 K with no magnetism. Bulk superconductivity is found at 1.4 K. The magnitude of the…
We present optical conductivity spectra for $Pb_{2}Ru_{2}O_{7-{\delta}}$ single crystal at different temperatures. Among reported pyrochlore ruthenates, this compound exhibits metallic behavior in a wide temperature range and has the least…
In CsW2O6, which undergoes a metal-insulator transition (MIT) at 213 K, the emergence of exotic properties associated with rattling motion of Cs is expected owing to its characteristic \beta-pyrochlore-type structure. However, a hurdle for…
Optical conductivity spectra of cubic pyrochlore $Y_{2-x} Bi_x Ru_2 O_7$ (0.0$\leq ${\it x}$\leq $2.0) compounds are investigated. As a metal-insulator transition (MIT) occurs around {\it x}$=$0.8, large spectral changes are observed. With…
The magnitude and the temperature dependence of the superconducting order parameter {\Delta}(T) of single-crystals of Cd2Re2O7 (Tc = 1.02 K) was measured using point contact spectroscopy. In order to fit the conductance spectra and to…
The recent discovery of high-temperature superconductivity in the Ruddlesden-Popper phase La3Ni2O7 under high pressure marks a significant breakthrough in the field of 3d transition-metal oxide superconductors. For an emerging novel class…
Compounds of series YBa2Cu3O7-d (d = 0.7), being synthesized by solid-state synthesis route with x = 0.0, 0.10, 0.15 and 0.20, crystallize in single-phase form with tetragonal structure (space group P4/mmm). The c-lattice parameter…
1T'-TaTe2 exhibits an intriguing first-order structural phase transition at around 170 K. Understanding the electronic structural properties is a crucial way to comprehend the origin of the structural phase transition. We performed a…
The observation of superconductivity at 4.3 K in a new crystalline form of Na0.3CoO2*1.3H2O is reported. The new superconductor has three layers of CoO6 octahedra per crystallographic unit cell, in contrast to the previously reported…
Multicontact configuration is one of the most powerful arrangements for electrical transport measurements applied to study vortex phase transition and vortex phase dimensionality in strongly anisotropic high-Tc superconducting materials. In…