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In this paper, we follow the general idea of the Onsager--Wilson theory of strong binary electrolyte solutions and completely calculate the velocity profile of ionic flow by first formally solving the hydrodynamic (Stokes) equation for the…

Chemical Physics · Physics 2010-11-25 Byung Chan Eu , Kyunil Rah

We study the thermodynamics of binary mixtures with the volume fraction of the minority component less than the amount required to form a flat interface and show that the surface tension dominated equilibrium phase of the mixture forms a…

Soft Condensed Matter · Physics 2023-03-07 Subhadip Biswas , Biswaroop Mukherjee , Buddhapriya Chakrabarti

Wetting phenomena, molecular protrusions of lipid bilayers and membrane stacks under lateral tension provide physical examples for interacting surfaces with tension. Such surfaces are studied theoretically using functional renormalization…

Statistical Mechanics · Physics 2009-10-31 A. Volmer , U. Seifert , R. Lipowsky

This paper explores the friction forces encountered by droplets on non-wetting surfaces, specifically focusing on superhydrophobic and superheated substrates. Employing a combination of experimental techniques, including inclined plane…

We introduce fluctuating hydrodynamics approaches on surfaces for capturing the drift-diffusion dynamics of particles and microstructures immersed within curved fluid interfaces of spherical shape. We take into account the interfacial…

Soft Condensed Matter · Physics 2023-10-24 David Rower , Misha Padidar , Paul J. Atzberger

A mean-field density-functional model for three-phase equilibria in fluids (or other soft condensed matter) with two spatially varying densities is analyzed analytically and numerically. The interfacial tension between any two out of three…

Statistical Mechanics · Physics 2019-08-14 Kenichiro Koga , Joseph O. Indekeu

The statistical mechanics of equilibrium interfaces has been well-established for over a half century. In the last decade, a wealth of observations have made increasingly clear that a new perspective is required to describe interfaces…

Soft Condensed Matter · Physics 2025-04-21 Luke Langford , Ahmad K. Omar

The application of the Young-Laplace equation to a solid-liquid interface is considered. Computer simulations show that the pressure inside a solid cluster of hard spheres is smaller than the external pressure of the liquid (both for small…

Soft Condensed Matter · Physics 2024-01-24 P. Montero de Hijes , K. Shi , E. G. Noya , E. E. Santiso , K. E. Gubbins , E. Sanz , C. Vega

Using the integral transformation, the field-theoretical Hamiltonian of the statistical field theory of fluids is obtained, along with the microscopic expressions for the coefficients of the Hamiltonian. Applying this approach to the…

Statistical Mechanics · Physics 2020-05-06 Nikolai V. Brilliantov , J. Miguel Rubi , Yury A. Budkov

The idea of working with a near-critical phase-separated liquid mixture whereby the surface tension becomes weak, has recently made the field of laser manipulation of liquid interfaces a much more convenient tool in practice. The…

Optics · Physics 2009-11-10 Aslak Hallanger , Iver Brevik , Skjalg Haaland , Roger Sollie

The objective of this work is to investigate the coupling of fluid dynamics, heat transfer and mass transfer during the impact and evaporation of droplets on a heated solid substrate. A laser-based thermoreflectance method is used to…

Fluid Dynamics · Physics 2010-10-14 Rajneesh Bhardwaj , Jon P. Longtin , Daniel Attinger

We present an approach to theoretical assessment of the mean specific interface area $(\delta{S}/\delta{V})$ for a well-stirred system of two immiscible liquids experiencing interfacial boiling. The assessment is based on the balance of…

Statistical Mechanics · Physics 2017-05-03 Denis S. Goldobin , Anastasiya V. Pimenova

The equilibrium contact angle of a droplet resting on a solid substrate can reveal essential properties of the solid's surface. However, when the motion of a droplet on a surface shows significant hysteresis, it is generally accepted that…

Soft Condensed Matter · Physics 2021-07-14 Jin Young Kim , Stefanie Heyden , Dominic Gerber , Nicolas Bain , Eric R. Dufresne , Robert W. Style

In the last decade, there has been a surge of experiments showing that certain chemical reactions undergo an enormous boost when taken from bulk aqueous conditions to microdroplet environments. The microscopic basis of this phenomenon…

The problem presented involves the development of a new analytical model for the general fluid-solid temperature jump. To the best of our knowledge, there are no analytical models that provide the accurate predictions of the temperature…

Soft Condensed Matter · Physics 2016-12-26 Jian-Jun Shu , Ji Bin Melvin Teo , Weng Kong Chan

We briefly review the effects of selective solvation of ions in aqueous mixtures, where the ion densities and the composition fluctuations are strongly coupled. We then examine the surface tension \gamma of a liquid-liquid interface in the…

Soft Condensed Matter · Physics 2015-06-04 Akira Onuki , Takeaki Araki

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

Soft Condensed Matter · Physics 2022-07-13 J. Pedro de Souza , Alexei A. Kornyshev , Martin Z. Bazant

Surface tension plays a ubiquitous role in phase transitions including condensation or evaporation of atmospheric liquid droplets. Especially, understanding of interfacial thermodynamics of the critical nucleus of 1 nm scale is important…

Soft Condensed Matter · Physics 2020-04-28 QHwan Kim , Wonho Jhe

We study the effective forces acting between colloidal particles trapped at a fluid interface which itself is exposed to a pressure field. To this end we apply what we call the ``force approach'', which relies solely on the condition of…

Soft Condensed Matter · Physics 2008-03-31 Alvaro Dominguez , Martin Oettel , Siegfried Dietrich

The hydrodynamics for a gas of hard-spheres which sometimes experience inelastic collisions resulting in the loss of a fixed, velocity-independent, amount of energy $\Delta $ is investigated with the goal of understanding the coupling…

Soft Condensed Matter · Physics 2007-05-23 James F. Lutsko