Molecular fields and statistical field theory of fluids. Application to interface phenomena
Abstract
Using the integral transformation, the field-theoretical Hamiltonian of the statistical field theory of fluids is obtained, along with the microscopic expressions for the coefficients of the Hamiltonian. Applying this approach to the liquid-vapor interface, we derive an explicit analytical expression for the surface tension in terms of temperature, density and parameters of inter-molecular potential. We also demonstrate that a clear physical interpretation may be given to the formal statistical field arising in the integral transformation - it may be associated with the one-body local microscopic potential. The results of the theory, lacking any ad-hoc or fitting parameters are in a good agreement with available simulation data.
Cite
@article{arxiv.2004.00283,
title = {Molecular fields and statistical field theory of fluids. Application to interface phenomena},
author = {Nikolai V. Brilliantov and J. Miguel Rubi and Yury A. Budkov},
journal= {arXiv preprint arXiv:2004.00283},
year = {2020}
}
Comments
Accepted for publication in Phys. Rev. E