Statistical field theory for liquid vapor interface
Statistical Mechanics
2012-07-02 v1
Abstract
A statistical field theory for an inhomogeneous liquid, a planar liquid/vapor interface, is devised from first principles. The grand canonical partition function is represented via a Hubbard-Stratonovitch tranformation leading, close to the critical point, to the usual scalar field theory which is then rigorously considered at the one-loop level. When further simplified it yields the well-known capillary wave theory without any ad hoc phenomenological parameter. Internal coherence of the one-loop approximation is discussed and good overall qualitative agreement with recent numerical simulations is stressed.
Cite
@article{arxiv.0911.5275,
title = {Statistical field theory for liquid vapor interface},
author = {V. Russier and Jean-Michel Caillol},
journal= {arXiv preprint arXiv:0911.5275},
year = {2012}
}
Comments
20 pages, 2 figures