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Conductance measurements of a molecular wire, contacted between an epitaxial molecule-metal bond and the tip of a scanning tunneling microscope, are reported. Controlled retraction of the tip gradually de-hybridizes the molecule from the…

Strongly Correlated Electrons · Physics 2024-02-05 R. Temirov , A. C. Lassise , F. Anders , F. S. Tautz

Experiments studying vibrational effects on electronic transport through single molecules have observed several seemingly inconsistent behaviors, ranging from up to 30 harmonics of a vibrational frequency in one experiment, to an absence of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Vivek Aji , J. E. Moore , C. M. Varma

We analyze non-equilibrium current transport in molecular electronic devices, using as an example devices formed by two terphenyl dithiol molecules attached to gold electrodes. Using a first-principles based self-consistent matrix Green's…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

Electrical and thermal transport properties of C60 molecules are investigated with density-functional-theory based calculations. These calculations suggest that the optimum contact geometry for an electrode terminated with a single-Au atom…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 G. Géranton , C. Seiler , A. Bagrets , L. Venkataraman , F. Evers

Monte Carlo simulations and an analytical approach within the framework of a semiclassical model are presented which permit the determination of Coulomb blockade and single electron charging effects for multiple tunnel junctions coupled in…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 U. E. Volmar , U. Weber , R. Houbertz , U. Hartmann

The characteristics of molecular electronic devices are critically determined by metal-organic interfaces, which influence the arrangement of the orbital levels that participate in charge transport. Studies on self-assembled monolayers…

We investigate the origin of asymmetry in various measured current-voltage (I-V) characteristics of molecules with no inherent spatial asymmetry, with particular focus on a recent break junction measurement. We argue that such asymmetry…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 F. Zahid , A. W. Ghosh , M. Paulsson , E. Polizzi , S. Datta

Electronegativity is shown to control charge transfer, energy level alignments, and electron currents in single molecule tunnel junctions, all of which are governed by correlations contained within the density matrix. This is demonstrated…

Mesoscale and Nanoscale Physics · Physics 2007-10-30 R. J. Bartlett , G. Fagas , J. C. Greer

We investigate thermally-driven transport of heat and charge in a superconducting single-electron transistor by means of a real-time diagrammatic transport theory. Our theoretical approach allows us to account for strong Coulomb…

Mesoscale and Nanoscale Physics · Physics 2021-12-01 Alexander G. Bauer , Björn Sothmann

The rational design of single molecule electrical components requires a deep and predictive understanding of structure-function relationships. Here we explore the relationship between chemical substituents and the conductance of…

Electronic transport characteristics through a single phenalenyl molecule sandwiched between two metallic electrodes are investigated by the use of Green's function technique. A parametric approach, based on the tight-binding model, is used…

Mesoscale and Nanoscale Physics · Physics 2009-11-06 Santanu K. Maiti

Single-molecule junctions represent electromechanical systems at the edge of device miniaturization. Despite extensive studies on the interplay between mechanical manipulation and electron transport in molecular junctions, a thorough…

It is shown that at low temperatures and moderate electron dephasing the electron transmission function reveales a structure containing information about donor/acceptor sites effectively participating in the electron transfer (ET) processes…

Biological Physics · Physics 2007-05-23 Natalya A. Zimbovskaya

We present a self-consistent method for the evaluation of the electronic current flowing through a multi-terminal molecular wire. The method is based on Buttiker- Landauer theory which relates the current to one-electron scattering…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Eldon G. Emberly , George Kirczenow

We present a theoretical analysis aimed at understanding electrical conduction in molecular tunnel junctions. We focus on discussing the validity of coherent versus incoherent theoretical formulations for single-level tunneling to explain…

Mesoscale and Nanoscale Physics · Physics 2016-06-06 Alvar R. Garrigues , Li Yuan , Lejia Wang , Eduardo R. Mucciolo , Damien Thompson , Enrique del Barco , Christian A. Nijhuis

A time-dependent approach is used to explore inelastic effects during electron transport through few-level systems. We study a tight-binding chain with one and two sites connected to vibrations. This simple but transparent model gives…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Monturet , N. Lorente

Electron transport experiments on two lateral quantum dots coupled in series are reviewed. An introduction to the charge stability diagram is given in terms of the electrochemical potentials of both dots. Resonant tunneling experiments show…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 W. G. van der Wiel , S. De Franceschi , J. M. Elzerman , T. Fujisawa , S. Tarucha , L. P. Kouwenhoven

Molecular electronic devices are the upmost destiny of the miniaturization trend of electronic components. Although not yet reproducible on large scale, molecular devices are since recently subject of intense studies both experimentally and…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. Cuniberti , F. Grossmann , R. Gutierrez

We study electron transport in polycyclic hydrocarbon molecules attached to two semi-infinite one-dimensional metallic electrodes by the use of Green's function formalism. Parametric calculations based on the tight-binding framework are…

Mesoscale and Nanoscale Physics · Physics 2009-11-06 Santanu K. Maiti

Strongly correlated physics arises from electron-electron scattering within partially filled orbitals. Organic molecules in open-shell configurations are therefore good candidates to exhibit many-body effects. We focus on electron transport…

Strongly Correlated Electrons · Physics 2025-11-14 G. Gandus , A. Jayaraj , D. Passerone , R. Stadler , M. Luisier , A. Valli
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