English

Electronegativity in quantum electronic transport

Mesoscale and Nanoscale Physics 2007-10-30 v1 Materials Science

Abstract

Electronegativity is shown to control charge transfer, energy level alignments, and electron currents in single molecule tunnel junctions, all of which are governed by correlations contained within the density matrix. This is demonstrated by the fact that currents calculated from the one-electron reduced density matrix to second order in electron correlation are identical to the currents obtained from the Green's function corrected to second order in electron self-energy.

Keywords

Cite

@article{arxiv.0710.5276,
  title  = {Electronegativity in quantum electronic transport},
  author = {R. J. Bartlett and G. Fagas and J. C. Greer},
  journal= {arXiv preprint arXiv:0710.5276},
  year   = {2007}
}

Comments

13 pages, 3 figures

R2 v1 2026-06-21T09:37:13.858Z