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Excitonic contributions to absorption and photocurrent generation in semiconductor nanostructures are described theoretically and simulated numerically using steady-state non-equilibrium Green's function theory. In a first approach, the…

Mesoscale and Nanoscale Physics · Physics 2012-09-28 U. Aeberhard

Excitonic insulator is a coherent electronic phase that results from the formation of a macroscopic population of bound particle-hole pairs - excitons. With only a few candidate materials known, the collective excitonic behavior is…

Strongly Correlated Electrons · Physics 2021-05-27 Pavel A. Volkov , Mai Ye , Himanshu Lohani , Irena Feldman , Amit Kanigel , Girsh Blumberg

Excitonic effects in the optical absorption spectra of solids can be described with time-dependent density-functional theory (TDDFT) in the linear-response regime, using a simple class of approximate, long-range corrected (LRC)…

Materials Science · Physics 2025-04-10 Jared R. Williams , Carsten A. Ullrich

Many-body effects are known to play a crucial role in the electronic and optical properties of solids and nano-structures. Nevertheless the majority of theoretical and numerical approaches able to capture the influence of Coulomb…

Materials Science · Physics 2015-05-30 C. Attaccalite , M. Grüning , A. Marini

We have calculated the frequency-dependent exact exchange (EXX) kernel of time-dependent (TD) density functional theory employing our recently proposed computational method based on cubic splines. With this kernel we have calculated the…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Maria Hellgren , Ulf von Barth

We present a channel-resolved interpretation of laser-driven Coulomb explosion of the HCl dimer from an ensemble of trajectories. Three dominant outcomes are identified: a minor three-body channel and two four-body channels (sequential and…

Chemical Physics · Physics 2026-01-21 Chen Jiang , Cody L. Covington , Kalman Varga

We quantify the excitonic coupling in the homodimer of dimeric Venus fluorescent protein using a quantum-classical hybrid workflow. Employing a transition-density coupling formalism, we calculate $J = 74.38~\mathrm{cm^{-1}}$, which is 5.6…

Chemical Physics · Physics 2026-05-04 Robson Christie , Cerys Murray , Youngchan Kim , Jaewoo Joo

The performance of several common approximations for the exchange-correlation kernel within time-dependent density-functional theory is tested for elementary excitations in the homogeneous electron gas. Although the adiabatic local-density…

Materials Science · Physics 2007-05-23 Krzysztof Tatarczyk , Arno Schindlmayr , Matthias Scheffler

We study the thermal conductivity in the excitonic insulator using a simple quasi one-dimensional two-band model consisting of electron and hole bands with the Coulomb interactions between these bands. Based on the linear response theory…

Strongly Correlated Electrons · Physics 2021-12-21 S. Takarada , M. Ogata , H. Matsuura

We formulate a time-dependent density-matrix functional theory (TDDMFT) approach for higher-order correlation effects like biexcitons in optical processes in solids based on the reduced two-particle density-matrix formalism within the…

Materials Science · Physics 2015-05-19 Volodymyr Turkowski , Carsten A. Ullrich , Talat S. Rahman , Michael N. Leuenberger

Adiabatic time-dependent density functional theory fails for excitations of a heteroatomic molecule composed of two open-shell fragments at large separation. Strong frequency-dependence of the exchange-correlation kernel is necessary for…

Other Condensed Matter · Physics 2009-11-11 Neepa T. Maitra , David G. Tempel

The bound electron-hole pairs known as excitons govern the optical properties of insulating solids. While their behavior in equilibrium is well-understood theoretically, the nonequilibrium regime at high excitation densities-where phenomena…

Mesoscale and Nanoscale Physics · Physics 2025-10-31 Pushpendra Yadav

The electronic exchange-correlation (XC) kernel constitutes a fundamental input for the estimation of a gamut of material properties such as the dielectric characteristics, the thermal and electrical conductivity, or the response to an…

Computational Physics · Physics 2024-02-26 Zhandos A. Moldabekov , Maximilian Böhme , Jan Vorberger , David Blaschke , Tobias Dornheim

Excitons, electron-hole pairs bound by the Coulomb potential, are fundamental quasiparticles of coherent light-matter interaction energizing processes from photosynthesis to optoelectronics. Excitons are observed in semiconductors, and…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Xuefeng Cui , Cong Wang , Adam Argondizzo , Sean Garrett-Roe , Branko Gumhalter , Hrvoje Petek

An exchange-correlation energy functional $ E_{\mathrm xc} $ and the resultant exchange-correlation potential $ v_{\mathrm xc}({\bf r}) $ in density-functional theory are proposed using orbital-dependent coupling-constant-averaged pair…

Strongly Correlated Electrons · Physics 2007-05-23 Hiroshi Yasuhara , Masahiko Higuchi , Yoshiyuki Kawazoe

Nonradiative exciton lifetime in silicon is determined by comparison of the experimental and theoretical curves of bulk minority charge carriers lifetime on doping and excitation levels. This value is used to analyze the influence of…

Materials Science · Physics 2016-12-21 A. V. Sachenko , V. P. Kostylyov , V. M. Vlasyuk , I. O. Sokolovskyi , M. Evstigneev

The discontinuous character of the exact exchange-correlation $(xc)$ energy functional of Density Functional Theory is shown to arise naturally in the subband spectra of semiconductor quantum wells. Using an \emph{ab-initio} $xc$…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Rigamonti , C. R. Proetto

We develop a microscopic theory of the linear electromagnetic response of bilayer excitonic insulators relevant to electron-hole double-layer systems. Using a self-consistent Hartree-Fock description of the excitonic ground state and…

Mesoscale and Nanoscale Physics · Physics 2026-01-08 Yuelin Shao , Hao Shi , Xi Dai

Charge-transfer excitons possessing long radiative lifetime and net permanent dipole moment are highly appealing for quantum dot (QD) based energy harvesting and photodetecting devices, in which the efficiency of charge separation after…

Mesoscale and Nanoscale Physics · Physics 2022-07-13 Yamei Zhou , Christos S. Garoufalis , Zaiping Zeng , Sotirios Baskoutas , Yu Jia , Zuliang Du

We calculate the critical temperature below which an excitonic insulator exists at the pressure-induced semiconductor-semimetal transition. Our approach is based on an effective-mass model for valence and conduction band electrons…

Strongly Correlated Electrons · Physics 2009-11-11 Franz X. Bronold , Holger Fehske