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The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a…

Statistical Mechanics · Physics 2020-08-28 Philipp Strasberg

Building on parallels between geometric quantum mechanics and classical mechanics, we explore an alternative basis for quantum thermodynamics that exploits the differential geometry of the underlying state space. We develop both…

Quantum Physics · Physics 2024-03-13 Fabio Anza , James P. Crutchfield

Quantum thermodynamics investigates how robust the second law of thermodynamics serves as the unique fundamental law in the small quantum world. To tackle this problem, the quantum coherence constitutes a major difficulty of investigations,…

Quantum Physics · Physics 2025-10-08 Naoto Shiraishi , Ryuji Takagi

We consider continuously monitored quantum systems and introduce definitions of work and heat along individual quantum trajectories that are valid for coherent superpositions of energy eigenstates. We use these quantities to extend the…

Quantum Physics · Physics 2016-03-22 Jose Joaquin Alonso , Eric Lutz , Alessandro Romito

This paper explores the non-equilibrium behavior of thermodynamics at the apparent horizon of isotropic and homogeneous universe model in $f(\mathcal{G},T)$ gravity ($\mathcal{G}$ and $T$ represent the Gauss-Bonnet invariant and trace of…

General Relativity and Quantum Cosmology · Physics 2018-03-13 M. Sharif , Ayesha Ikram

Completely positive trace preserving maps are essential for the formulation of the second law of thermodynamics. The dynamics of quantum systems, correlated with their environments, are in general not described by such maps. We explore how…

Quantum Physics · Physics 2016-08-18 Sai Vinjanampathy , Kavan Modi

There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for…

Statistical Mechanics · Physics 2022-11-30 Robert Hołyst , Karol Makuch , Anna Maciołek , Paweł J. Żuk

This paper has been withdrawn by the author. For the reason, see the bottom paragraph of this abstract. By generalizing Tasaki's work on the second law of thermodynamics for an adiabatic process between two equilibrium states of a…

Statistical Mechanics · Physics 2014-05-26 Hiroshi Matsuoka

Quantum dynamics controlled by a time-dependent coupling constant are studied. It is proven that an energy eigenstate expectation value of work done by the system in a quench process cannot exceed the work in the corresponding quasi-static…

Statistical Mechanics · Physics 2020-09-04 C. Itoi , M. Amano

The present paper reports our attempt to search for a new universal framework in nonequilibrium physics. We propose a thermodynamic formalism that is expected to apply to a large class of nonequilibrium steady states including a heat…

Statistical Mechanics · Physics 2007-05-23 Shin-ichi Sasa , Hal Tasaki

The second law of thermodynamics states that the entropy of an isolated system is almost always increasing. We propose combinatorial formalizations of the second law and explore their conditions of possibilities.

Combinatorics · Mathematics 2017-06-27 Rafael Diaz , Sergio Villamarin

Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems. These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of…

Quantum Physics · Physics 2021-02-23 Adam Hewgill , Gabriele De Chiara , Alberto Imparato

We consider a single harmonic oscillator coupled to a bath at zero temperature. As is well known, the oscillator then has a higher average energy than that given by its ground state. Here we show analytically that for a damping model with…

Quantum Physics · Physics 2009-11-13 ILki Kim , Guenter Mahler

While it is well known that complete positivity guarantees the fulfilment of the second law of thermodynamics, its possible violations have never been proposed as a check of the complete positivity of a given open quantum dynamics. We…

Quantum Physics · Physics 2015-10-28 G. Argentieri , F. Benatti , R. Floreanini , M. Pezzutto

Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this…

Quantum Physics · Physics 2025-12-02 J. M. Z. Choquehuanca

We relate Newton's Second Law with the Second Law of Thermodynamics through the analysis of a simple model introducing a dynamic pressure concept. From this analyses we can clarify some conceptual problems resulting from several concepts of…

General Physics · Physics 2007-05-23 Rodrigo de Abreu

The microscopic derivation of the second law for macroscopic system is given under the phenomenological assumption that both the initial and final states are described by mutually different canonical ensembles. In particular, it is also…

Classical Physics · Physics 2011-11-08 Takaaki Monnai

We consider the generic model of a finite-size quantum electron system connected to two (temperature and particle) reservoirs. The quantum open system is driven out of equilibrium by the presence of both a temperature and a chemical…

Statistical Mechanics · Physics 2017-04-04 H. Ness

Thermodynamics is traditionally concerned with systems comprised of a large number of particles. Here we present a framework for extending thermodynamics to individual quantum systems, including explicitly a thermal bath and work-storage…

Quantum Physics · Physics 2014-09-29 Paul Skrzypczyk , Anthony J. Short , Sandu Popescu

The heat theorem (i.e. the second law of thermodynamics or the existence of entropy) is a manifestation of a general property of hamiltonian mechanics and of the ergodic Hypothesis. In nonequilibrium thermodynamics of stationary states the…

Statistical Mechanics · Physics 2008-11-01 Giovanni Gallavotti
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