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Ab initio instanton rate theory is a computational method for rigorously including tunnelling effects into calculations of chemical reaction rates based on a potential-energy surface computed on the fly from electronic-structure theory.…

Chemical Physics · Physics 2018-05-08 Gabriel Laude , Danilo Calderini , David P. Tew , Jeremy O. Richardson

The processes of energy gain and redistribution in a dense gas subject to an intense ultrashort laser pulse are investigated theoretically for the case of high-pressure argon. The electrons released via strong-field ionization and driven by…

We investigate the anisotropy of the optical properties of thin Fe films on GaAs(001) from first-principles calculations. Both intrinsic and magnetization-induced anisotropy are covered by studying the system in the presence of spin-orbit…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Sebastian Putz , Martin Gmitra , Jaroslav Fabian

We investigate the properties of the optical model wave function for light heavy-ion systems where absorption is incomplete, such as $\alpha + ^{40}$Ca and $\alpha + ^{16}$O around 30 MeV incident energy. Strong focusing effects are…

Nuclear Theory · Physics 2008-11-26 F. Brau , F. Michel , G. Reidemeister

We present an implementation of the Heyd-Scuseria-Ernzerhof (HSE) hybrid functional within the full-potential linearized augmented-plane-wave (FLAPW) method. Pivotal to the HSE functional is the screened electron-electron interaction, which…

Materials Science · Physics 2011-11-11 Martin Schlipf , Markus Betzinger , Christoph Friedrich , Marjana Ležaić , Stefan Blügel

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

Recent high resolution Compton scattering experiments clearly reveal that there are fundamental limitations to the conventional local density approximation (LDA) based description of the ground state electron momentum density (EMD) in…

Strongly Correlated Electrons · Physics 2007-10-11 B. Barbiellini , A. Bansil

A systematic way of improving exchange-correlation energy functionals of density functional theory has been to make them satisfy more and more exact relations. Starting from the initial GGA functionals, this has culminated into the recently…

Chemical Physics · Physics 2017-10-11 Rabeet Singh , Manoj K. Harbola

If one-electron observables of a many-electron system are of interest, a many-electron dynamics can be represented exactly by a one-electron dynamics with effective potentials. The formalism for this reduction is provided by the Exact…

Chemical Physics · Physics 2021-01-04 Jakub Kocák , Axel Schild

A fully kinetic simulation approach, treating each plasma component based on the Vlasov equation, is adopted to study the disintegration of an initial density perturbation (IDP) into a number of ion-acoustic solitary waves (IASWs) in the…

Plasma Physics · Physics 2016-10-06 S. M. Jenab , F. Spanier

Calibrating for direction-dependent ionospheric distortions in visibility data is one of the main technical challenges that must be overcome to advance low-frequency radio astronomy. In this paper, we propose a novel probabilistic,…

Instrumentation and Methods for Astrophysics · Physics 2020-01-15 J. G. Albert , M. S. S. L. Oei , R. J. van Weeren , H. T. Intema , H. J. A. Röttgering

In the Projector Augmented Wave (PAW) method, a local potential, basis functions, and projector functions form an All-Electron (AE) basis for valence wave functions in the application of Density Functional Theory (DFT). The construction of…

Materials Science · Physics 2010-08-05 R. J. Snow , A. F. Wright , C. Y. Fong

We examine the effect of laser focusing on the potential of a recently discussed scheme [M.F. Ciappina {\em et al}, Phys. Rev. A 99, 043405 (2019); Las. Phys. Lett. 17, 025301 (2020)] for in situ determination of ultra-high intensities of…

Atomic Physics · Physics 2020-02-27 M. F. Ciappina , E. E. Peganov , S. V. Popruzhenko

We present a comprehensive ab initio study of the influence of band structure corrections, particularly the electron effective mass, on the phonon-limited electron drift and Hall mobilities of GaAs. Our approach is based on the DFT+$U$…

We present a novel technique to assess the focal volume of petawatt-class lasers at full power. Our approach exploits quantitative measurement of the angular distribution of electrons born in the focus via ionization of rarefied gas, which…

We formulate a Hartree-Fock-LAPW method for electronic band structure calculations. The method is based on the Hartree-Fock-Roothaan approach for solids with extended electron states and closed core shells where the basis functions of…

Materials Science · Physics 2016-08-31 A. V. Nikolaev , P. N. Dyachkov

Quantum mechanical methods based on the density functional theory (DFT) offer a realistic possibility of first-principles design of organic donor-acceptor systems and engineered band-gap materials. This promise is contingent upon the…

Chemical Physics · Physics 2013-12-03 Marcin Modrzejewski , Grzegorz Chałasiński , Małgorzata M. Szczęśniak

Density functional theory (DFT) is an exact alternative formulation of quantum mechanics, in which it is possible to calculate the total energy, the spin and the charge density of many-electron systems in the ground state. In practice, it…

Atomic Physics · Physics 2014-03-25 Uri Argaman , Guy Makov , Eli Kraisler

Negative ion detachment in two-colour laser field is considered within the recent modification of Keldysh model which makes it quantitatively reliable. The general approach is illustrated by calculation of angular differential detachment…

Atomic Physics · Physics 2009-10-30 M. Yu. Kuchiev , V. N. Ostrovsky

We perform nonadiabatic simulations of warm dense aluminum based on the electron-force field (EFF) variant of wave-packet molecular dynamics. Comparison of the static ion-ion structure factor with density functional theory (DFT) is used to…

Plasma Physics · Physics 2020-12-08 Ryan A. Davis , W. A. Angermeier , R. Hermsmeier , Thomas G. White