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Using electron diffraction, we show that free electron metals such as sodium and potassium form a highly regular quasiperiodic monolayer on the fivefold surface of icosahedral Al-Pd-Mn and that the quasiperiodicity propagates up to the…

Materials Science · Physics 2009-09-30 A. K. Shukla , R. S. Dhaka , S. W. Dsouza , Sanjay Singh , D. Wu , T. A. Lograsso , M. Krajci , J. Hafner , K. Horn , S. R. Barman

Lead has been deposited on the ten-fold surface of decagonal Al72Ni11Co17 to form an epitaxial quasicrystalline single-element monolayer. The overlayer grows through nucleation of nanometer-sized irregular islands and the coverage saturates…

Other Condensed Matter · Physics 2008-06-02 J. A. Smerdon , L. Leung , J. K. Parle , C. J. Jenks , R. McGrath , V. Fournee , J. Ledieu

A quasiperiodic Pb monolayer has been formed on the five-fold surface of the Al-Pd-Mn quasicrystal. Growth of the monolayer proceeds via self-assembly of an interconnected network of pentagonal Pb stars, which are shown to be tau-inflated…

Materials Science · Physics 2009-11-13 J. Ledieu , L. Leung , L. H. Wearing , R. McGrath , T. A. Lograsso , D. Wu , V. Fournée

A dodecagonal quasicrystal showing 12-fold symmetry forms in Mn-rich quaternary alloys containing 5.5 or 7.5 at.% Cr, 5.0 at.% Ni and 17.5 at.% Si. After annealing at 700 C for 130 h, the quasicrystal precipitated in a matrix of \b{eta}-Mn…

Materials Science · Physics 2016-02-17 Shuhei Iwami , Tsutomu Ishimasa

This paper reports formation enthalpies of phases in the Al-Mn-Pd ternary alloy system as calculated from first principles using electronic density functional theory. We consider all crystal structures as reported in the assessed phase…

Materials Science · Physics 2023-02-27 Marek Mihalkovic , Michael Widom

Realization of an elemental solid-state quasicrystal has remained a distant dream so far in spite of extensive work in this direction for almost two decades. Here, we report the discovery of quasiperiodic ordering in a thick layer of…

In this work, we present the formation and characterization of a quaternary (pseudo ternary) icosahedral quasicrystal in Al65Ga5Pd17Mn13 alloy. The X ray diffraction and transmission electron microscopy confirmed the formation of…

Materials Science · Physics 2009-11-13 T. P. Yadav , M. A. Shaz , R. S. Tiwari , O. N. Srivastava

Scanning tunnelling microscopy has been used to study the formation of a Bi monolayer deposited on the five-fold surface of i-Al70Pd21Mn9. Upon deposition of low sub-monolayer coverages, the nucleation of pentagonal clusters of Bi adatoms…

Other Condensed Matter · Physics 2009-11-13 J. A. Smerdon , J. K. Parle , L. H. Wearing , T. A. Lograsso , A. R. Ross , R. McGrath

We have synthesised a thin film of copper with a quasi-periodic structure by the adsorption of copper atoms on the five-fold surface of the icosahedral quasicrystal Al-Pd-Mn at room temperature. The quasi-periodicity of the thin film is…

Materials Science · Physics 2009-11-10 J. Ledieu , J. T. Hoeft , D. E. Reid , J. A. Smerdon , R. D. Diehl , T. A. Lograsso , A. R. Ross , R. McGrath

Thin film quasicrystal coatings have unique properties such as very high electrical and thermal resistivity and very low surface energy. A nano quasicrystalline thin film of icosahedral Al-Ga-Pd-Mn alloy, has produced by flash evaporation…

Materials Science · Physics 2021-07-06 Thakur Prasad Yadav

We report a novel kind of dodecagonal quasicrystal that has so far never been observed, nor theoretically predicted. It is composed of axially stacked hexagonal particle layers, with 12-fold rotational symmetry induced by 30 degrees…

Soft Condensed Matter · Physics 2015-04-16 Alfredo Metere , Peter Oleynikov , Mikhail Dzugutov , Sven Lidin

While performing molecular dynamics simulations of a simple monatomic liquid, we observed the crystallization of a material displaying octagonal symmetry in its simulated diffraction pattern. Inspection of the atomic arrangements in the…

A P-type icosahedral quasicrystal is formed in Au-Al-Yb alloy of which 6-dimensional lattice parameter a6D = 7.448 {\AA}. The composition of the quasicrystal was analyzed to be Au51Al34Yb15. This quasicrystal is formed in as-cast alloys,…

Materials Science · Physics 2015-05-27 Tsutomu Ishimasa , Yukinori Tanaka , Shiro Kashimoto

We review our Al adsorption experiments on the tenfold-symmetry surface of the decagonal Al-Co-Ni quasicrystal and present computational simulations of adsorption on a structural model based on a fundamental Al-Co cluster with 20 \AA…

We discover the detailed atomic structure of $d$-MgZnY, a stable decagonal quasicrystal alloy of the layered Frank-Kasper type, and related phases, using the "tiling and decoration" approach. The atoms have invariable sites in the rectangle…

Materials Science · Physics 2011-12-19 M. Mihalkovic , C. L. Henley , J. Richmond-Decker , M. Oxborrow

We have studied and resolved occupancy correlations in the existing average structure model of the complex metallic alloy xi'-Al-Pd-Mn [Boudard et al., Phil. Mag. A, 74, 939 (1996)], which has approximately 320 atoms in the unit cell and…

The dodecagonal quasicrystal classified into the five-dimensional space group P126/mmc, recently discovered in a Mn-Cr-Ni-Si alloy, has been analyzed using atomic-resolution spherical aberration-corrected electron microscopy, i.e.…

Materials Science · Physics 2016-02-17 Tsutomu Ishimasa , Shuhei Iwami , Norihito Sakaguchi , Ryo Oota , Marek Mihalkovic

Using scanning tunneling microscopy (STM), low energy electron diffraction (LEED), and density functional theory (DFT), we demonstrate the formation of quasicrystalline gallium adlayer on icosahedral ($i$)-Al-Pd-Mn. Quasiperiodic motifs are…

Materials Science · Physics 2024-03-08 Pramod Bhakuni , Marian Krajčí , Sudipta Roy Barman

Quasicrystals provide a fascinating class of materials with intriguing properties. Despite a strong potential for numerous technical applications, the conditions under which quasicrystals form are still poorly understood. Currently, it is…

Materials Science · Physics 2010-05-13 J. Mikhael , M. Schmiedeberg , S. Rausch , J. Roth , H. Stark , C. Bechinger

6-d polyhedral models give a periodic description of aperiodic quasicrystals. There are powerful tools to describe their structural surface properties. Basis of the model for icosahedral quasicrystals are given. This description is further…

Materials Science · Physics 2007-05-23 L. Barbier , D. Gratias
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