Related papers: Boltzmann's Approach to Statistical Mechanics
We consider the kinetic theory of dilute gases in the Boltzmann--Grad limit. We propose a new perspective based on a large deviation estimate for the probability of the empirical distribution dynamics. Assuming Boltzmann molecular chaos…
Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. (Only in this case this is equivalent to the fundamental microcanonical ensemble.) However, some 170 years ago the original motivation of…
Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. However, some 150 years ago the original motivation of thermodynamics was the description of steam engines, i.e. boiling water. Its essential…
In 1910 Einstein published a crucial aspect of his understanding of Boltzmann entropy. He essentially argued that the likelihood function of any system composed by two probabilistically independent subsystems {\it ought} to be factorizable…
In this manuscript we present a brief life history of Ludwig Edward Boltzmann and his achivements. Particularly, we discuss his H-theorem, his work on entropy and statistical interpretation of second-law of thermodynamics. We point out his…
Molecular Dynamics and Statistical Mechanics make possible a particle-based understanding of Thermodynamics and Hydrodynamics, including the fascinating Loschmidt contradiction between time-reversible atomistic mechanics and the…
Within the description of stochastic differential equations it is argued that the existence of Boltzmann-Gibbs type distribution in economy is independent of the time reversal symmetry in econodynamics. Both power law and exponential…
We study a mechanical system that was considered by Boltzmann in 1868 in the context of the derivation of the canonical and microcanonical ensembles. This system was introduced as an example of ergodic dynamics, which was central to…
Boltzmann's principle S(E,N,V)=k\ln W relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
Are your perceptions, memories and observational data, a statistical fluctuation out of the thermal equilibrium of the universe, having no correlation with the actual past state of the universe? Arguments are given in the literature for and…
To address the observation of Max Born (M. Born 1969) that the Newton's second law can emerge from a purely statistical perspective, we derive the evolution equation about the statistical distribution for dilute gas based solely on…
We study the statistical underpinnings of life. We question some common assumptions about the thermodynamics of life and illustrate how, contrary to widespread belief, even in a closed system entropy growth can accompany an increase in…
The application of classical methods of statistical mechanics, originally developed by Ludwig Boltzmann in gas dynamics, to the description of social phenomena is a successful story that we try to outline in this paper. On one hand, it is…
The development of stochastic thermodynamics during the last decades prompted the discovery of novel nonequilibrium relations refining our understanding of the second law in small fluctuating systems and its connection with information…
Many physicists think that the maximum entropy formalism is a straightforward application of Bayesian statistical ideas to statistical mechanics. Some even say that statistical mechanics is just the general Bayesian logic of inductive…
We present a derivation of Boltzmann principle $S_{B}=k_{B}\ln \mathcal{W}$ based on classical mechanical models of thermodynamics. The argument is based on the heat theorem and can be traced back to the second half of the nineteenth…
This paper analyzes the ergodic hypothesis in the context of Boltzmann's late work in statistical mechanics, where Boltzmann lays the foundations for what is today known as the typicality account. I argue that, based on the concepts of…
I give a highly selective overview of the way statistical mechanics explains the microscopic origins of the time asymmetric evolution of macroscopic systems towards equilibrium and of first order phase transitions in equilibrium. These…
The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…
Stefan-Boltzmann law was empirically deduced by Stefan in 1874 by fitting existing experiments and theoretically validated by Boltzmann in 1884 on the basis of a classical model involving thermodynamics principles and the Maxwell equations.…