English

Derivation of Boltzmann Principle

Statistical Mechanics 2010-05-24 v1

Abstract

We present a derivation of Boltzmann principle SB=kBlnWS_{B}=k_{B}\ln \mathcal{W} based on classical mechanical models of thermodynamics. The argument is based on the heat theorem and can be traced back to the second half of the nineteenth century with the works of Helmholtz and Boltzmann. Despite its simplicity, this argument has remained almost unknown. We present it in a modern, self-contained and accessible form. The approach constitutes an important link between classical mechanics and statistical mechanics.

Keywords

Cite

@article{arxiv.0911.2070,
  title  = {Derivation of Boltzmann Principle},
  author = {Michele Campisi and Donald H. Kobe},
  journal= {arXiv preprint arXiv:0911.2070},
  year   = {2010}
}