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Phases with distinct thermodynamic properties must differ in their underlying distributions of microscopic structures. While ordered phases are readily distinguished by unit cells and space groups, the local structural basis differentiating…

The phase transition of a fluid adsorbed in a heterogeneous system is studied with two simple lattice gas models within the framework of a mean-field theory. Despite the different origin of the heterogeneity (spatial variation of binding…

Statistical Mechanics · Physics 2007-05-23 E. V. Vakarin , W. Dong , J. P. Badiali

Linearly-sloped or `ramp' potentials belong to a class of core-softened models which possess a liquid-liquid critical point (LLCP) in addition to the usual liquid-gas critical point. Furthermore they exhibit thermodynamic anomalies in the…

Statistical Mechanics · Physics 2009-11-11 Helen M. Gibson , Nigel B. Wilding

We present a review on the study of metastable silicon, primarily focusing mainly on the aspects of liquid-liquid transition, critical point and phase behaviour, structural and dynamic properties of liquid phase as well as crystal…

Materials Science · Physics 2021-09-01 Vishwas V. Vasisht , Srikanth Sastry

In simulations of a water-like model (ST2) that exhibits a liquid-liquid phase transition, we test for the occurrence of a thermodynamic region in which the liquid can be modelled as a two-component mixture. We assign each molecule to one…

Statistical Mechanics · Physics 2011-03-24 Megan J. Cuthbertson , Peter H. Poole

In network glass including chalcogenides, the network topology of microscopic structures can be tuned by changing the chemical compositions. As the composition is varied, an intermediate phase (IP) singularly different from the adjacent…

Soft Condensed Matter · Physics 2019-08-27 J. Quetzalcoatl Toledo-Marin , Le Yan

We present a simple model for an associating liquid in which polymorphism and density anomaly are connected. Our model combines a two dimensional lattice gas with particles interacting through a soft core potential and orientational degrees…

Statistical Mechanics · Physics 2009-11-10 Vera B. Henriques , Marcia C Barbosa

In equilibrium and supercooled liquids, polymorphism is manifested by thermodynamic regions defined in the phase diagram, which are predominantly of different short- and medium-range order (local structure). It is found that on the phase…

Soft Condensed Matter · Physics 2024-03-19 Anatolii V. Mokshin , Roman V. Vlasov

The liquid-gas phase transition in strange hadronic matter is reexamined by using the new parameters about the $\Lambda - \Lambda$ interaction deduced from recent observation of $^{6}_{\Lambda\Lambda}He$ double hypernucleus. The extended…

Nuclear Theory · Physics 2007-05-23 Li Yang , Shao Yu Yin , Wei Liang Qian , Ru-keng Su

Liquid-liquid phase separation is key to understanding aqueous two-phase systems (ATPS) arising throughout cell biology, medical science, and the pharmaceutical industry. Controlling the detailed morphology of phase-separating compound…

Soft Condensed Matter · Physics 2023-10-27 Eric W. Hester , Sean P. Carney , Vishwesh Shah , Alyssa Arnheim , Bena Patel , Dino Di Carlo , Andrea L. Bertozzi

Fluid polyamorphism, the existence of multiple amorphous fluid states in a single-component system, has been observed or predicted in a variety of substances. A remarkable example of this phenomenon is the fluid-fluid phase transition in…

Soft Condensed Matter · Physics 2022-09-21 Nathaniel R. Fried , Thomas J. Longo , Mikhail A. Anisimov

Melt supercooling leads to glass formation. Liquid-to-liquid phase transitions are observed depending on thermal paths. Viscosity, density and surface tension thermal dependences measured at heating and subsequent cooling show hysteresis…

Materials Science · Physics 2016-12-21 Robert F. Tournier

The origin of water's anomalous behavior remains a central open problem in the physical sciences and is often attributed to a liquid-liquid transition (LLT) between high- and low-density liquid states deep in the supercooled regime.…

Soft Condensed Matter · Physics 2026-04-02 Florian Pabst , Ali Hassanali

Using event driven molecular dynamics simulations, we study a three dimensional one-component system of spherical particles interacting via a discontinuous potential combining a repulsive square soft core and an attractive square well. In…

Soft Condensed Matter · Physics 2009-11-10 A. Skibinsky , S. V. Buldyrev , G. Franzese , G. Malescio , H. E. Stanley

In this paper we present a new thermodynamically consistent phase transition model describing the evolution of a liquid substance, e.g., water, in a rigid container $\Omega$ when we freeze the container. Since the density $\varrho_{2}$ of…

Analysis of PDEs · Mathematics 2014-01-10 Michel Fremond , Elisabetta Rocca

Temperature-driven polyamorphism has been reported in various supercooled liquids and glasses. The dynamical and structural routes followed by the system during such crossovers are however not universal and appear to be related to intrinsic…

Disordered Systems and Neural Networks · Physics 2018-08-29 S. Hechler , B. Ruta , M. Stolpe , E. Pineda , Z. Evenson , O. Gross , W. Hembree , A. Bernasconi , R. Busch , I. Gallino

We find that a system of particles interacting through a simple isotropic potential with a softened core is able to exhibit a rich phase behavior including: a liquid-liquid phase transition in the supercooled phase, as has been suggested…

Soft Condensed Matter · Physics 2009-10-31 G. Malescio , G. Pellicane

Strongly interacting, dynamically disordered and with no small parameter, liquids took a theoretical status between gases and solids. We review different approaches to liquids and propose that liquids do not need classifying in terms of…

Soft Condensed Matter · Physics 2016-01-13 K. Trachenko , V. V. Brazhkin

The liquid-gas phase transition in strange hadronic matter is studied utilizing an extended Furnstahl-Serot-Tang model with nucleons and hyperons. The system is treated as of two components. The phase transition is analyzed by investigating…

Nuclear Theory · Physics 2009-11-10 Li Yang , Wei Liang Qian , Ru-Keng Su , Hong Qiu Song

The dynamics of a thin layer of liquid, between a flat solid substrate and an infinitely-thick layer of saturated vapor, is examined. The liquid and vapor are two phases of the same fluid, governed by the diffuse-interface model. The…

Statistical Mechanics · Physics 2021-09-27 E. S. Benilov