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Metal-fullerene compounds are characterized by significant electron transfer to the fullerene cage, giving rise to an electric dipole moment. We use the method of electrostatic beam deflection to verify whether such reactions take place…

Atomic and Molecular Clusters · Physics 2022-04-26 John W. Niman , Benjamin S. Kamerin , Thomas H. Villers , Thomas M. Linker , Aiichiro Nakano , Vitaly V. Kresin

Fullerene peapods, that is carbon nanotubes encapsulating fullerene molecules, can offer enhanced functionality with respect to empty nanotubes. However, the present incomplete understanding of how a nanotube is affected by entrapped…

Mesoscale and Nanoscale Physics · Physics 2010-09-08 Pawel Utko , Raffaello Ferone , Ilya V. Krive , Robert I. Shekhter , Mats Jonson , Marc Monthioux , Laure Noé , Jesper Nygård

Metal-string complexes in the quasi-1D framework may play an important role in molecular electronics by serving not only as nanoscale interconnects but also as active functional elements for nanoelectronic devices. However, because of the…

Mesoscale and Nanoscale Physics · Physics 2020-01-03 Talem Rebeda Roy , Arijit Sen

Devices made of few molecules constitute the miniaturization limit that both inorganic and organic-based electronics aspire to reach. However, integration of millions of molecular junctions with less than 100 molecules each has been a long…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Kacem Smaali , Nicolas Clement , Gilles Patriarche , Dominique Vuillaume

Electron transport characteristics are investigated through some molecular chains attached to two non-superconducting electrodes by the use of Green's function method. Here we do parametric calculations based on the tight-binding…

Mesoscale and Nanoscale Physics · Physics 2009-07-31 Santanu K. Maiti

We present a microscopic theory of single-electron tunneling through metallic nanoparticles connected to the electrodes through molecular bridges. It combines the theory of electron transport through molecular junctions with the description…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

We study the variation of electron transmission through Au-S-benzene-S-Au junctions and related systems as a function of the structure of the Au:S contacts. For junctions with semi-infinite flat Au(111) electrodes, the highly coordinated…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 A. Grigoriev , J. Skoeldberg , G. Wendin , Z. Crljen

A method for the calculation of the conductance of nanoscale electrical junctions is extended to ab-initio electronic structure methods and applied to realistic models of metallic wires and break-junctions of sodium and gold. The method is…

Materials Science · Physics 2014-05-13 Matthieu J. Verstraete , P. Bokes , R. W. Godby

Tunneling of electrons through rotor-stator anthracene aldehyde molecular interfaces is studied with a combined ab initio and model approach. Molecular electronic structure calculated from first principles is utilized to model different…

Chemical Physics · Physics 2016-05-27 Irina Petreska , Vladimir Ohanesjan , Ljupco Pejov , Ljupco Kocarev

We present a quaternion-inspired formalism specifically developed to evaluate the electric current that traverses a single molecule subjected to an externally applied voltage. The molecule of interest is covalently connected to two small…

Mesoscale and Nanoscale Physics · Physics 2014-08-06 Augusto C. L. Moreira , Celso P. de Melo

Electronic transport properties through some model quantum systems are re-visited. A simple tight-binding framework is given to describe the systems where all numerical calculations are made using the Green's function formalism. First, we…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Santanu K. Maiti

We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Latha Venkataraman , Young S. Park , Adam C. Whalley Colin Nuckolls , Mark S. Hybertsen , Michael L. Steigerwald

The electron-conduction properties of fullerene chains are examined by first-principles calculations based on the density functional theory. The conductivity of the C$_{60}$ dimer is low owing to the constraint of the junction of the…

Materials Science · Physics 2015-06-25 Tomoya Ono , Kikuji Hirose

The scattering-based approach for calculating the ballistic conductance of open quantum systems is generalized to deal with magnetic transition metals as described by ultrasoft pseudo-potentials. As an application we present…

Materials Science · Physics 2009-11-10 A. Smogunov , A. Dal Corso , E. Tosatti

An exact Quantum Kinetic Monte Carlo method is proposed to calculate electron transport for 1D Fermi Hubbard model. The method is directly formulated in real time and can be applied to extract time dependent dynamics of general interacting…

Materials Science · Physics 2018-05-07 Fei Lin , Jianqiu Huang , Celine Hin

We present a scheme for calculating coherent electron transport in atomic-scale contacts. The method combines a formally exact Green's function formalism with a mean-field description of the electronic structure based on the Kohn-Sham…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 K. S. Thygesen , K. W. Jacobsen

We have measured electron transport in small bundles of identical conducting Molybdenum Selenide nanowires where the number of weakly interacting one-dimensional chains ranges from 1-300. The linear conductance and current in these…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Latha Venkataraman , Yeon Suk Hong , Philip Kim

Traditionally, the understanding of quantum transport, coherent and ballistic1, relies on the measurement of macroscopic properties such as the conductance. While powerful when coupled to statistical theories, this approach cannot provide a…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 B. Hackens , F. Martins , T. Ouisse , H. Sellier , S. Bollaert , X. Wallart , A. Cappy , J. Chevrier , V. Bayot , S. Huant

In a recent paper Liang {\it et al.} [Nature {\bf 411}, 665 (2001)] showed experimentally, that metallic nanotubes, strongly coupled to external electrodes, may act as coherent molecular waveguides for electronic transport. The experimental…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 S. Krompiewski , J. Martinek , J. Barnas

To assist the design of novel, highly efficient molecular junctions, a deep understanding of the precise charge transport mechanisms through these devices is of prime importance. In the present contribution, we describe a procedure to…

Chemical Physics · Physics 2020-01-13 Vincent Pohl , Lukas Eugen Marsoner Steinkasserer , Jean Christophe Tremblay