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The dependence of the transport properties on the specific location of the Fermi level in molecular electronics devices is studied by using electrodes of different materials. The zero-bias transport properties are shown to depend…

Mesoscale and Nanoscale Physics · Physics 2008-12-06 V. M. García-Suárez , C. J. Lambert

We do parametric calculations to elucidate multi-terminal electron transport properties through a molecular system where a single phenalenyl molecule is attached to semi-infinite one-dimensional metallic leads. A formalism based on the…

Mesoscale and Nanoscale Physics · Physics 2010-05-25 Paramita Dutta , Santanu K. Maiti , S. N. Karmakar

By employing a real-space formulation of the Kubo-Greenwood equation based on a Green's function embedding technique combined with the fully relativistic spin-polarized Korringa-Kohn-Rostoker method a detailed investigation of the…

Materials Science · Physics 2009-11-10 K. Palotas , B. Lazarovits , L. Szunyogh , P. Weinberger

A theory of electrical transport through molecular wires is used to estimate the electronic factor in the intramolecular electron transfer (ET) in porphyrin-nitrobenzene supermolecules, and to analyze its structure. The chosen molecules…

Soft Condensed Matter · Physics 2007-05-23 Natalya Zimbovskaya , Godfrey Gumbs

Quantum interference in nano-electronic devices could lead to reduced-energy computing and efficient thermoelectric energy harvesting. When devices are shrunk down to the molecular level it is still unclear to what extent electron…

We present a theoretical study of electron transport through a molecule connected to two metallic nanocontacts. The system investigated is 1,4 benzene-dithiolate (BDT) chemically bonded to two Au contacts. The surface chemistry is modeled…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Eldon Emberly , George Kirczenow

The electron transport in a four-terminal nanodevice consisting of two crossed nanotubes is investigated in the framework of the Landauer-Buttiker formalism. The evident formula for the ballistic conductance of the device is found using a…

Mesoscale and Nanoscale Physics · Physics 2011-11-09 Viktor Margulis , Mikhail Pyataev

Electron transport properties of C$_{20}$ molecules suspended between gold electrodes are investigated using first-principles calculations. Our study reveals that the conductances are quite sensitive to the number of C$_{20}$ molecules…

Condensed Matter · Physics 2009-11-10 Megumi Otani , Tomoya Ono , Kikuji Hirose

The effects of different contact geometries, bond dimerization, and gate voltage on quantum transport through a C$_{60}$ molecule are studied by the Landauer-B\"{u}ttiker formula based on the Green's function technique. It is shown that the…

Mesoscale and Nanoscale Physics · Physics 2008-08-12 Alireza Saffarzadeh

We introduce a new quantum transport formalism based on a map of a real 3-dimensional lead-conductor-lead system into an effective 1-dimensional system. The resulting effective 1D theory is an in principle exact formalism to calculate the…

Other Condensed Matter · Physics 2013-05-29 Pierre Darancet , Valerio Olevano , Didier Mayou

It is proposed two models describing transport and absorbtion processes that occur in nanoscale fragments of electrical circuits, pulled adsorbed molecules, atomic or molecular chains connecting electrodes. Discrete chain model of a…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 V. N. Evteev , M. V. Moiseenko , E. V. Zhuravel , E. Ya. Glushko

We have modeled transport properties of nanostructures using the Green's function method within the framework of the density-functional theory. The scheme is computationally demanding so that numerical methods have to be chosen carefully. A…

Computational Physics · Physics 2007-05-23 Paula Havu , Ville Havu , Martti J. Puska , Mikko H. Hakala , Adam S. Foster , Risto M. Nieminen

We evidence the importance of electron charging under nonequilibrium conditions for carbon-nanotube-based molecular bridges, using a self-consistent Green's function method with an extended Huckel Hamiltonian and a three-dimensional Poisson…

Mesoscale and Nanoscale Physics · Physics 2007-10-23 Ioannis Deretzis , Antonino La Magna

Here, we present theoretical analysis of electron transport in polyaniline based (PANi) nanofibers assuming the metalic state of the material. To build up this theory we treat conducting polymers as a special kind of granular metals, and we…

Soft Condensed Matter · Physics 2012-08-27 Natalya A. Zimbovskaya , Alan T. Johnson, , Nicholas J. Pinto

Calculating an exact self energy for ab initio transport calculations relevant to ``Molecular Electronics'' can be troublesome. Errors or insufficient approximations made at this step are often the reason why many molecular transport…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 F. Evers , A. Arnold

We present a new semi-empirical model for calculating electron transport in atomic-scale devices. The model is an extension of the Extended H\"uckel method with a self-consistent Hartree potential. This potential models the effect of an…

Mesoscale and Nanoscale Physics · Physics 2012-04-04 Kurt Stokbro , Dan Erik Petersen , Søren Smidstrup , Anders Blom , Mads Ipsen , Kristen Kaasbjerg

The ability to control the conductance of single molecules will have a major impact in nanoscale electronics. Azobenzene, a molecule that changes conformation as a result of a trans/cis transition when exposed to radiation, could form the…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Miriam del Valle , Rafael Gutierrez , Carlos Tejedor , Gianaurelio Cuniberti

We propose a simple scheme that describes accurately essential non-equilibrium effects in nanoscale electronics devices using equilibrium transport theory. The scheme, which is based on the alignment and dealignment of the junction…

Mesoscale and Nanoscale Physics · Physics 2012-10-01 V. M. García-Suárez , J. Ferrer

We describe a first-principles method for calculating electronic structure, vibrational modes and frequencies, electron-phonon couplings, and inelastic electron transport properties of an atomic-scale device bridging two metallic contacts…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Thomas Frederiksen , Magnus Paulsson , Mads Brandbyge , Antti-Pekka Jauho

We discuss the conductance of a molecular bridge between mesoscopic electrodes supporting low-dimensional transport and bearing an internal structure. As an example for such nanoelectrodes we assume semi-infinite (carbon) nanotubes. In the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. Fagas , G. Cuniberti , K. Richter