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The conformational behavior of a coarse-grained finite polymer chain near an attractive spherical surface was investigated by means of multicanonical Monte Carlo computer simulations. In a detailed analysis of canonical equilibrium data…

Soft Condensed Matter · Physics 2018-01-03 Handan Arkin , Wolfhard Janke

By applying local primitive path and Rouse modes analysis we study the chains conformations, local dynamics and viscosity of a model polymer melt in a polymer-wall interface. We establish that the presence of a repulsive wall leads to…

Materials Science · Physics 2009-11-11 Mihail Vladkov , J. -L. Barrat

We study the diffusion of a linear polymer in the presence of permeable membranes without excluded volume interactions, using scaling theory and Monte Carlo simulations. We find that the average time it takes for a chain with polymerization…

Condensed Matter · Physics 2016-08-31 Hyoungsoo Yoon , J. M. Deutsch

We analyze diffusion of small particles in a solid polymeric medium taking into account a short range particle-polymer interaction. The system is modeled by a particle diffusion on a ternary lattice where the sites occupied by polymer…

Statistical Mechanics · Physics 2015-06-11 Federico Camboni , Andreas Koher , Igor M. Sokolov

We study a model of a semiflexible long chain polymer confined to a two-dimensional slit of width $w$, and interacting with the walls of the slit. The interactions with the walls are controlled by Boltzmann weights $a$ and $b$, and the…

Statistical Mechanics · Physics 2019-12-03 Nicholas R. Beaton , Leo Li , Jonathon Liu , Thomas Wong

Advanced chain-growth computer simulation methodologies have been employed for a systematic statistical analysis of the critical behavior of a polymer adsorbing at a substrate. We use finitesize scaling techniques to investigate the…

Soft Condensed Matter · Physics 2017-05-09 J. A. Plascak , Paulo H. L. Martins , Michael Bachmann

Reactions at a strongly segregated interface of a symmetric binary polymer blend are investigated via Monte Carlo simulations. End functionalized homopolymers of different species interact at the interface instantaneously and irreversibly…

Statistical Mechanics · Physics 2009-10-30 Marcus Mueller

We propose and analyze a technique that allows to suppress inelastic collisions and simultaneously enhance elastic interactions between cold polar molecules. The main idea is to cancel the leading dipole-dipole interaction with a suitable…

Statistical Mechanics · Physics 2008-09-29 A. V. Gorshkov , P. Rabl , G. Pupillo , A. Micheli , P. Zoller , M. D. Lukin , H. P. Büchler

This work investigates the effects of tangent polar activity on the conformational and dynamic properties of entangled polymer melts through Langevin molecular dynamics simulations. We examine systems composed of all self-propelled,…

Soft Condensed Matter · Physics 2024-11-19 Javier Oller-Iscar , Andrés R. Tejedor , Marisol Ripoll , Jorge Ramírez

In this work, we explore the dynamics of active entangled chains using molecular dynamics simulations of a modified Kremer-Grest model. The active chains are diluted in a mesh of very long passive linear chains, to avoid constraint release…

Soft Condensed Matter · Physics 2022-11-01 Andres R. Tejedor , Raquel Carracedo , Jorge Ramírez

We report the results of Monte Carlo simulations investigating the effect of a spherical confinement within a simple model for a flexible homopolymer. We use the parallel tempering method combined with multi-histogram reweighting analysis…

Soft Condensed Matter · Physics 2012-12-27 M. Marenz , J. Zierenberg , H. Arkin , W. Janke

We present a Monte Carlo algorithm that provides efficient and unbiased sampling of polymer melts consisting of two chains of equal length that jointly visit all the sites of a cubic lattice with rod geometry L x L x rL and non-periodic…

Statistical Mechanics · Physics 2010-11-03 Jesper Lykke Jacobsen

Dimerization and subsequent aggregation of polymers and biopolymers often occur under nonequilibrium conditions. When the initial state of the polymer is not collapsed or the final folded native state, the dynamics of dimerization can…

Soft Condensed Matter · Physics 2024-11-19 Sangita Mondal , Ved Mahajan , Biman Bagchi

We present an analytical and computational study characterizing the structural and dynamical properties of an active filament confined in cylindrical channels. We first outline the effects of the interplay between confinement and polar…

Soft Condensed Matter · Physics 2024-10-09 José Martín-Roca , Emanuele Locatelli , Valentino Bianco , Paolo Malgaretti , Chantal Valeriani

We use path-integral Monte Carlo (PIMC) to study the effects of adding a long-range repulsive Coulomb interaction to the usual Van der Waals interaction between two atoms of a submonolayer quantum film such as helium on graphite or a pure…

Statistical Mechanics · Physics 2009-11-11 Keola Wierschem , Efstratios Manousakis

We consider forces acting on objects immersed in, or attached to, long fluctuating polymers. The confinement of the polymer by the obstacles results in polymer-mediated forces that can be repulsive (due to loss of entropy) or attractive (if…

Statistical Mechanics · Physics 2017-08-28 Yacov Kantor , Mehran Kardar

Contours associated to many interesting low-temperature statistical mechanics models (2D Ising model, (2+1)D SOS interface model, etc) can be described as self-interacting and self-avoiding walks on $\mathbb Z^2$. When the model is defined…

Probability · Mathematics 2015-06-22 Dmitry Ioffe , Senya Shlosman , Fabio Lucio Toninelli

In this article we study the effect of a delta-interaction on a polymerized membrane of arbitrary internal dimension D. Depending on the dimensionality of membrane and embedding space, different physical scenarios are observed. We emphasize…

Condensed Matter · Physics 2009-11-07 Henryk A. Pinnow , Kay Joerg Wiese

We study the link between three seeming-disparate cases of self-avoiding polymers: strongly overlapping multiple chains in dilute solution, chains under spherical confinement, and the onset of semi-dilute solutions. Our main result is that…

Biological Physics · Physics 2007-05-23 Suckjoon Jun , Axel Arnold , Bae-Yeun Ha

While the dynamics of polymer chains in equilibrium media is well understood by now, the polymer dynamics in active non-equilibrium environments can be very different. Here we study the dynamics of polymers in a viscous medium containing…

Soft Condensed Matter · Physics 2017-06-23 Jaeoh Shin , Andrey G. Cherstvy , Won Kyu Kim , Vasily Zaburdaev