Semi-flexible directed polymers in a strip with attractive walls
Abstract
We study a model of a semiflexible long chain polymer confined to a two-dimensional slit of width , and interacting with the walls of the slit. The interactions with the walls are controlled by Boltzmann weights and , and the flexibility of the polymer is controlled by another Boltzmann weight . This is a simple model of the steric stabilisation of colloidal dispersions by polymers in solution. We solve the model exactly and compute various quantities in -space, including the free energy and the force exerted by the polymer on the walls of the slit. In some cases these quantities can be computed exactly for all , while for others only asymptotic expressions can be found. Of particular interest is the zero-force surface -- the manifold in -space where the free energy is independent of , and the loss of entropy due to confinement in the slit is exactly balanced by the energy gained from interactions with the walls.
Keywords
Cite
@article{arxiv.1912.00151,
title = {Semi-flexible directed polymers in a strip with attractive walls},
author = {Nicholas R. Beaton and Leo Li and Jonathon Liu and Thomas Wong},
journal= {arXiv preprint arXiv:1912.00151},
year = {2019}
}
Comments
25 pages, 10 figures