English

Semi-flexible directed polymers in a strip with attractive walls

Statistical Mechanics 2019-12-03 v1 Mathematical Physics Combinatorics math.MP

Abstract

We study a model of a semiflexible long chain polymer confined to a two-dimensional slit of width ww, and interacting with the walls of the slit. The interactions with the walls are controlled by Boltzmann weights aa and bb, and the flexibility of the polymer is controlled by another Boltzmann weight cc. This is a simple model of the steric stabilisation of colloidal dispersions by polymers in solution. We solve the model exactly and compute various quantities in (a,b,c)(a,b,c)-space, including the free energy and the force exerted by the polymer on the walls of the slit. In some cases these quantities can be computed exactly for all ww, while for others only asymptotic expressions can be found. Of particular interest is the zero-force surface -- the manifold in (a,b,c)(a,b,c)-space where the free energy is independent of ww, and the loss of entropy due to confinement in the slit is exactly balanced by the energy gained from interactions with the walls.

Keywords

Cite

@article{arxiv.1912.00151,
  title  = {Semi-flexible directed polymers in a strip with attractive walls},
  author = {Nicholas R. Beaton and Leo Li and Jonathon Liu and Thomas Wong},
  journal= {arXiv preprint arXiv:1912.00151},
  year   = {2019}
}

Comments

25 pages, 10 figures