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We have studied the neutron diffuse scattering in the relaxor PMN. The diffuse scattering appears around the Burns temperature (~620K), indicating its origin from the polar nanoregions (PNR). While the relative diffuse intensities are…

Materials Science · Physics 2009-11-07 K. Hirota , Z. -G. Ye , S. Wakimoto , P. M. Gehring , G. Shirane

We present a combined single-crystal x-ray diffuse scattering and ab-initio molecular dynamics study of lead telluride, PbTe. Well-known for its thermoelectric and narrow-gap semiconducting properties, PbTe recently achieved further…

Neutron spectroscopy measurements reveal short-range spin correlations near and above the ferromagnetic-paramagnetic phase transition in manganite materials of the form La$_{1-x}A_{x}$MnO$_{3}$, including samples with an insulating ground…

Soft X-ray resonant scattering studies at the Mn $L_{\texttt{II, III}}$- and the La $M_{\texttt{IV, V}}$- edges of single-crystal LaSr$_2$Mn$_2$O$_7$ are reported. At low temperatures, below $T_\texttt{N} \approx 160$ K, energy scans with a…

Strongly Correlated Electrons · Physics 2014-07-08 H. -F. Li , Y. Su , Tapan Chatterji , A. Nefedov , J. Persson , P. Meuffels , Y. Xiao , Th. Brückel

Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ is one of the simplest representatives of the class of lead relaxors and often serves as a model system for more complicated compounds. In this paper we analyse both polarized and depolarized Raman scattering…

Materials Science · Physics 2009-11-10 Oleksiy Svitelskiy , Jean Toulouse , Z. -G. Ye

Elastic neutron scattering experiments performed in semi-conducting La(1-x)Ca(x)MnO3 single crystals (x=0.05, 0.08), reveal new features in the problem of electronic phase separation and metal insulator transition. Below TN, the observation…

Strongly Correlated Electrons · Physics 2009-10-31 M. Hennion , F. Moussa , G. Biotteau , J. Rodriguez-Carvajal , L. Pinsard , A. Revcolevschi

Using neutron pair distribution function (PDF) analysis over the temperature range from 1000 K to 15 K, we demonstrate the existence of local polarization and the formation of medium-range, polar nanoregions (PNRs) with local rhombohedral…

Disordered Systems and Neural Networks · Physics 2009-11-10 I. -K. Jeong , T. W. Darling , J. K. Lee , Th. Proffen , R. H. Heffner , J. S. Park , K. S. Hong , W. Dmowski , T. Egami

The existence of exchange-coupled Ni$^{2+}$ ions -- the so-called magnetic dimers -- in wolframite-type NiWO$_4$ and Zn$_c$Ni$_{1-c}$WO$_4$ solid solutions with high nickel content was discovered by X-ray absorption spectroscopy combined…

Materials Science · Physics 2021-08-09 G. Bakradze , A. Kalinko , A. Kuzmin

High energy (67 keV) x-ray diffuse scattering measurements were performed on single crystals of Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$-$x$PbTiO$_3$ (PZN-$x$PT). A novel technique was developed to map out the diffuse scattering distribution in all…

Materials Science · Physics 2007-05-23 Guangyong Xu , Z. Zhong , H. Hiraka , G. Shirane

Synchrotron x-ray scattering studies of anti-ferroelectric nanoregions (AFR) as fluctuations, which give rise to 1/2(hk0) superlattice reflections (alpha spots), were systematically performed in Pb(Mg1/3Nb2/3)O3 (PMN) ferroelectric relaxor.…

Materials Science · Physics 2007-05-23 A. Tkachuk , Haydn Chen

We have investigated the magnetic diffuse scattering of isostructural $S$ = 5/2 fcc antiferromagnets Ba$_2$MnTeO$_6$ and Ba$_2$MnWO$_6$ using polarized neutrons. Both materials display short-range correlated magnetism above their respective…

The low-energy part of vibration spectrum in PbMg$_{1/3}$Nb$_{2/3}$O$_3$ relaxor ferroelectric was studied by inelastic neutron scattering. We observed the coexistence of a resolution-limited central peak with strong quasielastic…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , S. G. Lushnikov , B. Roessli

We report measurements of the neutron diffuse scattering from a single crystal of the relaxor ferroelectric Pb(Zn_1/3Nb_2/3)O_3 doped with 8% PbTiO_3 (PZN-8%PT) for temperatures 100 K < T < 530 K and electric fields 0 kV/cm < E < 10 kV/cm.…

Materials Science · Physics 2009-11-10 P. M. Gehring , K. Ohwada , G. Shirane

The quadrupolar splittings of perdeuteriated n-decane dissolved in nematic phases formed by mesogenic dimers of the CBnCB series, for n=7,9,10,11 are measured throughout the entire temperature range of these phases. The results of the…

Crystalline Bi5NbO10 nanoparticles have been achieved through a modified sol-gel process using a mixture of ethylenediamine and ethanolamine as a solvent. The Bi5NbO10 nanoparticles were characterized by X-ray diffraction (XRD),…

Materials Science · Physics 2009-10-26 Jungang Hou , Rahul Vaish , Yuanfang Qu , Dalibor Krsmanovica , K. B. R. Varmac , R. V. Kumara

Relaxor ferroelectrics have been a focus of intense attention due to their anomalous dielectric characteristics, diffuse phase transitions, and strong piezoelectricity. Understanding the structure and dynamics of relaxors has been one of…

Materials Science · Physics 2013-12-09 Hiroyuki Takenaka , Ilya Grinberg , Andrew M. Rappe

Microstrctural, vibrational, ferroelectric and dielectric properties investigation reveals non-stoichiometric chemical ordered regions (CORs) and relaxor like dielectric characteristics in lead magnesium niobate (PMN) ceramics uniaxially…

Materials Science · Physics 2018-10-03 Adityanarayan H. Pandey , Surya M. Gupta , Vasant G. Sathe , Niranjan P. Lalla

Macroscopic polarity and its dynamic response to external electric fields and temperature in the nominally ergodic relaxor phase of pristine lead magnesium niobate crystals and ceramics, Pb(Mg1/3Nb2/3)O3 (PMN), were investigated. Dynamic…

Materials Science · Physics 2020-11-06 Lukas M. Riemer , Kanghyun Chu , Yang Li , Hana Ursic , Andrew J. Bell , Brahim Dkhil , Dragan Damjanovic

The intermolecular interactions in the title compound are investigated using self-consistent charge density functional based tight binding molecular dynamics. Emphasis is put on the analysis of correlated motions of ion pairs using ideas of…

Chemical Physics · Physics 2016-03-22 Tobias Zentel , Oliver Kühn

High energy resolution neutron spin-echo spectroscopy has been used to measure intrinsic width of diffuse scattering discovered earlier in relaxor ferroelectric crystals. The anisotropic and transverse components of the scattering have been…

Materials Science · Physics 2017-09-13 Sergey Vakhrushev , Alexandre Ivanov , Jiri Kulda