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We propose a simple phenomenological picture to explain the unusual dielectric properties of the proto-typical ferroelectric relaxor lead magnesium niobate-titanate (PMN-PT). Our model assumes a specific, slowly changing, displacement…

Materials Science · Physics 2011-01-11 A. Bosak , D. Chernyshov , S. Vakhrushev , M. Krisch

The relaxor ferroelectric PbMg_1/3Ta_2/3O_3 was studied by single-crystal neutron and synchrotron x-ray diffraction and its detailed atomic structure has been modeled in terms of static Pb-displacements that lead to the formation of polar…

Diffuse neutron scattering is a valuable tool to obtain information about the size and orientation of the polar nanoregions that are a characteristic feature of relaxor ferroelectrics. In this paper, we present new diffuse scattering…

Materials Science · Physics 2009-11-07 D. La-Orauttapong , J. Toulouse , Z. -G. Ye , R. Erwin , J. L. Robertson , W. Chen

Diffuse scattering around the (110) reciprocal lattice point has been investigated by elastic neutron scattering in the paraelectric and the relaxor phases of the disordered complex perovskite crystal-Pb(Zn1/3Nb2/3)O3(PZN). The appearance…

Materials Science · Physics 2009-11-07 D. La-Orauttapong , J. Toulouse , J. L. Robertson , Z. -G. Ye

We present neutron diffraction, dielectric permittivity and photoconductivity measurements, evidencing that lead-magnesium niobate experiences a diffuse phase transformation between the spherical glass and quadrupole glass phases, in the…

High-pressure and variable temperature single crystal synchrotron X-ray measurements combined with first-principles based molecular dynamics simulations study diffuse scattering in the relaxor ferroelectric system PSN…

Materials Science · Physics 2015-05-13 P. Ganesh , E. Cockayne , M. Ahart , R. E. Cohen , B. Burton , R. J. Hemley , Yang Ren , Wenge Yang , Z-G Ye

The short range ordered magnetic correlations have been studied in half doped La0.5Ca0.5-xSrxMnO3 (x = 0.1, 0.3 and 0.4) compounds by polarized neutron scattering technique. On doping Sr2+ for Ca2+ ion, these compounds with x = 0.1, 0.3,…

Materials Science · Physics 2015-05-18 I. Dhiman , A. Das , R. Mittal , Y. Su , A. Kumar , A. Radulescu

We have performed a series of neutron diffuse scattering measurements on a single crystal of the solid solution Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$ (PZN) doped with 8% PbTiO$_3$ (PT), a relaxor compound with a Curie temperature T$_C \sim 450$ K,…

Materials Science · Physics 2009-11-11 Guangyong Xu , P. M. Gehring , G. Shirane

Short-range polar orders in the relaxor ferroelectric material PbMg$_{1/3}$Nb$_{2/3}$O$_3$-$28\%$PbTiO$_3$ (PMN-28PT) have been studied using neutron diffuse scattering. An external electric field along [110] direction can affect the…

Materials Science · Physics 2019-08-07 Zhijun Xu , Fei Li , Shujun Zhang , Christopher Stock , Jun Luo , Peter M. Gehring , Guangyong Xu

We have characterized the dynamics of the polar nanoregions in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) through high-resolution neutron backscattering and spin-echo measurements of the diffuse scattering cross section. We find that the diffuse…

Materials Science · Physics 2015-05-18 C. Stock , L. Van Eijck , P. Fouquet , M. Maccarini , P. M. Gehring , Guangyong Xu , H. Luo , X. Zhao , J. -F. Li , D. Viehland

Neutron elastic diffuse scattering experiments performed on Pb(Zn1/3Nb2/3)O3 (PZN) and on its solid solution with PbTiO3(PT), known as PZN-xPT, with x=4.5% and 9% around many reflections show that diffuse scattering is observed around…

Materials Science · Physics 2009-11-07 D. La-Orauttapong , J. Toulouse , Z. -G. Ye , W. Chen , R. Erwin , J. L. Robertson

We have performed elastic diffuse neutron scattering studies on the relaxor Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$ (PMN). The measured intensity distribution near a (100) Bragg peak in the (hk0) scattering plane assumes the shape of a butterfly with…

Materials Science · Physics 2009-11-10 Guangyong Xu , G. Shirane , J. R. D. Copley , P. M. Gehring

We discovered a near room temperature lead-free relaxor-ferroelectric (Ba0.6Bi0.2Li0.2)TiO3 (BBLT) having A-site compositional disordered ABO3 perovskite structure. Microstructure-property relations revealed that the chemical…

Materials Science · Physics 2016-06-22 Hitesh Borkar , Vaibhav Rao , Soma Dutta , Arun Barvat , Prabir Pal , M Tomar , Vinay Gupta , J. F. Scott , Ashok Kumar

A review is given of recent neutron and x-ray scattering studies of the lead-oxide perovskite relaxor systems Pb(Zn1/3Nb2/3)O3-xPbTiO3 and Pb(Mg1/3Nb2/3)O3-xPbTiO3. X-ray measurements by Noheda et al. have established that these two systems…

Strongly Correlated Electrons · Physics 2007-05-23 G. Shirane , Guangyong Xu , P. M. Gehring

Neutron elastic, inelastic and high energy x-ray scattering techniques are used to explore the nature of the polaron order and dynamics in La0.7Ca0.3MnO3. Static polaron correlations develop within a narrow temperature regime as the Curie…

Strongly Correlated Electrons · Physics 2007-08-02 J. W. Lynn , D. N Argyriou , Y. Ren , Y. Chen , Y. M. Mukovskii , D. A. Shulyatev

Neutron scattering investigations were carried out in PbMg$_{1/3}$Ta$_{2/3}$O$_3$ and BaMg$_{1/3}$Ta$_{2/3}$O$_3$ complex perovskites. The crystal structure of both compounds does not show any phase transition in the temperature range 1.5…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , B. Roessli , D. Sheptyakov , S. G. Lushnikov , T. A. Shaplygina

The temperature dependent dielectric properties revealed re-entrant relaxor behaviour (Tm ~130 K and 210 K for 1 kHz) below a high temperature diffused phase transition, Tc ~270 K in lead cobalt niobate (PCN). Multiple positive/negative…

Materials Science · Physics 2018-10-30 Adityanarayan H. Pandey , Surya Mohan Gupta

We have used element specific X-ray resonant scattering to investigate the M edge resonances in a single crystal of \unpo. Earlier neutron diffraction and M\"{o}ssbauer studies had shown the presence of long-range AF order below T$_{N}$ =…

Strongly Correlated Electrons · Physics 2009-11-10 S. B. Wilkins , J. A. Paxiao , R. Caciuffo , P. Javorsky , F. Wastin , J. Rebizant , C. Detlefs , N. Bernhoeft , P. Santini , G. H. Lander

We report measurements of the neutron diffuse scattering in a single crystal of the relaxor ferroelectric material 95.5%Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$-4.5%PbTiO$_3$ (PZN-4.5%PT). Our results suggest that the nanometer scale structure in this…

Materials Science · Physics 2010-11-10 Zhijun Xu , Jinsheng Wen , Guangyong Xu , C. Stock , J. S. Gardner , P. M. Gehring

The temperature dependence of the superlattice reflections: a) F spots and b) alpha spots in a lead magnesium niobate (PMN) single crystals containing 0% and 6% of PbTiO3 (PT) has been studied using synchrotron x-ray scattering techniques.…

Materials Science · Physics 2015-06-24 A. Tkachuk , Paul Zschack , Eugene Colla , Haydn Chen
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