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We investigate spherical macroions in the strong Coulomb coupling regime within the primitive model in salt-free environment. We first show that the ground state of an isolated colloid is naturally overcharged by simple electrostatic…

Soft Condensed Matter · Physics 2016-08-16 René Messina , Christian Holm , Kurt Kremer

Like-charged macroions attract each other as a result of strong electrostatic correlations in the presence of multivalent counterions or at low temperatures. We investigate the effective electrostatic interaction between i) two like-charged…

Soft Condensed Matter · Physics 2007-05-23 Ali Naji , Roland R. Netz

By a length scale analysis, we study the equilibrium interactions between two like-charge planes confining neutralising counter-ions. At large Coulombic couplings, approaching the two charged bodies leads to an unbinding of counter-ions, a…

Soft Condensed Matter · Physics 2012-10-23 E. Trizac , L. Samaj

Charged soft-matter systems--such as colloidal dispersions and charged polymers--are dominated by attractive forces between constituent like-charged particles when neutralizing counterions of high charge valency are introduced. Such…

Soft Condensed Matter · Physics 2009-11-11 Ali Naji , Swetlana Jungblut , Andre G. Moreira , Roland R. Netz

A simple model is presented for the appearance of attraction between two like charged polyions inside a polyelectrolyte solution. The polyions are modeled as rigid cylinders in a continuum dielectric solvent. The strong electrostatic…

Soft Condensed Matter · Physics 2009-10-31 Alexandre Diehl , Humberto A. Carmona , Yan Levin

Strong short ranged positional correlations involving counterions can induce a net attractive force between negatively charged strands of DNA, and lead to the formation of ion pairs in dilute ionic solutions. But the long range of the…

Statistical Mechanics · Physics 2009-11-11 Yng-Gwei Chen , John D. Weeks

We study the effective interaction mediated by strongly coupled Coulomb fluids between dielectric surfaces carrying quenched, random monopolar charges with equal mean and variance, both when the Coulomb fluid consists only of mobile…

Soft Condensed Matter · Physics 2020-10-01 Malihe Ghodrat , Ali Naji , Haniyeh Komaie-Moghaddam , Rudolf Podgornik

We present a simple model for the possible mechanism of appearance of attraction between like charged polyions inside a polyelectrolyte solution. The attraction is found to be short ranged, and exists only in presence of multivalent…

Soft Condensed Matter · Physics 2009-10-31 Jeferson J. Arenzon , Juergen F. Stilck , Yan Levin

We study the interaction potential between two polyions inside a colloidal suspension. It is shown that at large separation the interaction potential is purely repulsive, with the induced attractive interactions being doubly screened. For…

Soft Condensed Matter · Physics 2015-06-25 Yan Levin

We present an analytical approach to the strong coupling regime of similarly and highly charged plates in the presence of counter-ions. The procedure is physically transparent and based on an exact expansion around the ground state formed…

Statistical Mechanics · Physics 2011-02-23 L. Samaj , E. Trizac

We are interested in rationalizing the phenomenon of like-charge attraction between charged bodies, such as a pair of colloids, in the strong coupling regime. The two colloids are modelled as uniformly charged parallel plates, neutralized…

Soft Condensed Matter · Physics 2025-01-13 L. Samaj , E. Trizac , M. Trulsson

We present an overview of our understanding of electrostatic interactions between charged macromolecular surfaces mediated by mobile counter- and coions. The dichotomy between the weak and the strong coupling regimes is described in detail…

Soft Condensed Matter · Physics 2016-12-21 Ali Naji , Matej Kanduc , Roland R. Netz , Rudolf Podgornik

Despite decades of intensive studies, the effective interactions between strongly charged colloids still remain elusive. Here we show that a strongly charged surface with a layer of condensed counter- ions behaves effectively as a…

Soft Condensed Matter · Physics 2011-07-12 Xiangjun Xing , Zhenli Xu , Hongru Ma

Strong coupling phenomena, such as the like charged macroions attraction, opposite charged macroions repulsion, charge renormalization or charge inversion, are known to be mediated by multivalent counterions. Most theories treat the…

Soft Condensed Matter · Physics 2016-02-03 Sandipan Dutta , Y. S. Jho

It is known that in a water solution with multivalent counterions (Z-ions), two likely charged macroions can attract each other due to correlations of Z-ions adsorbed on their surfaces. This "correlation" attraction is short-ranged and…

Soft Condensed Matter · Physics 2009-11-10 Rui Zhang , B. I. Shklovskii

The electrostatic double layer force is key to determining the stability and self-assembly of charged colloids and many other soft matter systems. Fully understanding the attractive force between two like-charged surfaces remains a great…

Soft Condensed Matter · Physics 2024-02-27 Nikhil R. Agrawal , Ravtej Kaur , Carlo Carraro , Rui Wang

We propose a mean-field analytical model to account for the observed asymmetry in the ability to form long-range attraction by the negatively charged colloidal particles and not their equivalently charged positive counterpart. We conjecture…

Soft Condensed Matter · Physics 2009-11-13 William Kung , Monica Olvera de la Cruz

Over the past few decades the experimental literature has consistently reported observations of attraction between like-charged colloidal particles and macromolecules in solution. Examples include nucleic acids and colloidal particles in…

Soft Condensed Matter · Physics 2020-04-22 Alzbeta Kubincova , Philippe H. Hunenberger , Madhavi Krishnan

Charge-stabilized colloidal spheres dispersed in deionized water are supposed to repel each other. Instead, artifact-corrected video microscopy measurements reveal an anomalous long-ranged like-charge attraction in the interparticle pair…

Soft Condensed Matter · Physics 2009-11-11 Marco Polin , David G. Grier , Yilong Han

We study the effective electrostatic interactions between a pair of charged colloidal particles without salt ions while the system is confined in two dimensions. In particular we use a simplified model to elucidate the effects of rotational…

Soft Condensed Matter · Physics 2010-09-09 Chi-Lun Lee , Sio-Kit Ng
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