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We develop a general formalism to investigate the effect of quenched fixed charge disorder on effective electrostatic interactions between charged surfaces in a one-component (counterion-only) Coulomb fluid. Analytical results are…

Soft Condensed Matter · Physics 2009-11-11 Ali Naji , Rudolf Podgornik

We present general arguments for the importance, or lack thereof, of the structure in the charge distribution of counterions for counterion-mediated interactions between bounding symmetrically charged surfaces. We show that on the mean…

Soft Condensed Matter · Physics 2015-05-13 M. Kanduc , A. Naji , Y. S. Jho , P. A. Pincus , R. Podgornik

We perform a study of the interfacial properties of a model suspension of hard sphere colloids with diameter $\sigma_c$ and non-adsorbing ideal polymer coils with diameter $\sigma_p$. For the mixture in contact with a planar hard wall, we…

Soft Condensed Matter · Physics 2009-11-11 Andrea Fortini , Marjolein Dijkstra , Matthias Schmidt , Paul P. F. Wessels

Studies of the thermodynamics of complex coacervation of pairs of symmetric, strongly ionizable, oppositely charged polyelectrolyte chains are abundant. To generalize such understanding to asymmetric chain lengths and variable ionizability…

Soft Condensed Matter · Physics 2023-06-07 Souradeep Ghosh , Soumik Mitra , Arindam Kundagrami

An analytical description of polymer melts and their mixtures as liquids of interacting soft colloidal particles is obtained from liquid-state theory. The derived center-of-mass pair correlation functions with no adjustable parameters…

Soft Condensed Matter · Physics 2009-11-10 G. Yatsenko , E. J. Sambriski , M. A. Nemirovskaya , M. Guenza

The dependencies of charged particle pseudorapidity density and transverse energy pseudorapidity density at midrapidity on the collision energy and on the number of nucleon participants, or centrality, measured in nucleus-nucleus collisions…

High Energy Physics - Phenomenology · Physics 2015-04-01 Aditya Nath Mishra , Raghunath Sahoo , Edward K. G. Sarkisyan , Alexander S. Sakharov

A variational approach is used to calculate free energy and conformational properties in polyelectrolytes. The true bond and Coulomb potentials are approximated by a trial isotropic harmonic energy containing monomer-monomer force constants…

High Energy Physics - Lattice · Physics 2009-09-25 B. Jönsson , C. Peterson , B. Söderberg

We present a theoretical model to study the effect of counterion size on the effective charge, size, and thermodynamic behavior of a single, isolated, and flexible polyelectrolyte (PE) chain. We analyze how altering counterion size modifies…

Soft Condensed Matter · Physics 2023-10-18 Souradeep Ghosh , Arindam Kundagrami

We theoretically study the polarizability and the interactions of neutral complexes consisting of a semi-flexible polyelectrolyte adsorbed onto an oppositely charged spherical colloid. In the systems we studied, the bending energy of the…

Soft Condensed Matter · Physics 2009-11-07 J. Dzubiella , A. G. Moreira , P. A. Pincus

The dynamics of colloidal particles in potential energy landscapes have mainly been investigated theoretically. In contrast, here we discuss the experimental realization of potential energy landscapes with the help of light fields and the…

When a colloid is mixed with a depletant such as a non-adsorbing polymer, one observes attractive effective interactions between the colloidal particles. If these particles are anisotropic, analysis of these effective interactions is…

Soft Condensed Matter · Physics 2016-09-08 Clement Law , Douglas J. Ashton , Nigel B. Wilding , Robert L. Jack

Motivated by the intriguing phase behavior of charged colloidal platelets, we investigate the structure and dynamics of charged repulsive disks by means of Monte-Carlo simulations. The electrostatic interactions are taken into account…

Soft Condensed Matter · Physics 2015-03-17 Sara Jabbari-Farouji , Jean-Jacques Weis , Patrick Davidson , Pierre Levitz , Emmanuel Trizac

A highly-charged spherical colloid in a salt-free environment exerts such a powerful attraction on its counterions that a certain fraction condenses onto the surface of a particle. The degree of condensation depends on the curvature of the…

We calculate the effective potentials of the octet baryon and heavy meson systems using the chiral effective field theory up to the next-to-leading order. We consider the contact terms, one-pseudoscalar-meson and two-pseudoscalar-meson…

High Energy Physics - Phenomenology · Physics 2024-12-12 Bo-Lin Huang , Bo Wang , Shi-Lin Zhu

Monolayers of colloidal particles at oil-water interfaces readily crystalize owing to electrostatic repulsion, which is often mediated through the oil. However, little attempts exist to control it using oil-soluble electrolytes. We probe…

Soft Condensed Matter · Physics 2023-05-04 Carolina van Baalen , Jacopo Vialetto , Lucio Isa

In its original formulation, the seminal Deryaguin-Landau-Verwey-Overbeek (DLVO) theory of colloidal stability seemed like a simple but realistic description of the world of colloid interactions in electrolyte solutions. It is based on a…

Soft Condensed Matter · Physics 2021-01-06 Rudolf Podgornik , David Andelman

We generalize the concept of charge regulation of ionic solutions, and apply it to complex fluids with mobile macro-ions having internal non-electrostatic degrees of freedom. The suggested framework provides a convenient tool for…

Soft Condensed Matter · Physics 2018-01-17 Tomer Markovich , David Andelman , Rudi Podgornik

We study thermal equilibrium of classical pointlike counterions confined between symmetrically charged walls at distance $d$. At very large couplings when the counterion system is in its crystal phase, a harmonic expansion of particle…

Soft Condensed Matter · Physics 2019-01-21 L. Samaj , M. Trulsson , E. Trizac

We investigate the influence of geometric confinement on the free energy of an idealized model for charge-stabilized colloidal suspensions. The mean-field Poisson-Boltzmann formulation for this system predicts pure repulsion among…

Soft Condensed Matter · Physics 2009-11-07 Ajay Gopinathan , Tong Zhou , S. N. Coppersmith , L. P. Kadanoff , David G. Grier

In this paper, we present a continuation of our research on modeling electrolyte solutions within charged slit pores. We make use of the model developed by Blossey et al., which takes into account the structural interactions between ions…

Soft Condensed Matter · Physics 2023-07-26 Victoria A. Vasileva , Daria A. Mazur , Yury A. Budkov
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