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We present the first analytical study of stability loss and evolution of domain structure in inhomogeneous ferroelectric samples for exactly solvable model. The model assumes a short-circuited capacitor with two regions with slightly…

Statistical Mechanics · Physics 2009-11-07 A. M. Bratkovsky , A. P. Levanyuk

Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

Materials Science · Physics 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

In steels and single-crystal superalloys the control of the formation of topologically close-packed (TCP) phases is critical for the performance of the material. The structural stability of TCP phases in multi-component transition-metal…

Materials Science · Physics 2016-05-18 Thomas Hammerschmidt , Arthur F. Bialon , David G. Pettifor , Ralf Drautz

Simulations of nematic-isotropic transition of liquid crystals in two dimensions are performed using an O(2) vector model characterised by non linear nearest neighbour spin interaction governed by the fourth Legendre polynomial $P\_4$. The…

Statistical Mechanics · Physics 2016-08-16 Ana Fariñas-Sanchez , Ricardo Paredes , Bertrand Berche

We carry out a completely first-principles study of the ferroelectric phase transitions in BaTiO$_3$. Our approach takes advantage of two features of these transitions: the structural changes are small, and only low-energy distortions are…

mtrl-th · Physics 2016-09-07 W. Zhong , David Vanderbilt , K. M. Rabe

The coexistence of different ferroelectric phases enables the tunability of the macroscopic properties and extensive applications from piezoelectric transducers to nonvolatile memories. Here we develop a thermodynamic model to predict the…

Materials Science · Physics 2022-01-26 Yang Zhang , Fei Xue , Bo Wang , Jia-Mian Hu , Shuai Dong , Jun-Ming Liu , Long-Qing Chen

Crystallization is a key for ferroelectricity which is a collective behavior of microscopic electric dipoles. On the other hand, uncontrolled crystallization leads to uneven morphology and random crystal orientations, which undermines the…

Materials Science · Physics 2022-05-10 Yifan Yuan , Yuanyuan Ni , Xuanyuan Jiang , Yu Yun , Xiaoshan Xu

HfO$_{2}$-based ferroelectric thin films are promising for their application in ferroelectric devices. Predicting the ultimate magnitude of polarization and understanding its switching mechanism are critical to realize the optimal…

Materials Science · Physics 2023-04-04 Yao Wu , Yuke Zhang , Jie Jiang , Limei Jiang , Minghua Tang , Yichun Zhou , Min Liao , Qiong Yang , Evgeny Y. Tsymbal

Exploring the vast composition space of multi-component alloys presents a challenging task for both \textit{ab initio} (first principles) and experimental methods due to the time-consuming procedures involved. This ultimately impedes the…

Single crystals of $(Cd_{1-x} Zn_x)_3 As_2$ were synthesized from high-temperature solutions and characterized in terms of their structural and electrical properties. Based on the measurements of resistivity and Hall signals, we revealed a…

Materials Science · Physics 2017-12-21 Hong Lu , Xiao Zhang , Shuang Jia

Phase-Field Crystal (PFC) models are able to resolve atomic length scale features of materials during temporal evolution over diffusive time scales. Traditional PFC models contain solid and liquid phases, however many important materials…

Materials Science · Physics 2015-06-16 Edwin J. Schwalbach , James A. Warren , Kuo-An Wu , Peter W. Voorhees

Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…

Soft Condensed Matter · Physics 2026-02-19 Calum J Gibb , Jordan Hobbs , William C Ogle , Richard J Mandle

The perovskite-like ferroelectric system PbZr(1-x)Ti(x)O3 (PZT) has a nearly vertical morphotropic phase boundary (MPB) around x=0.45-0.50. Recent synchrotron x-ray powder diffraction measurements by Noheda et al. [Appl. Phys. Lett. 74,…

Materials Science · Physics 2009-10-31 B. Noheda , J. A. Gonzalo , L. E. Cross , R. Guo , S-E. Park , D. E. Cox , G. Shirane

An effective Hamiltonian for the ferroelectric transition in $PbTiO_3$ is constructed from first-principles density-functional-theory total-energy and linear-response calculations through the use of a localized, symmetrized basis set of…

mtrl-th · Physics 2009-10-28 K. M. Rabe , U. V. Waghmare

Ferroelectrics are widely used for a broad array of technological applications due to their attractive electrical and electromechanical properties. In order to obtain large functional properties, material compositions are often designed to…

Materials Science · Physics 2025-01-31 Abhijit Pramanick , Laurent Daniel

Prediction of properties from composition is a fundamental goal of materials science and can greatly accelerate development of functional materials. It is particularly relevant for ferroelectric perovskite solid solutions where…

Neutron scattering has been used to study the nature of the ferromagnetic transition in single crystals of La_0.7Ca_0.3MnO_3 and La_0.8Ca_0.2MnO_3, and polycrystalline samples of La_0.67Ca_0.33MnO_3 and La_5/8Ca_3/8MnO_3 where the naturally…

Strongly Correlated Electrons · Physics 2009-11-10 C. P. Adams , J. W. Lynn , V. N. Smolyaninova , A. Biswas , R. L. Greene , W. Ratcliff , S-W. Cheong , Y. M. Mukovskii , D. A. Shulyatev

Here, we provide a detailed study of the crystal structure and physical properties of the recently discovered vdW ferromagnet FePd$_2$Te$_2$. We find this compound has a relatively wide width of formation, and grow single crystals with…

Strongly Correlated Electrons · Physics 2025-11-25 Rafaela F. S. Penacchio , Siham Mohamed , Sérgio L. Morelhão , Sergey L. Bud'ko , Paul C. Canfield , Tyler J. Slade

Electric field plays an important role in ferroelectric phase transition. There have been numerous phase field formulations attempting to account for electrostatic interactions subject to different boundary conditions. In this paper, we…

Computational Physics · Physics 2019-10-18 Qiang Du , Ruotai Li , Lei Zhang

We present a comprehensive study on the low-temperature orthorhombic phase of Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ based on the Korringa-Kohn-Rostoker-Green function approach. Using this bandstructure method in combination with the coherent…

Superconductivity · Physics 2014-11-19 Gerald Derondeau , Svitlana Polesya , Sergiy Mankovsky , Hubert Ebert , Ján Minár