English

Formation and rapid evolution of domain structure at phase transitions in slightly inhomogeneous ferroelectrics

Statistical Mechanics 2009-11-07 v2 Materials Science

Abstract

We present the first analytical study of stability loss and evolution of domain structure in inhomogeneous ferroelectric samples for exactly solvable model. The model assumes a short-circuited capacitor with two regions with slightly different critical temperatures Tc1 > Tc2, where Tc1-Tc2 << Tc1, Tc2. Even a tiny inhomogeneity like 10-5 K may result in splitting the system into domains below the phase transition temperature. At T < Tc2 the domain width aa is proportional to (Tc1 - T)/(Tc1 - Tc2) and quickly increases with lowering temperature. The minute inhomogeneities in Tc may result from structural (growth) inhomogeneities which are always present in real samples and a similar role can be played by inevitable temperature gradients.

Keywords

Cite

@article{arxiv.cond-mat/0112001,
  title  = {Formation and rapid evolution of domain structure at phase transitions in slightly inhomogeneous ferroelectrics},
  author = {A. M. Bratkovsky and A. P. Levanyuk},
  journal= {arXiv preprint arXiv:cond-mat/0112001},
  year   = {2009}
}

Comments

5 pages, 2 figures, discussion expanded and references added to experiments on graded ferroelectrics and ferroelectric superlattices