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The parent compounds of the recently discovered iron-arsenic (pnictide) high temperature superconductors transition into an intriguing spin density wave (SDW) phase at low temperatures. Progress in understanding this SDW state has been…

For $\rm Sn_2P_2S_6$ ferroelectrics by first-principles calculations an analysis of the $\rm P_2S_6$ cluster electronic structure and their comparison with crystal valence band in paraelectric and ferroelectric phases has been done and the…

Materials Science · Physics 2015-03-19 Konstantin Glukhov , Kristina Fedyo , Yulian Vysochanskii

We report the ferroelectric property in Tb2Ti2O7 pyrochlore, prepared by a two-step solid-state reaction method. A concave P-E (polarisation vs electric field) loop observed from 382 K confirms ferroelectricity, below which the loop remains…

Materials Science · Physics 2021-02-03 B. Santhosh Kumar , Rajesh Narayana Perumal , C. Venkateswaran

Li2SrNb2O7 (LSNO) crystallizes in a structure closely related to n = 2 Ruddlesden-Popper-type compounds, which is gen-erally formed by intergrowth of 2-dimensional perovskite-type blocks and rocksalt-type layers. The present study…

Layered perovskites $A_3M_2$O$_7$ are known to exhibit the so-called hybrid improper ferroelectricity. Despite experimentally confirmed cases (e.g. nonmagnetic $M$=Ti and Sn), the ferroelectricity in magnetic Ca$_3$Mn$_2$O$_7$ remains a…

PbTiO3 has the highest tetragonal distortion (c/a=1.064) and highest spontaneous polarization among perovskite titanates. But, it is hazardous and hence one needs to reduce Pb content by substituting or reducing Pb content for use in…

By means of density functional theory the electronic structure of the MgB2 superconductor was characterised and compared with that of the related iso-structural systems: AlB2, ZrB2, NbB2, and TaB2. Using the full-potential linearized…

Superconductivity · Physics 2009-11-07 Pablo de la Mora , Miguel Castro , Gustavo Tavizon

The alkaline earth binary oxides adopt a simple rocksalt structure and form an important family of compounds because of their large presence in the earth's mantle and their potential use in microelectronic devices. In comparison to the…

Materials Science · Physics 2021-04-06 Eric Bousquet , Nicola A. Spaldin , Philippe Ghosez

The electronic structure of fluorite crystals are studied by means of density functional theory within the local density approximation for the exchange correlation energy. The ground-state electronic properties, which have been calculated…

Materials Science · Physics 2011-08-01 Emiliano Cadelano , Giancarlo Cappellini

In ferroelectrics, complex interactions among various degrees of freedom enable the condensation of topologically protected polarization textures. Known as ferroelectric solitons, these particle-like structures represent a new class of…

Materials Science · Physics 2023-08-02 V. Govinden , P. R. Tong , X. Guo , Q. Zhang , S. Mantri , S. Prokhorenko , Y. Nahas , Y. Wu , L. Bellaiche , H. Tian , Z. Hong , D. Sando , V. Nagarajan

The presence of a switchable spontaneous electric polarization makes ferroelectrics ideal candidates for the use in many applications such as memory and sensors devices. Since known ferroelectrics are rather limited, finding new…

Materials Science · Physics 2016-02-25 Ke Xu , Xue-Zeng Lu , H. J. Xiang

First principles calculations based on the density functional theory within the local spin density approximation plus U(LSDA+U)scheme, show rhombohedral Bi$_2$FeTiO$_6$ is a potential multiferroic in which the magnetism and ferroelectricity…

Materials Science · Physics 2012-12-20 Hong-Jian Feng , Fa-Min Liu

Wide bandgap semiconductors (WBGs) are predicted to be the potential materials for energy generation and storing. In this work, we used density functional theory (DFT) that incorporates generalized gradient approximation (GGA) and…

The Co-doped anatase TiO$_{2}$, a recently discovered room-temperature ferromagnetic insulator, has been studied by the first-principles calculations in the pseudo-potential plane-wave formalism within the local-spin-density approximation…

Materials Science · Physics 2007-05-23 Hongming Weng , Xiaoping Yang , Jinming Dong , H. Mizuseki , M. Kawasaki , Y. Kawazoe

Crystallography and dielectric properties in Dion-Jacobson layered perovskites, CsNdNb$_2$O$_7$ and RbNdNb$_2$O$_7$, have been examined in dense polycrystalline samples, and polarization hysteresis loops that substantiate ferroelectricity…

The electronic structure of HfZn$_{2}$ has been studied based on the density functional theory within the local-density approximation. The calculation indicates that HfZn$_{2}$ shows ferromagnetic instability. Large enhancement of the…

Strongly Correlated Electrons · Physics 2009-11-11 T. Jeong

The stability of high-symmetry $P4mm$ polar phase in eleven ferroelectric perovskite superlattices with the polar discontinuity is studied from first principles. In most superlattices, this phase exhibits either the ferroelectric or the…

Materials Science · Physics 2021-09-03 Alexander I. Lebedev

Presence of excitons significantly influence the optoelectronic properties and potential applications of materials. Using combined theoretical and experimental tools, we investigate the absorption spectra of $d^0$ double perovskite oxides…

Using first-principles calculations, we predict that tunable ferroelectricity can be realized in oxide perovskites with the Grenier structure and ordered oxygen vacancies. Specifically, we show that $R_{1/3}A_{2/3}\mathrm{FeO}_{2.67}$…

Materials Science · Physics 2023-07-12 Yongjin Shin , Giulia Galli

In this research paper, we investigated the structural, electronic, and magnetic features of titanium atom substituting calciumatom in rock salt structure of CaS to explore the new dilute magnetic semiconductor compounds. The calculations…

Materials Science · Physics 2022-02-16 Meryem Ziati , Hamid Ez-Zahraouy