Related papers: Polymer Stretching by Turbulence
The dynamics of elastocapillary thinning in high molecular weight polymer solutions are re-examined using high-speed digital video microscopy. At long times, the evolution of the viscoelastic thread deviates from self-similar exponential…
We consider a simple model for steady-state luminescence of single polymer chains in a dilute solution in the case when excitation quenching is due to energy transfer between a donor and an acceptor attached to the ends of the chain. We…
We investigate theoretically and numerically the effect of polymer additives on two-dimensional turbulence by means of a viscoelastic model. We provide compelling evidence that at vanishingly small concentrations, such that the polymers are…
We investigate the effect of polymer additives on a two-dimensional Kolmogorov flow at very low Reynolds numbers by direct numerical simulations of the Oldroyd-B viscoelastic model. We find that above the elastic instability threshold the…
Remarkably, even under negligible inertia, the addition of microstructural agents can generate chaotic flow fields. Such behavior can arise in polymer solutions, leading to elastic turbulence, or from active, self-driven particles, which…
We investigate the stretching response of a thick polymer model by means of extensive stochastic simulations. The computational results are synthesized in an analytic expression that characterizes how the force versus elongation curve…
I develop a kinetic mechanism to explain chain folding in polymer crystallization which is based on the competition between the formation of stems, which is due to frequent occupations of trans states along the chains in the supercooled…
A thermodynamically related model is developed for describing elastic rubber-like behavior of amorphous and crystallizing polymers and demonstrated on example of simple extension. Both the “entropic” and “energetic”…
Linear polymers are represented as chains of hopping reptons and their motion is described as a stochastic process on a lattice. This admittedly crude approximation still catches essential physics of polymer motion, i.e. the universal…
The dynamics of elongated inertial particles in an extensional flow is studied numerically by performing simulations of freely jointed bead-rod chains. The coil-stretch transition and the tumbling instability are characterized as a function…
The dynamics of fibres, modelled as a sequence of inertial beads linked via elastic springs, in turbulent flows is dictated by a non-trivial interplay of their inertia and elasticity. Such elastic, inertial fibres preferentially sample a…
By tracking small particles in the bulk of an intensely turbulent flow, we show that even a very small concentration of long-chain polymers disrupts the usual turbulent energy cascade. The polymers affect scales much larger than their…
Recent step strain experiments in well-entangled polymeric liquids demonstrated a bulk fracture-like phenomenon. We have studied this instability using a modern version of the Doi-Edwards theory for entangled polymers, and we find close…
We use nonequilibrium molecular dynamics simulations to verify recent tube-model predictions that associative polymer networks exhibit broad stretch fluctuations during elongational flow. Simulations further show that these fluctuating…
Early turbulence in periodic cylinder arrays is of particular interest in many practical applications to enhance mixing and material/heat exchange. In this study, we reveal a new early transition pathway to a chaotic wavy state and drag…
We make use of the previously developed formalism for a monomer ensemble and include angular dependence of the segments of the polymer chains thus described. In particular we show how to deal with stiffness when the polymer chain is…
Random packings of granular chains are presented as a model polymer system to investigate the contribution of entanglements to strain-stiffening in the absence of Brownian motion. The chain packings are sheared in triaxial compression…
Constitutive equations are derived for the time-dependent behavior of particle-reinforced elastomers at isothermal loading with finite strains. A rubbery polymer is modelled as a network of macromolecules bridged by junctions which can slip…
We analyze the nonequilibrium dynamics of single inextensible semiflexible biopolymers as stretching forces are applied at the ends. Based on different (contradicting) heuristic arguments, various scaling laws have been proposed for the…
Polymer solutions are often injected in porous media for applications such as oil recovery and groundwater remediation. As the fluid navigates the tortuous pore space, elastic stresses build up, causing the flow to become unstable at…