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Apparent Fracture in Polymeric Fluids under Step Shear

Fluid Dynamics 2015-06-04 v3 Soft Condensed Matter

Abstract

Recent step strain experiments in well-entangled polymeric liquids demonstrated a bulk fracture-like phenomenon. We have studied this instability using a modern version of the Doi-Edwards theory for entangled polymers, and we find close quantitative agreement with the experiments. The phenomenon occurs because the viscoelastic liquid is sheared into a rubbery state that possesses an elastic constitutive instability (Marrucci and Grizzuti, 1983). The fracture is a transient manifestation of this instability, which relies on the amplification of spatially inhomogeneous fluctuations. This mechanism differs from fracture in glassy materials and dense suspensions.

Keywords

Cite

@article{arxiv.1204.4169,
  title  = {Apparent Fracture in Polymeric Fluids under Step Shear},
  author = {Okpeafoh S. Agimelen and Peter D. Olmsted},
  journal= {arXiv preprint arXiv:1204.4169},
  year   = {2015}
}

Comments

5 pages,3 figures. Accepted in the Physical Review Letters

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