Related papers: Non-Thermal Chemistry in Diffuse Clouds with Low M…
There is a robust polyatomic chemistry in diffuse, partially-molecular interstellar gas that is readily accessible in absorption at radio/mm/sub-mm wavelengths. Accurate column densities are derived owing to the weak internal excitation, so…
We present a theoretical investigation of CN and HCN molecule formation in dense interstellar clouds. We study the gas-phase CN and HCN production efficiencies from the outer photon-dominated regions (PDRs) into the opaque cosmic-ray…
We discuss the interstellar absorption from many atomic and molecular species seen in high-resolution $HST$/STIS UV and high-S/N optical spectra of the moderately reddened B3-5~V star HD~62542. This remarkable sight line exhibits both very…
We present high-resolution optical spectra (at ~0.6--1.8 km s-1) of interstellar CN, CH, CH^+, \ion{Ca}{1}, \ion{K}{1}, and \ion{Ca}{2} absorption toward 29 lines of sight in three star-forming regions, \rho Oph, Cep OB2, and Cep OB3. The…
Aims. Excitation of far-infrared and submillimetric molecular lines may originate from nonreactive collisions, chemical formation, or far infrared, near-infrared, and optical fluorescences. As a template, we investigate the impact of each…
Cosmological N-body hydrodynamic computations following atomic and molecular chemistry (e$^-$, H, H$^+$, H$^-$, He, He$^+$, He$^{++}$, D, D$^+$, H$_2$, H$_2^+$, HD, HeH$^+$), gas cooling, star formation and production of heavy elements (C,…
In the Halo21 absorption modeling challenge we generated synthetic absorption spectra of the circumgalactic medium (CGM), and attempted to estimate the metallicity, temperature, and density (Z, T, and nH) of the underlying gas using…
We present optical high-resolution spectra of a sample of sixteen post-AGB stars and IRC +10216. Of the post-AGB stars, ten show C2 Phillips and Swan and CN Red System absorption, one CH+ emission, one CH+ absorption, and four without any…
Surprisingly large column densities of H3+ have been detected using infrared absorption spectroscopy in seven diffuse cloud sightlines (Cygnus OB2 12, Cygnus OB2 5, HD 183143, HD 20041, WR 104, WR 118, and WR 121), demonstrating that H3+ is…
Chemical diversity of the gas in low-mass protostellar cores is widely recognized. In order to explore its origin, a survey of chemical composition toward 36 Class 0/I protostars in the Perseus molecular cloud complex, which are selected in…
Interstellar absorption lines up to J"=10 in the (2,0) band and up to J"=6 in the (3,0) band of the C$_2$ $A^1\Pi_u$ - $X^1\Sigma^+_g$ system are detected toward star Cernis 52 (BD+31$^o$ 640) in the Perseus molecular complex. The star lies…
The [CII] fine--structure line at 158um is an excellent tracer of the warm diffuse gas in the ISM and the interfaces between molecular clouds and their surrounding atomic and ionized envelopes. Here we present the initial results from…
A detailed quantum analysis of a ionic reaction with a crucial role in the ISM is carried out to generate ab initio reactive cross sections with a quantum method. From them we obtain the corresponding CH+ depletion rates over a broad range…
We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…
Based on the analysis of available published data and archival data along 24 sightlines (5 of which are new) we derive more accurate estimates of the column densities of OH and CH towards diffuse/translucent clouds and revisit the typically…
We observed the 9-cm Lambda-doubling lines of CH along the dense filament of TMC-1. The CH column densities were compared with the total H2 column densities derived using the 2MASS NIR data and previously published SCUBA maps and with OH…
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The…
In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in…
Using high resolution infrared spectroscopy we have surveyed twenty sightlines for H3+ absorption. H3+ is detected in eight diffuse cloud sightlines with column densities varying from 0.6x10^14 cm^-2 to 3.9x10^14 cm^-2. This brings to…
While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds…