Related papers: Non-Thermal Chemistry in Diffuse Clouds with Low M…
We present analytic theory for the total column density of singly ionized carbon (C+) in the optically thick photon dominated regions (PDRs) of far-UV irradiated (star-forming) molecular clouds. We derive a simple formula for the C+ column…
ABRIDGED: Context: HI and CO large scale surveys of the Milky Way trace the diffuse atomic clouds and the dense shielded regions of molecular hydrogen clouds. However, until recently, we have not had spectrally resolved C+ surveys to…
We have observed CH absorption lines ($J=3/2, N=1 \leftarrow J=1/2, N=1$) against the continuum source Sgr~B2(M) using the \textit{Herschel}/HIFI instrument. With the high spectral resolution and wide velocity coverage provided by HIFI, 31…
The CH$^+$ ion is a key species in the initial steps of interstellar carbon chemistry. Its formation in diverse environments where it is observed is not well understood, however, because the main production pathway is so endothermic (4280…
Aims: Interstellar molecules form early in the evolutionary sequence of interstellar material that eventually forms stars and planets. To understand this evolutionary sequence, it is important to characterize the chemical composition of its…
We present a theoretical investigation of the chemistry of fluorine-bearing molecules in diffuse and dense interstellar gas clouds. The chemistry of interstellar fluorine is qualitatively different from that of any other element, because -…
The 1-50 GHz GBT PRIMOS data contains ~50 molecular absorption lines observed in diffuse and translucent clouds located in the Galactic Center, Bar, and spiral arms in the line-of-sight to Sgr B2(N). We measure the column densities and…
We present high-resolution observations of interstellar CN, CH, CH^{+}, \ion{Ca}{1}, and \ion{Ca}{2} absorption lines toward the multiple star systems HD206267 and HD217035. Substantial variations in CN absorption are observed among three…
Using high-resolution (~85000) and high signal-to-noise ratio (~200) optical spectra acquired with the European Southern Observatory Ultraviolet and Visual Echelle Spectrograph, we have determined the interstellar column densities of C2 for…
Measuring the temperature and abundance patterns of clouds in the interstellar medium (ISM) provides an observational basis for models of the physical conditions within the clouds, which play an important role in studies of star and planet…
Context. The chemistry of the diffuse interstellar medium rests upon three pillars: exothermic ion-neutral reactions (" cold chemistry "), endothermic neutral-neutral reactions with significant activation barriers (" warm chemistry "), and…
We use UV measurements of interstellar CO towards nearby stars to calculate the density in the diffuse molecular clouds containing the molecules responsible for the observed absorption. Chemical models and recent calculations of the…
Although they are only minor constituents of the interstellar medium, halogen-containing molecules are of special interest because of their unique thermochemistry. Here, we present a theoretical study of the chemistry of interstellar…
Neither HI nor CO emission can reveal a significant quantity of so-called dark gas in the interstellar medium (ISM). It is considered that CO-dark molecular gas (DMG), the molecular gas with no or weak CO emission, dominates dark gas. We…
Ionized carbon is the main gas-phase reservoir of carbon in the neutral diffuse interstellar medium and its 158 micron fine structure transition [CII] is the most important cooling line of the diffuse interstellar medium (ISM). We combine…
The internal energy available in vibrationally excited H2 molecules can be used to overcome or diminish the activation barrier of various chemical reactions of interest for molecular astrophysics. In this article we investigate in detail…
We investigate the correlation between OH and H2 column densities in diffuse Galactic clouds, in order to identify potential molecular tracers of interstellar H2. For this, we analyse near-UV spectra extracted from the ESO/VLT archives…
We present a comprehensive examination of interstellar P and Cl abundances based on an analysis of archival spectra acquired with the Space Telescope Imaging Spectrograph of the Hubble Space Telescope and the Far Ultraviolet Spectroscopic…
Ions (e.g., H$_3^+$, H$_2$O$^+$) have been used extensively to quantify the cosmic-ray ionization rate (CRIR) in diffuse sightlines. However, measurements of CRIR in low-to-intermediate density gas environments are rare, especially when…
We present high-sensitivity CH 9 cm ON/OFF observations toward 18 extra-galactic continuum sources that have been detected with OH 18 cm absorption in the Millennium survey with the Arecibo telescope. CH emission was detected toward six of…