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CO2 is one of the dominant components of the interstellar ice. Recent observations show CO2 exists more abundantly in polar (H2O-dominated) ice than in apolar (H2O-poor) ice. CO2 ice formation is primarily attributed to the reaction between…

Astrophysics of Galaxies · Physics 2023-09-06 Germán Molpeceres , Joan Enrique-Romero , Yuri Aikawa

Formation of interstellar clouds as a consequence of thermal instability is studied using two-dimensional two-fluid magnetohydrodynamic simulations. We consider the situation of converging, supersonic flows of warm neutral medium in the…

Astrophysics of Galaxies · Physics 2015-05-14 Tsuyoshi Inoue , Shu-ichiro Inutsuka

Motivated by recent observations of deuterated molecules in the interstellar medium, we examine the production of HD and D$_2$ molecules on dust grain surfaces. A mechanism for the enhanced production of these deuterated molecules is…

Astrophysics · Physics 2009-11-10 Azi Lipshtat , Ofer Biham , Eric Herbst

Methane is typically thought to be formed in the solid state on the surface of cold interstellar icy grain mantles via the successive atomic hydrogenation of a carbon atom. In the current work we investigate the potential role of molecular…

Astrophysics of Galaxies · Physics 2022-04-06 Thanja Lamberts , Gleb Fedoseev , Marc van Hemert , Danna Qasim , Ko-Ju Chuang , Julia C. Santos , Harold Linnartz

Gas in galactic disks is collected by gravitational instabilities into giant atomic-molecular complexes, but only the inner, molecular parts of these structures are able to collapse to form stars. Determining what controls the ratio of…

Astrophysics · Physics 2009-11-13 Mark R. Krumholz , Christopher F. McKee , Jason Tumlinson

New and archival interferometric 12CO(1->0) datasets from six nearby galaxies are combined with H_2 2.122um and H-alpha maps to explore in detail the interstellar medium in different star-forming galaxies. We investigate the relation…

It is commonly believed that it is unfavourable for adsorbed H atoms on carbonaceous surfaces to form H$_2$ without the help of incident H atoms. Using ring-polymer instanton theory to describe multidimensional tunnelling effects, combined…

Chemical Physics · Physics 2022-04-05 Erxun Han , Wei Fang , Michail Stamatakis , Jeremy O. Richardson , Ji Chen

In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in…

Astrophysics of Galaxies · Physics 2018-10-12 Y. Oba , T. Tomaru , T. Lamberts , A. Kouchi , N. Watanabe

Understanding how the $\mathrm{H}_2$ molecule is formed under the chemical conditions of the interstellar media (ISM) is critical to the whole chemistry of it. Formation of $\mathrm{H}_2$ in the ISM requires a third body acting as a…

Astrophysics of Galaxies · Physics 2023-07-21 Nicolás F. Barrera , Patricio Fuentealba , Francisco Muñoz , Tatiana Gómez , Carlos Cárdenas

Interstellar formamide (NH2CHO) has recently attracted significant attention due to its potential role as a molecular building block in the formation of precursor biomolecules relevant for the origin of life. Its formation, whether on the…

Earth and Planetary Astrophysics · Physics 2018-10-09 Albert Rimola , Dimitrios Skouteris , Nadia Balucani , Cecilia Ceccarelli , Joan Enrique-Romero , Vianney Taquet , Piero Ugliengo

(ABRIDGED) We use hydrodynamical simulations of disk galaxies to study relations between star formation and properties of the molecular interstellar medium (ISM). We implement a model for the ISM that includes low-temperature (T<10^4K)…

Astrophysics · Physics 2009-11-13 Brant Robertson , Andrey Kravtsov

Water ice is abundant both astrophysically, for example in molecular clouds, and in planetary systems. The Kuiper belt objects, many satellites of the outer solar system, the nuclei of comets and some planetary rings are all known to be…

Astrophysics · Physics 2009-11-13 Weijun Zheng , David Jewitt , Ralf I. Kaiser

Observations of spiral galaxies show a strong linear correlation between the ratio of molecular to atomic hydrogen surface density R_mol and midplane pressure. To explain this, we simulate three-dimensional, magnetized turbulence, including…

Astrophysics of Galaxies · Physics 2015-05-20 Mordecai-Mark Mac Low , Simon C. O. Glover

The formation of CO2 in quiescent regions of molecular clouds is not yet fully understood, despite CO2 having an abundance of around 10-34 % H2O. We present a study of the formation of CO2 via the non-energetic route CO + OH on non-porous…

Solar and Stellar Astrophysics · Physics 2011-07-05 Jennifer Anna Noble , François Dulieu , Emanuele Congiu , Helen Jane Fraser

We use observations of the CI, CII, HI, and H_2 column densities along lines of sight in the Galactic plane to determine the formation rate of H_2 on grains and to determine chemical reaction rates with Polycyclic Aromatic Hydrocarbons.…

Astrophysics · Physics 2009-11-13 Mark G. Wolfire , A. G. G. M. Tielens , David Hollenbach , Michael J. Kaufman

The recent discovery of terrestrial-type organic species such as methyl formate and dimethyl ether in the cold interstellar gas has proved that the formation of organic matter in the Galaxy begins at a much earlier stage of star formation…

Astrophysics of Galaxies · Physics 2015-06-15 A. I. Vasyunin , Eric Herbst

We report the results of initial FUSE observations of molecular hydrogen (H2) in translucent clouds. These clouds have greater optical depth than any of the diffuse clouds previously observed for far-UV H2 absorption, and provide new…

Interstellar complex organic molecules (iCOMs) can be loosely defined as chemical compounds with at least six atoms in which at least one is carbon. The observations of iCOMs in star-forming regions have shown that they contain an important…

Solar and Stellar Astrophysics · Physics 2019-09-30 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Piero Ugliengo , Nadia Balucani , Dimitrios Skouteris

Molecules in space are synthesized via a large variety of gas-phase reactions, and reactions on dust-grain surfaces, where the surface acts as a catalyst. Especially, saturated, hydrogen-rich molecules are formed through surface chemistry.…

Astrophysics of Galaxies · Physics 2022-02-11 H. M. Cuppen , A. Fredon , T. Lamberts , E. M. Penteado , M. Simons , C. Walsh

Hydrogenated amorphous carbon (a-C:H) has been proposed as one of the carbonaceous solids detected in the interstellar medium. Energetic processing of the a-C:H particles leads to the dissociation of the C-H bonds and the formation of…

Earth and Planetary Astrophysics · Physics 2016-06-22 Rafael Martín-Doménech , Emmanuel Dartois , Guillermo M. Muñoz Caro