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Decoherence mechanisms in crystals of weakly anisotropic magnetic molecules, such as V15, are studied. We show that an important decohering factor is the rapid thermal fluctuation of dipolar interactions between magnetic molecules. A model…

Materials Science · Physics 2009-10-31 V. V. Dobrovitski , M. I. Katsnelson , B. N. Harmon

We derive unconditionally stable and convergent variable-step BDF2 scheme for solving the MBE model with slope selection. The discrete orthogonal convolution kernels of the variable-step BDF2 method is commonly utilized recently for solving…

Numerical Analysis · Mathematics 2023-02-07 Xuan Zhao , Haifeng Zhang , Hong Sun

We present a semi-classical theory for light deflection by a coherent $\Lambda$-type three-level atomic medium in an inhomogeneous magnetic field or an inhomogeneous control laser. When the atomic energy levels (or the Rabi coupling by the…

Quantum Physics · Physics 2014-03-05 D. L. Zhou , Lan Zhou , R. Q. Wang , S. Yi , C. P. Sun

The behavior of a single molecule driven simultaneously by a laser and by an electric radio frequency field is investigated using a non-Hermitian Hamiltonian approach. Employing the renormalization group method for differential equations we…

Quantum Physics · Physics 2013-05-29 Igor Rozhkov , E. Barkai

The time-dependent optical properties of molecular systems are investigated by step-scan Fourier-transform spectroscopy in order to explore the dynamics at phase transitions and molecular orientation in the milli- and microsecond range. The…

Materials Science · Physics 2016-07-20 Tobias Peterseim , Martin Dressel

We reported a detailed experimental study of the cold collision of Barium monofluoride (BaF) with buffer gas and the high-resolution spectroscopy relevant with direct laser cooling. BaF molecules are efficiently produced with laser ablation…

Atomic Physics · Physics 2017-03-22 Wenhao Bu , Tao Chen , Guitao Lv , Bo Yan

We show that combining vibrational spectroscopy with signal processing can result in a scheme for ultrasensitive detection of molecules. We consider the vibrational spectrum as a signal on the energy axis and apply a matched filter on that…

Computational Physics · Physics 2018-12-10 Tay Yong Boon , Ian Tay Rongde , Loy Liang Yi , Aw Ke Fun , Ong Zhi Li , Sergei Manzhos

We report on the electrostatic trapping of neutral SrF molecules. The molecules are captured from a cryogenic buffer-gas beam source into the moving traps of a 4.5 m long traveling-wave Stark decelerator. The SrF molecules in…

An optical cycling center (OCC) is a recently coined term to indicate two electronic states within a complex quantum object that can repeatedly experience optical laser excitation and spontaneous decay, while being well isolated from its…

Chemical Physics · Physics 2019-12-04 Ming Li , Jacek Kłos , Alexander Petrov , Svetlana Kotochigova

Precision spectroscopic measurements in atoms and molecules play an increasingly important role in chemistry and physics, e.g., to characterize structure and dynamics at long timescales, to determine physical constants, or to search for…

We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 R. Härtle , M. Butzin , M. Thoss

We investigate the dynamics of binary mixtures of inelastic particles through event-driven molecular dynamics simulations, focusing on velocity autocorrelation functions (VACFs). The study examines two distinct particle types under varying…

Soft Condensed Matter · Physics 2025-03-04 Rameez Farooq Shah , Syed Rashid Ahmad , Shikha Kumari

Molecular collisions can be studied at very low relative kinetic energies, in the milliKelvin range, by merging codirectional beams with much higher translational energies, extending even to the kiloKelvin range, provided that the beam…

Chemical Physics · Physics 2015-06-05 Qi Wei , Igor Lyuksyutov , Dudley Herschbach

A time-dependent vibrational electronic coupled-cluster (VECC) approach is proposed to simulate photoelectron/ UV-VIS absorption spectra, as well as time-dependent properties for non-adiabatic vibronic models, going beyond the…

Chemical Physics · Physics 2023-12-25 Songhao Bao , Neil Raymond , Marcel Nooijen

We present an experimental realization of a moving magnetic trap decelerator, where paramagnetic particles entrained in a cold supersonic beam are decelerated in a co-moving magnetic trap. Our method allows for an efficient slowing of both…

A multiscale QM/classical approach is presented, that is able to model the optical properties of complex nanostructures composed of a molecular system adsorbed on metal nanoparticles. The latter are described by a combined…

Chemical Physics · Physics 2024-10-29 Pablo Grobas Illobre , Piero Lafiosca , Luca Bonatti , Tommaso Giovannini , Chiara Cappelli

It has been roughly three decades since laser cooling techniques produced ultracold atoms, leading to rapid advances in a vast array of fields. Unfortunately laser cooling has not yet been extended to molecules because of their complex…

Atomic Physics · Physics 2015-05-27 E. S. Shuman , J. F. Barry , D. DeMille

A Stark decelerator is an effective tool for controlling motional degrees of freedom of polar molecules. Due to technical limitations, many of the current Stark decelerators focus on molecules in low-field-seeking quantum states and are…

Atomic Physics · Physics 2017-05-25 Demitri Y. Balabanov , Liam M. Duffy

We introduce the variable coherence model (VCM) for simulating free-electron laser (FEL) pulses generated through self-amplified spontaneous emission. Building on the established partial coherence model of [T. Pfeifer et. al, Opt. Lett. 35,…

Optics · Physics 2026-04-23 Austin Bartunek , Nils H. Sommerfeld , Francois Mauger

Optically trapped laser-cooled polar molecules hold promise for new science and technology in quantum information and quantum simulation. Large numerical aperture optical access and long trap lifetimes are needed for many studies, but these…

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