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Closed quantum systems with quenched randomness exhibit many-body localized regimes wherein they do not equilibrate even though prepared with macroscopic amounts of energy above their ground states. We show that such localized systems can…

Statistical Mechanics · Physics 2013-10-24 David A. Huse , Rahul Nandkishore , Vadim Oganesyan , Arijeet Pal , S. L. Sondhi

Accurately solving the electronic structure problem through the variational quantum eigensolver (VQE) is hindered by the available quantum resources of current and near-term devices. One approach to relieving the circuit depth requirements…

Quantum Physics · Physics 2023-08-31 Robert A. Lang , Aadithya Ganeshram , Artur F. Izmaylov

The field-induced antiferromagnetic ordering in systems of weakly coupled S=1/2 dimers at zero temperature can be described as a Bose-Einstein condensation of triplet quasiparticles (singlet quasiholes) in the ground state. For the case of…

Strongly Correlated Electrons · Physics 2010-03-23 Tommaso Roscilde , Stephan Haas

Quantum state discrimination is a fundamental primitive in quantum information processing, underpinning tasks in quantum communication, sensing, and learning. We consider the general Bayes framework, as introduced by Helstrom, for state…

Quantum Physics · Physics 2026-05-01 Ankith Mohan , Jamie Sikora , Sarvagya Upadhyay

For any local Hamiltonian H, I construct a local CPT map and stopping condition which converges to the ground state subspace of H. Like any ground state preparation algorithm, this algorithm necessarily has exponential run-time in general…

Quantum Physics · Physics 2023-09-25 Toby S. Cubitt

Variational algorithms are promising candidates to be implemented on near-term quantum computers. The variational quantum eigensolver (VQE) is a prominent example, where a parametrized trial state of the quantum mechanical wave function is…

The problem of quantum state discrimination between two wave functions of a particle in a square well potential is considered. The optimal minimum-error probability for the state discrimination is known to be given by the Helstrom bound. A…

Quantum Physics · Physics 2010-10-26 Bernhard K. Meister

The Variational Quantum Eigensolver (VQE) is one the most perspective algorithms for simulation of quantum many body physics that have recently attached a lot of attention and believed would be practical for implementation on the near term…

Quantum Physics · Physics 2021-05-03 Belozerova Polina , Shangareev Arthur , Zotov Yuriy , Yung Manhong , lv Dingshun

Analog models of quantum information processing, such as adiabatic quantum computation and analog quantum simulation, require the ability to subject a system to precisely specified Hamiltonians. Unfortunately, the hardware used to implement…

Quantum Physics · Physics 2014-02-25 Kevin C. Young , Robin Blume-Kohout , Daniel A. Lidar

One of the challenging scientific computing problems is topology optimization, where searching through the combinatorially complex configurations and solving the constraints of partial differential equations need to be done simultaneously.…

Quantum Physics · Physics 2025-03-05 Jungin E. Kim , Yan Wang

The variational quantum eigensolver (VQE) is currently the flagship algorithm for solving electronic structure problems on near-term quantum computers. This hybrid quantum/classical algorithm involves implementing a sequence of…

Variational Quantum Eigensolver (VQE) is a promising algorithm for near-term quantum machines. It can be used to estimate the ground state energy of a molecule by performing separate measurements of $O(N^4)$ terms. Several recent papers…

Quantum Physics · Physics 2019-09-02 Pranav Gokhale , Frederic T. Chong

Hybrid quantum-classical approaches offer potential solutions to quantum chemistry problems, yet they often manifest as constrained optimization problems. Here, we explore the interconnection between constrained optimization and generalized…

Quantum Physics · Physics 2025-03-27 Muqing Zheng , Bo Peng , Ang Li , Xiu Yang , Karol Kowalski

The iterative diagonalization of a sequence of large ill-conditioned generalized eigenvalue problems is a computational bottleneck in quantum mechanical methods employing a nonorthogonal basis for {\em ab initio} electronic structure…

Materials Science · Physics 2013-08-13 Yunfeng Cai , Zhaojun Bai , John E. Pask , N. Sukumar

In the Noisy Intermediate-Scale Quantum (NISQ) era, solving the electronic structure problem from chemistry is considered as the "killer application" for near-term quantum devices. In spite of the success of variational hybrid…

Variational approaches, such as variational Monte Carlo (VMC) or the variational quantum eigensolver (VQE), are powerful techniques to tackle the ground-state many-electron problem. Often, the family of variational states is not invariant…

Quantum Physics · Physics 2023-10-10 Javier Robledo Moreno , Jeffrey Cohn , Dries Sels , Mario Motta

Variational quantum algorithms (VQAs) have emerged as a promising approach for achieving quantum advantage on current noisy intermediate-scale quantum devices. However, their large-scale applications are significantly hindered by…

Quantum Physics · Physics 2026-03-03 Shikun Zhang , Zheng Qin , Yongyou Zhang , Yang Zhou , Rui Li , Chunxiao Du , Zhisong Xiao

The accurate calculation of electronic potential energy surfaces for ground and excited states is crucial for understanding photochemical processes, particularly near conical intersections. While classical methods are limited by scaling and…

Quantum Physics · Physics 2025-09-18 Tomáš Bezděk

Computational cost of energy estimation for molecular electronic Hamiltonians via Quantum Phase Estimation (QPE) grows with the difference between the largest and smallest eigenvalues of the Hamiltonian. In this work we propose a…

Quantum Physics · Physics 2023-10-26 Ignacio Loaiza , Artur F. Izmaylov

Quantum computing has gained a lot of attention recently, and scientists have seen potential applications in this field using quantum computing for Cryptography and Communication to Machine Learning and Healthcare. Protein folding has been…

Quantum Physics · Physics 2022-11-16 Hasan Mustafa , Sai Nandan Morapakula , Prateek Jain , Srinjoy Ganguly