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The role of chirality in determining the spin dynamics of photoinduced electron transfer in donor-acceptor molecules remains an open question. Although chirality-induced spin selectivity (CISS) has been demonstrated in molecules bound to…

The chiral-induced spin selectivity (CISS) effect, a phenomenon where the chirality of molecules imparts significant spin selectivity to electron transfer processes, has garnered increasing interest among the chemistry, biology, and physics…

Chemical Physics · Physics 2025-09-05 Tian-Yi Zhang , Yue Mao , Ai-Min Guo , Qing-Feng Sun

Spin triplet exciton formation sets limits on technologies using organic semiconductors that are confined to singlet-triplet photophysics. In contrast, excitations in the spin doublet manifold in organic radical semiconductors can show…

Chemical Physics · Physics 2023-12-19 Qinying Gu , Sebastian Gorgon , Alexander S. Romanov , Feng Li , Richard H. Frienda , Emrys Evansd

Chiral-induced spin selectivity (CISS) enables spin selectivity of charge carriers in chiral molecular systems without magnetic materials. While spin selectivity has been widely investigated, its quantum coherence has not yet been explored.…

Quantum Physics · Physics 2026-01-09 Hanna T. Fridman , Rotem Malkinson , Amir Hen , Shira Yochelis , Yossi Paltiel , Nir Bar-gill

Here we propose a mechanism by which spin polarization can be generated dynamically in chiral molecular systems undergoing photo-induced electron transfer. The proposed mechanism explains how spin polarization emerges in systems where…

Mesoscale and Nanoscale Physics · Physics 2021-08-19 Thomas P. Fay , David T. Limmer

Chiral molecular structures enable time-odd pseudotensor that controls correlations between photoelectron spin and molecular orientation in photoionization (arXiv:2505.22433). We show that chiral structures also support time-even…

Biomolecules that constitute life on Earth are chiral, but the precise mechanism by which homochirality emerged remains a mystery. In this work it is demonstrated that reactions of radical pairs, where one of the radical electron spins is…

Chemical Physics · Physics 2025-08-08 Thomas P Fay

The spin dynamics of radical-triplet system (RTS) has been calculated by using the Lindblad formalism within the theory of open quantum system. The single-radical-triplet system (SRTS) is considered here for single-qubit quantum gate…

Quantum Physics · Physics 2015-01-05 Wei Wu

For over two decades, the role of structural chirality in spin polarization has been widely investigated, with implications for the origins of life, catalysis, and quantum phenomena. Yet, it remains unclear whether all chirality-induced…

Mesoscale and Nanoscale Physics · Physics 2025-05-12 Pius M. Theiler , Sander Driessen , Matthew C. Beard

Radical pairs in the flavoprotein cryptochrome are central to various magnetically sensitive biological processes, including the proposed mechanism of avian magnetoreception. Cryptochrome's molecular chirality has been hypothesized to…

Quantum Physics · Physics 2025-05-06 Luke D. Smith , Sukesh Tallapudi , Matt C. J. Denton , Daniel R. Kattnig

High-spin states in molecular systems hold significant interest for a wide range of applications ranging from optoelectronics to quantum information and singlet fission (SF). Quintet and triplet states play crucial roles, particularly in SF…

Despite generally lacking ferromagnetic properties or strong spin-orbit coupling, electrons in chiral molecules exhibit unique spin-dependent transport behavior, known as chiral-induced spin selectivity (CISS). This phenomenon implies a…

Chemical Physics · Physics 2025-09-05 Peng-Yi Liu , Tian-Yi Zhang , Qing-Feng Sun

Chiral-induced spin selectivity (CISS) has been shown to enhance magnetic sensitivity in radical pair mechanism (RPM) models under specific Hamiltonian conditions, yet whether these enhancements persist across a broader parameter space…

Biological Physics · Physics 2026-05-22 Tristen Gwynn , Betony Adams , Francesco Petruccione

Recent progress in constructing supramolecular assemblies with hierarchical chirality offers new opportunities to investigate the chirality-induced spin selectivity (CISS) effect and its potential applications. In this work, we…

Mesoscale and Nanoscale Physics · Physics 2025-12-22 Song Chen , Kai-Yuan Zhang , Xi Sun , Shu-Zheng Zhou , Hua-Hua Fu

The chirality-induced spin selectivity (CISS) effect has garnered significant interest in the field of molecular spintronics due to its potential for creating spin-polarized electrons without the need for a magnet. Recent studies devoted to…

We present a non-perturbative theory that describes how light regulates chiral-induced spin selectivity (CISS) from the perspective of strong light-matter interactions. The research results indicate that 1) light can have opposite effects…

Quantum Physics · Physics 2023-10-18 Wei Liu , Jingqi Chen , Wenjie Dou

The chirality-induced spin selectivity (CISS) effect has been confirmed experimentally for a large class of organic molecules. Adequately modeling the effect remains a challenging task, with both phenomenological models and first-principle…

Mesoscale and Nanoscale Physics · Physics 2020-06-24 Matthias Geyer , Rafael Gutierrez , Gianaurelio Cuniberti

We provide a critical overview of the theory of the chirality-induced spin selectivity (CISS) effect, i.e., phenomena in which the chirality of molecular species imparts significant spin selectivity to various electron processes. Based on…

Chirality-induced spin selectivity (CISS) is a striking quantum phenomenon in which electron transport through chiral molecules leads to spin polarization -- even in the absence of external magnetic fields or magnetic components. Although…

Mesoscale and Nanoscale Physics · Physics 2025-09-12 Shiv Upadhyay , Xuechen Zheng , Tian Wang , Agam Shayit , Jun Liu , Dali Sun , Xiaosong Li

The helical distribution of the electronic density in chiral molecules, such as DNA and bacteriorhodopsin, has been suggested to induce a spin-orbit coupling interaction that may lead to the so-called chirality-induced spin selectivity…

Mesoscale and Nanoscale Physics · Physics 2020-01-01 Miguel A. Sierra , David Sanchez , Rafael Gutierrez , Gianaurelio Cuniberti , Francisco Dominguez-Adame , Elena Diaz
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