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Oxygen evolution reaction (OER) with intractable high overpotential is the rate-limiting step for rechargeable metal-air battery, water electrolysis systems, and solar fuels devices. There exists a spin state transition from spin singlet…

Materials Science · Physics 2020-04-14 Xiaoning Li , Zhenxiang Cheng , Xiaolin Wang

NiFe oxyhydroxide is one of the most promising oxygen evolution reaction (OER) catalysts for renewable hydrogen production, and deciphering the identity and reactivity of the oxygen intermediates on its surface is a key challenge but is…

Materials Science · Physics 2020-10-01 Yaming Hao , Yefei Li , Jianxiang Wu , Jinling Wang , Chenglin Jia , Tao Liu , Xuejing Yang , Zhipan Liu , Ming Gong

A comprehensive understanding of the electrode-electrolyte interface in energy conversion systems remains challenging due to the complex and multifaceted nature of interfacial processes. This complexity hinders the development of more…

Chemical Physics · Physics 2024-10-23 Ben Wang , Tomohiro Fukushima , Hiro Minamimoto , Andrey Lyalin , Kei Murakoshi , Tetsuya Taketsugu

Interactions between the different degrees of freedom form the basis of many manifestations of intriguing physics in condensed matter. In this respect, quantifying the dynamics of normal modes that themselves arise from these interactions…

This article provides a review of recent developments in the field of 3d transition metal (TM) catalysts for different reactions including oxygen-based reactions such as Oxygen Reduction Reaction (ORR) and Oxygen Evolution Reaction (OER).…

Materials Science · Physics 2023-09-13 Satadeep Bhattacharjee , Swetarekha Ram , Seung-Cheol Lee

We show that an ensemble of $^2\Sigma$ molecules in the rotationally ground state trapped on an optical lattice exhibits collective spin excitations that can be controlled by applying superimposed electric and magnetic fields. In…

Chemical Physics · Physics 2010-10-12 Jesús Pérez-Ríos , Felipe Herrera , Roman V. Krems

For large-scale deployment and use of polymer electrolyte fuel cells, high-performance electrocatalysts with low platinum consumption are desirable. One promising strategy to meet this demand is to explore alternative materials that retain…

Materials Science · Physics 2025-09-01 Kevin Allen , Christopher Lane , Emilia Morosan , Jian-Xin Zhu

While 3$d$-containing materials display strong electron correlations, narrow band widths, and robust magnetism, 5$d$ systems are recognized for strong spin-orbit coupling, increased hybridization, and more diffuse orbitals. Combining these…

To reach a long term viable green hydrogen economy, rational design of active oxygen evolution reaction (OER) catalysts is critical. An important hurdle in this reaction originates from the fact that the reactants are singlet molecules,…

We report a neutron diffraction study of the multiferroic mechanism in (ND4)2FeCl5D2O, a molecular compound that exhibits magnetically induced ferroelectricity. This material exhibits two successive magnetic transitions on cooling: a…

Spin-orbit entangled magnetic dipoles, often referred to as pseudospins, provide a new avenue to explore novel magnetism inconceivable in the weak spin-orbit coupling limit, but the nature of their low-energy interactions remains to be…

Using spin-assisted ab-initio random structure searches, we explore an exhaustive quantum phase diagram of archetypal interfaced Mott insulators, i.e. lanthanum-iron and lanthanum-titanium oxides. In particular, we report that the charge…

Strongly Correlated Electrons · Physics 2021-04-29 Carla Lupo , Evan Sheridan , Edoardo Fertitta , David Dubbink , Chris J. Pickard , Cedric Weber

Oxidation catalysis on reducible oxide-supported small metal clusters often involves lattice oxygen. In the present work, we trace the path of lattice oxygen from Fe3O4(001) onto small Pt clusters during the CO oxidation, aiming at…

Magnetoelasticity plays a crucial role in numerous magnetic phenomena, including magnetocalorics, magnon excitation via acoustic waves, and ultrafast demagnetization/Einstein-de Haas effect. Despite a long-standing discussion on…

Dielectric study on Ca3Mn2O7 features relaxor-like segmented dynamics below the antiferromagnetic ordering. Dipolar relaxations of different origin are spectrally resolved exhibiting distinct H-field alterations. This identifies their…

Materials Science · Physics 2019-09-10 Pooja Sahlot , Gaurav Sharma , Vasant Sathe , Anand Mohan Awasthi

Novel interplay of spin-orbit coupling and electron correlations in complex Ir oxides recently emerged as a new paradigm for correlated electron physics. Because of a large spin-orbit coupling of ~0.5 eV, which is comparable to the transfer…

Strongly Correlated Electrons · Physics 2015-06-22 Jobu Matsuno , Kota Ihara , Shugen Yamamura , Hiroki Wadati , Kenji Ishii , V. Vijay Shankar , Hae-Young Kee , Hidenori Takagi

Spin-phonon coupling originated from spin-lattice correlation depends upon different exchange interactions in transition metal oxides containing 3d magnetic ions. Spin-lattice coupling can influence the coupling mechanism in magnetoelectric…

Strongly Correlated Electrons · Physics 2021-09-09 P. Pal , Shalini Badola , P. K. Biswas , Ranjana R. Das , Surajit Saha , S. D. Kaushik , P. N. Vishwakarma , A. K. Singh

The magnetic Gilbert damping and spin-orbital to charge interconversion phenomenon play vital role in controlling the modern spintronics device performances. Though the ferromagnets (FMs) and heavy metals (HMs) are considered to be the key…

Mesoscale and Nanoscale Physics · Physics 2024-11-05 Antarjami Sahoo , Swayang Priya Mahanta , Subhankar Bedanta

In antiferromagnets, the interplay of spin frustration and spin-lattice coupling has been extensively studied as the source of complex spin patterns and exotic magnetism. Here, we demonstrate that, although neglected in the past, the…

Motivated by the recent activities on the Ni-based diamond lattice antiferromagnet NiRh$_2$O$_4$, we theoretically explore on a general ground the unique spin and orbital physics for the Ni$^{2+}$ ions with a $3d^8$ electron configuration…

Strongly Correlated Electrons · Physics 2019-07-10 Fei-Ye Li , Gang Chen
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