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Understanding how colloids move in crowded environments is key for gaining control over their transport in applications such as drug delivery, filtration, contaminant/microplastic remediation and agriculture. The classical models of colloid…

Soft Condensed Matter · Physics 2026-04-15 Mobin Alipour , Yiran Li , Haoyu Liu , Amir A. Pahlavan

In this letter, we show that pore-scale diffusiophoresis of colloidal particles along local salt gradients manifests in the macroscopic dispersion of particles in a porous medium. Despite is transient character, this microscopic phenomenon…

Soft Condensed Matter · Physics 2023-03-16 Mamta Jotkar , Pietro de Anna , Marco Dentz , Luis Cueto-Felgueroso

Predicting and controlling the transport of colloids in porous media is essential for a broad range of applications, from drug delivery to contaminant remediation. Chemical gradients are ubiquitous in these environments, arising from…

Soft Condensed Matter · Physics 2026-04-13 Yiran Li , Mobin Alipour , Amir Pahlavan

Diffusiophoresis, a ubiquitous phenomenon that induces particle transport whenever solute concentration gradients are present, was recently observed in the context of microsystems and shown to strongly impact colloidal transport (patterning…

Solute-surface interactions have garnered considerable interest in recent years as a novel control mechanism for driving unique fluid dynamics and particle transport with potential applications in fields such as biomedicine, the development…

Fluid Dynamics · Physics 2023-05-05 Jian Teng , Bhargav Rallabandi , Jesse T. Ault

We report an experimental study on the manipulation of colloidal particles in a drop sitting on a hydrogel. The manipulation is achieved by diffusiophoresis, which describes a directed motion of particles induced by solute gradients. By…

Soft Condensed Matter · Physics 2017-10-17 François Boulogne , Sangwoo Shin , Julien Dervaux , Laurent Limat , Howard A. Stone

Current theories of diffusiophoresis in porous media are limited to a porous medium saturated with a valence symmetric electrolyte. A predictive model for diffusiophoresis in porous media saturated with a valence asymmetric electrolyte, or…

Soft Condensed Matter · Physics 2024-12-03 Siddharth Sambamoorthy , Henry C. W. Chu

Efficient mixing of colloids, particles or molecules is a central issue in many processes. It results from the complex interplay between flow deformations and molecular diffusion, which is generally assumed to control the homogenization…

Diverse processes -- e.g., environmental pollution, groundwater remediation, oil recovery, filtration, and drug delivery -- involve the transport of colloidal particles in porous media. Using confocal microscopy, we directly visualize this…

Soft Condensed Matter · Physics 2021-03-23 Navid Bizmark , Joanna Schneider , Rodney D. Priestley , Sujit S. Datta

In this article, we study experimentally the dispersion of colloids in a two-dimensional, time independent, Rayleigh-B\'enard flow in the presence of salt gradients. Due to the additional scalar, the colloids do not follow exactly the…

Fluid Dynamics · Physics 2026-01-14 Florence Raynal , Menghua Zhao , Romain Volk

In this work, we numerically investigate the impact of two-dimensional solute gradients on the distribution of colloidal particles, i.e., colloidal banding, induced via diffusiophoresis. The solute gradients are generated by spatially…

Soft Condensed Matter · Physics 2023-01-11 Ritu R. Raj , C. Wyatt Shields , Ankur Gupta

Microparticles migrate in response to gradients in solute concentration through diffusiophoresis and diffusioosmosis. Merging streams of fluid with distinct solute concentrations is a common strategy for producing a steady concentration…

Fluid Dynamics · Physics 2023-06-01 Robben E. Migacz , Guillaume Durey , Jesse T. Ault

We study a reaction-diffusion model posed on two distinct spatial scales that accounts for diffusion, aggregation, fragmentation, and deposition of populations of colloidal particles within a porous material. In this model, the macroscopic…

Analysis of PDEs · Mathematics 2026-04-14 Christos Nikolopoulos , Michael Eden , Adrian Muntean

Periodic forcing of flow in compressible porous media is an important driver for solute dispersion and mixing in geological and engineered porous media subject for example to tides, pumping and recharge cycles, or fluid injection and…

Fluid Dynamics · Physics 2025-06-17 Satoshi Tajima , Marco Dentz

Diffusiophoresis (DP) refers to the migration of particles driven by a solute concentration gradient in a liquid. Observations in the case of molecular neutral solutes are rather scarce, due to the low drift velocities in dilute solutions,…

Solute gradients next to an interface drive a diffusioosmotic flow, the origin of which lies in the intermolecular interactions between the solute and the interface. These flows on the surface of colloids introduce an effective slip…

Soft Condensed Matter · Physics 2025-06-09 Haoyu Liu , Amir A. Pahlavan

We study bacterial diffusion in disordered porous media. Interactions with obstacles, at unknown locations, make this problem challenging. We approach it by abstracting the environment to cell states with memoryless transitions. With this,…

Soft Condensed Matter · Physics 2023-12-29 Henry H. Mattingly

In a binary fluid mixture, the concentration gradient of a heavier molecular solute leads to a diffusive flux of solvent and solute to achieve thermodynamic equilibrium. If the solute concentration decreases with height, the system is…

We study analytically the joint dispersion of Gaussian patches of salt and colloids in linear flows, and how salt gradients accelerate or delay colloid spreading by diffusiophoretic effects. Because these flows have constant gradients in…

In this article, we study numerically the dispersion of colloids in a two-dimensional cellular flow in the presence of an imposed mean salt gradient. Owing to the additional scalar, the colloids do not follow exactly the Eulerian flow…

Fluid Dynamics · Physics 2022-09-23 Romain Volk , Michaël Bourgoin , Charles-Édouard Bréhier , Florence Raynal
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