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Nonlinear spectroscopy provides a unique perspective to understand time-resolved molecular dynamics under vibrational strong coupling (VSC). Herein, equilibrium-nonequilibrium cavity molecular dynamics simulations are performed to compute…

Chemical Physics · Physics 2026-03-26 Xinwei Ji , Tomislav Begusic , Tao E. Li

Polariton chemistry has been hailed as a potential new route to direct molecular processes with electromagnetic fields. To make further strides, it is essential for the community to clarify which unusual polaritonic phenomena are true…

Chemical Physics · Physics 2025-11-19 Alexander M. McKillop , Marissa L. Weichman

Recent experiments have revealed the profound effect of strong light-matter interactions in optical cavities on the electronic ground state of molecular systems. This phenomenon, known as vibrational strong coupling (VSC), can modify…

Quantum Physics · Physics 2023-12-19 Thomas Schnappinger , Markus Kowalewski

Phase transitions, where observable properties of a many-body system change discontinuously, can occur in both open and closed systems. Ultracold atoms have provided an exemplary model system to demonstrate the physics of closed-system…

We propose a scheme which can realize an extended two-component Bose-Hubbard model using polaritons confined in an array of optical cavities. In addition to the density-dependent interactions, this model also contains nonlinear coupling…

Strongly Correlated Electrons · Physics 2015-06-11 Yong-Chang Zhang , Xiang-Fa Zhou , Xingxiang Zhou , Guang-Can Guo , Han Pu , Zheng-Wei Zhou

We study a 2D system of trion-polaritons at the quantum level and demonstrate that for monolayer semiconductors they can exhibit a strongly nonlinear optical response. The effect is due to the composite nature of trion-based excitations…

Quantum Physics · Physics 2020-11-11 O. Kyriienko , D. N. Krizhanovskii , I. A. Shelykh

High-harmonic spectroscopy driven by circularly-polarized laser pulses and their counter-rotating second harmonic is a new branch of attosecond science which currently lacks quantitative interpretations. We extend this technique to the…

Atomic Physics · Physics 2019-09-04 Denitsa Baykusheva , Simon Brennecke , Manfred Lein , Hans Jakob Wörner

Cavity dressing of molecular vibrational dynamics expands the role of characteristic vibrations as spectroscopic markers of underlying ultrafast dynamics. Interacting vibrational modes exhibit a pronounced excited state delocalization due…

Quantum Physics · Physics 2026-01-06 Arunangshu Debnath

We report on confined exciton resonances of acoustic and folded acoustic phonon light scattering in a GaAs/AlAs multi-quantum-well. Significant variations of the line shifts and widths are observed across the resonance and quantitatively…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 B. Jusserand , A. Fainstein , R. Ferreira , S. Majrab , A. Lemaitre

Motivated by the recent advances in optical imaging and tracking of wave-packet propagation in optical cavities, we systematically explore the non-Hermitian polariton dynamics within a decay-tunable multimode cavity model. The complex…

Quantum Physics · Physics 2025-07-29 Md Qutubuddin , Ilia Tutunnikov , Jianshu Cao

We model single photon nonlinearities resulting from the dipole-dipole interactions of cold polar molecules. We propose utilizing ``dark state polaritons'' to effectively couple photon and molecular states; through this framework, coherent…

Quantum Physics · Physics 2013-05-29 R. M. Rajapakse , T. Bragdon , A. M. Rey , T. Calarco , S. F. Yelin

Techniques for coherent multidimensional optical spectroscopy have been developed and utilised to understand many different processes, including energy transfer in photosynthesis and many-body effects in semiconductor nanostructures.…

Optics · Physics 2017-01-24 Jonathan Tollerud , Jeffrey Davis

Calculation of the coherent nonlinear response of a system is essential to correctly interpret results from advanced techniques such as two-dimensional coherent spectroscopy (2DCS). Usually, even for the simplest systems, such calculations…

In many-cycle plane waves at intermediate intensities, the nonlinear trident process can be well-approximated by the two sequential steps of nonlinear Compton scattering of a polarised real photon followed by its transformation into an…

High Energy Physics - Phenomenology · Physics 2023-05-11 S. Tang , B. King

In this work we investigate anharmonic vibrational polaritons formed due to strong light-matter interactions in an optical cavity between radiation modes and anharmonic vibrations beyond the long-wavelength limit. We introduce a…

Quantum Physics · Physics 2024-09-13 Dipti Jasrasaria , Arkajit Mandal , David R. Reichman , Timothy C. Berkelbach

We study the quantum dynamics of diatomic molecule driven by a circularly polarized resonant electric field. We look for a quantum effect due to classical chaos appearing due to the overlapping of nonlinear resonances associated to the…

Quantum Physics · Physics 2015-05-20 G. V. Lopez , J. G. T. Zanudo

Controlling the quantum field statistics of confined light is a long-standing goal in integrated photonics. We show that by coupling molecular vibrations with a confined mid-infrared cavity vacuum, the photocount and quadrature field…

Quantum Physics · Physics 2022-02-23 Johan F. Triana , Felipe Herrera

We present a simple and efficient method to incorporate anharmonic effects in the vibrational \textcolor{black}{analyses} of molecules within density functional theory (DFT) calculations. This approach is closely related to the traditional…

Recent advances in the study of synthetic dimensions revealed a possibility to employ the frequency space as an additional degree of freedom which allows for investigating and exploiting higher-dimensional phenomena in a priori…

Pattern Formation and Solitons · Physics 2020-08-19 Aleksandr K. Tusnin , Alexey M. Tikan , Tobias J. Kippenberg

The one-electron spectral function of the Holstein-Hubbard bipolaron in one dimension is studied using cluster perturbation theory together with the Lanczos method. In contrast to other approaches, this allows one to calculate the spectrum…

Strongly Correlated Electrons · Physics 2007-06-13 Martin Hohenadler , Markus Aichhorn , Wolfgang von der Linden