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The thermodynamics of a long self-repulsive chain is studied. In $D<4$ dimensions it shows two distinctly different regimes, corresponding to weak and strong correlations in the system. A simple microscopic analytical model is presented…

Statistical Mechanics · Physics 2007-05-23 A. N. Rubtsov

During fast diffusion-influenced polymerization, nonequilibrium behavior of the polymer chains and the surrounding reactive monomers has been reported recently. Based on the laws of thermodynamics, the emerging nonequilibrium structures…

Soft Condensed Matter · Physics 2022-03-14 Michael Bley , Joachim Dzubiella

We study the dynamics of a single chain polymer confined to a two dimensional cell. We introduce a kinetically constrained lattice gas model that preserves the connectivity of the chain, and we use this kinetically constrained model to…

Statistical Mechanics · Physics 2011-11-09 Armin Rahmani , Claudio Castelnovo , Jeremy Schmit , Claudio Chamon

Non-equilibrium random fluctuations of non-thermal nature are a salient feature of active matter. In this work, we consider the collective excitations of active systems at high density, focusing on a one-dimensional chain of elastically…

Soft Condensed Matter · Physics 2024-01-17 Umberto Marini Bettolo Marconi , Hartmut Löwen , Lorenzo Caprini

Based on the explicit knowledge of a Hamiltonian of mean force, the classical statistical mechanics and equilibrium thermodynamics of open systems in contact with a thermal environment at arbitrary interaction strength can be formulated.…

Statistical Mechanics · Physics 2016-09-14 Peter Talkner , Peter Hänggi

The bond fluctuation model with a bond potential has been applied to investigation of the glass transition of linear chains and chains with a regular disposition of small branches. Cooling and subsequent heating curves are obtained for the…

Soft Condensed Matter · Physics 2007-05-23 Juan J. Freire

We explore the transport features of a single flexible polymer chain that walks on a periodic ratchet potential coupled with spatially varying temperature. At steady state the polymer exhibits a fast unidirectional motion where the…

Soft Condensed Matter · Physics 2015-07-20 Mesfin Asfaw Taye

Conventional studies of biomolecular behaviors rely largely on the construction of kinetic schemes. Since the selection of these networks is not unique, a concern is raised whether and under which conditions hierarchical schemes can reveal…

Molecular Networks · Quantitative Biology 2015-07-07 De-Ming Deng , Cheng-Hung Chang

In this work an approximated path integral model describing the dynamics of a inextensible chain is presented. To this purpose, the nonlinear constraints which enforce the property of inextensibility of the chain are relaxed and are just…

Statistical Mechanics · Physics 2010-09-20 Franco Ferrari , Maciej Pyrka

Aiming at the mechanical properties of cross-linked biopolymers, we set up and analyze a model of two weakly bending wormlike chains subjected to a tensile force, with regularly spaced inter-chain bonds (cross-links) represented by harmonic…

Biological Physics · Physics 2014-06-24 Alice von der Heydt , Daniel Wilkin , Panayotis Benetatos , Annette Zippelius

We present an exactly solvable model of a Gaussian (flexible) polymer chain in a quenched random medium. This is the case when the random medium obeys very long range quadratic correlations. The model is solved in $d$ spatial dimensions…

Disordered Systems and Neural Networks · Physics 2009-10-31 Yohannes Shiferaw , Yadin Y. Goldschmidt

We study a model of rolling particles subject to stochastic fluctuations, which may be relevant in systems of nano- or micro-scale particles where rolling is an approximation for strong static friction. We consider the simplest possible…

Mathematical Physics · Physics 2016-10-04 Miranda Holmes-Cerfon

From understanding the sand on the beach to the foam on your beer, soft sphere simulations have been crucial to the study of the amorphous world around us. However, many of the materials we interact with on a daily basis aren't comprised of…

Soft Condensed Matter · Physics 2024-03-18 R. C. Dennis

The statistical mechanics of a long knotted collapsed polymer is determined by a free-energy with a knot-dependent subleading term, which is linked to the length of the shortest polymer that can hold such knot. The only other parameter…

Statistical Mechanics · Physics 2014-12-01 Marco Baiesi , Enzo Orlandini , Attilio L. Stella

The stretching response of polymer chains fundamentally determines the mechanical properties of polymer networks. In this Letter, we develop a statistical mechanics model that incorporates both bond stretching and bond angle deformation,…

Soft Condensed Matter · Physics 2025-06-02 Jie Zhu , Laurence Brassart

We analyze the fluctuations in particle positions and inter-particle forces in disordered jammed crystals in the limit of weak disorder. We demonstrate that such athermal systems are fundamentally different from their thermal counterparts,…

Soft Condensed Matter · Physics 2020-07-08 Pappu Acharya , Surajit Sengupta , Bulbul Chakraborty , Kabir Ramola

The elastic response is studied of a single flexible chain grafted on a rigid plane and an ensemble of non-interacting tethered chains. It is demonstrated that the entropic theory of rubber elasticity leads to conclusions that disagree with…

Statistical Mechanics · Physics 2007-05-23 A. D. Drozdov

The characterization of the interactions between two fully flexible self-avoiding polymers is one of the classic and most important problems in polymer physics. In this paper we measure these interactions in the presence of active…

Soft Condensed Matter · Physics 2022-04-06 M. C. Gandikota , A. Cacciuto

We consider the force on the end of a polymer chain being pulled through a network at velocity $v$, using computer simulations. We develop algorithms for measuring the force on the end of the chain using lattice models of polymers. Our…

Condensed Matter · Physics 2009-10-22 J. M. Deutsch , Hyoungsoo Yoon

Motivated by recent advances in single molecule manipulation techniques that enabled several groups to tie knots in individual polymer strands and to monitor their dynamics, we have used computer simulations to study "friction knots"…

Biological Physics · Physics 2007-05-23 Serdal Kirmizialtin , Dmitrii E. Makarov